Liquid absorbing sheet and nonaqueous electrolyte battery pack

• US 7,399,531 B2
• Filed: 02/17/2004
• Issued: 07/15/2008
• Est. Priority Date: 02/18/2003
• Status: Active Grant

• Current Assignee: Sony Corporation (Sony Group Corp.)
• Original Assignee: Sony Chemical & Information Device Corporation (Sony Group Corp.), Sony Corporation (Sony Group Corp.)
• Inventors: Hatsuda, Kouki, Fujita, Yasuhiro, Nomura, Mamiko, Moriyama, Hironobu
• Primary Examiner(s): Rickman; Holly
• Assistant Examiner(s): HARRIS, GARY D
• Application Number:
  US10/543,134
• Publication Number:
  US 20060188724A1
• Time in Patent Office: 1,610 Days
• Field of Search: 428/411, 428/520
• US Class Current: 428/522
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/4228 Leak testing of cells or batteries
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A liquid absorbing sheet includes a liquid absorbing resin layer that can effectively absorb nonaqueous electrolyte solutions used in nonaqueous electrolyte secondary cells that make nonaqueous electrolyte battery packs (in particular, lithium ion-based nonaqueous secondary battery packs). The liquid absorbing resin layer is obtained by irradiating UV-rays onto a monomer composition to polymerize the monomer composition, the monomer composition containing:

• • a monofunctional monomer component containing a monofunctional monomer capable of forming a homopolymer that is soluble in a nonaqueous solvent used in a nonaqueous electrolyte secondary battery; and
  • a polyfunctional monomer component.

Claims

1. A liquid absorbing sheet comprising a liquid absorbing resin layer, wherein the liquid absorbing resin layer is obtained by irradiating UV-rays onto a monomer composition to polymerize the monomer composition, the monomer composition containing:

a monofunctional monomer component containing a monofunctional monomer capable of forming a homopolymer that is soluble in a nonaqueous solvent used in a nonaqueous electrolyte secondary battery; and

a polyfunctional monomer component;

wherein;

the nonaqueous solvent contains at least one of dimethyl carbonate, propylene carbonate and ethylene carbonate;

the monofunctional monomer is benzyl acrylate, N-vinyl-2-pyrrolidone, imide acrylate, acryloyl morpholine, phenoxyethyl acrylate, N,N-diethylacrylamide, methoxypolyethylene glycol acrylate, tetrahydrofurfuryl acrylate, or phenoxypolyethylene glycol acrylate;

the liquid absorbing resin layer has a crosslink density of 0.0001 to 0.17;

the monofunctional monomer is contained at 20 mol % in the monofunctional monomer component; and

the polyfunctional monomer component is selected from the group consisting of hydroxyl pivalic acid neopentyl glycol diacrylate, polyethylene glycol diacrylate (ethylene oxide-added mol number (n) =14), bisphenol A diacrylate, phenyl glycidyl ether acrylate, and hexamethylene diisocyanate urethane prepolymer.

3. The liquid absorbing layer according to claim 1, further comprising a phosphate-based liquid flame retardant that is bisphenol A bis(diphenyl)phosphate, hydroquinol bis(diphenyl)phosphate, phenyl dixylenyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, trixylenyl phosphate, xylenyl diphenyl phosphate, resorcinol bis(diphenyl)phosphate, or 2-ethylhexyl diphenyl phosphate and the phosphate-based liquid flame retardant is present in the monomer composition in an amount of 70 to 200 parts by weight with respect to 100 parts by weight of the monofunctional monomer component and the polyfunctional monomer component combined.

15. A nonaqueous electrolyte battery pack comprising a nonaqueous electrolyte battery cell, a circuit board, an electrolyte-absorbing element for absorbing an electrolyte solution in the event of electrolyte leakage from the nonaqueous electrolyte battery cell, and a battery case encasing the battery cell, the circuit board and the electrolyte-absorbing element, characterized in that the electrolyte-absorbing element is formed of the liquid absorbing sheet according to claim 1.

17. The liquid absorbing sheet according to claim 1, wherein the difference between a solubility parameter value of the monofunctional monomer and a solubility parameter value of the nonaqueous solvent is in the range of -1.0 to 8.0.

18. The liquid absorbing sheet according to claim 17, wherein the nonaqueous solvent has a solubility parameter value of 17 to 28.

19. The liquid absorbing sheet according to claim 1, wherein the homopolymer dissolves in the nonaqueous solvent when 1 part by weight of the homopolymer is immersed in 30 parts by weight of the mixed solvent at room temperature for 24 hours.

20. The liquid absorbing sheet according to claim 1, wherein the liquid absorbing resin layer is formed on a substrate.

21. The liquid absorbing sheet according to claim 20, wherein the substrate is capable of absorbing and retaining the nonaqueous electrolyte solution.

22. The liquid absorbing sheet according to claim 1, wherein the monomer composition further contains a phosphate-based liquid flame retardant.

2. A liquid absorbing sheet comprising a liquid absorbing resin layer, wherein the liquid absorbing resin layer is obtained by irradiating UV-rays onto a monomer composition to polymerize the monomer composition, the monomer composition containing:

a monofunctional monomer component containing a monofunctional monomer capable of forming a homopolymer that is soluble in a nonaqueous solvent used in a nonaqueous electrolyte secondary battery; and

a polyfunctional monomer component;

wherein a phosphate-based liquid flame retardant is bisphenol A bis(diphenyl)phosphate, hydroquinol bis(diphenyl)phosphate, phenyl dixylenyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, trixylenyl phosphate, xylenyl diphenyl phosphate, resorcinol bis(diphenyl)phosphate, or 2-ethylhexyl diphenyl phosphate and the phosphate-based liquid flame retardant is present in the monomer composition in an amount of 70 to 200 parts by weight with respect to 100 parts by weight of the monofunctional monomer component and the polyfunctional monomer component combined.

4. The liquid absorbing sheet according to claim 2, wherein the difference between a solubility parameter value of the monofunctional monomer and a solubility parameter value of the nonaqueous solvent is in the range of -1.0 to 8.0.

5. The liquid absorbing sheet according to claim 4, wherein the nonaqueous solvent has a solubility parameter value of 17 to 28.

6. The liquid absorbing sheet according to claim 2, wherein the nonaqueous solvent contains at least one of dimethyl carbonate, propylene carbonate, and ethylene carbonate, and the homopolymer is obtained by adding 0.1 to 5 parts by weight of a UV-polymerization initiator per 100 parts by weight of the monofunctional monomer and irradiating UV-rays onto the mixture.

7. The liquid absorbing sheet according to claim 6, wherein the homopolymer dissolves in the nonaqueous solvent when 1 part by weight of the homopolymer is immersed in 30 parts by weight of the mixed solvent at room temperature for 24 hours.

8. The liquid absorbing sheet according to claim 2, wherein the monofunctional monomer is benzyl acrylate, N-vinyl-2-pyrrolidone, imide acrylate, acryloyl morpholine, phenoxyethyl acrylate, N,N-diethylacrylamide, methoxypolyethylene glycol acrylate, tetrahydrofurfuryl acrylate, or phenoxypolyethylene glycol acrylate.

9. The liquid absorbing sheet according to claim 2, wherein the liquid absorbing resin layer has a crosslink density of 0.0001 to 0.17.

10. The liquid absorbing sheet according to claim 2, wherein the liquid absorbing resin layer is formed on a substrate.

11. The liquid absorbing sheet according to claim 10, wherein the substrate is capable of absorbing and retaining the nonaqueous electrolyte solution.

12. The liquid absorbing sheet according to claim 2, wherein the monomer composition further contains a phosphate-based liquid flame retardant.

13. The liquid absorbing sheet according to claim 12, wherein the phosphate-based liquid flame retardant is bisphenol A bis(diphenyl)phosphate, hydroquinol bis(diphenyl)phosphate, phenyl dixylenyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, trixylenyl phosphate, xylenyl diphenyl phosphate, resorcinol bis(diphenyl)phosphate, or 2-ethylhexyl diphenyl phosphate.

14. The liquid absorbing sheet according to claim 12, wherein the phosphate-based liquid flame retardant is present in the monomer composition in an amount of 70 to 200 parts by weight with respect to 100 parts by weight of the monofunctional monomer component and the polyfunctional monomer component combined.

16. A nonaqueous electrolyte battery pack comprising a nonaqueous electrolyte battery cell, a circuit board, an electrolyte-absorbing element for absorbing an electrolyte solution in the event of electrolyte leakage from the nonaqueous electrolyte battery cell, and a battery case encasing the battery cell, the circuit board and the electrolyte-absorbing element, characterized in that the electrolyte-absorbing element is formed of the liquid absorbing sheet according to claim 2.