Apparatus and methods for producing hydrogen

• US 7,402,287 B2
• Filed: 12/17/2004
• Issued: 07/22/2008
• Est. Priority Date: 12/17/2004
• Status: Expired due to Fees

• Current Assignee: Texaco Incorporated (Chevron Corp.)
• Original Assignee: Texaco Incorporated (Chevron Corp.)
• Inventors: Sun, Hongqiao, Wheat, W. Spencer, Balasubramanian, Bhaskar, Mirkovic, Vesna R.
• Primary Examiner(s): Bhat; N.
• Application Number:
  US11/015,358
• Publication Number:
  US 20080005963A1
• Time in Patent Office: 1,313 Days
• Field of Search: 95/1, 95/16, 95/15, 95/19, 95/90, 95/96, 95/97, 48/61, 481/277, 48/76, 481/97.R, 422/191, 422/193, 422/105, 961/25
• US Class Current: 422/105
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2259/403 using three beds
• CPC Class Codes: B01D 53/0446 Means for feeding or distributing gases
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01J 2208/00637 Means for stopping or slowing down the reaction
• CPC Class Codes: B01J 2208/00646 Means for starting up the reaction
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: B01J 2219/0004 Processes in series
• CPC Class Codes: B01J 2219/00202 at the reactor outlet
• CPC Class Codes: B01J 2219/00216 Parameter value calculated by equations
• CPC Class Codes: B01J 2219/00231 at the reactor inlet
• CPC Class Codes: C01B 2203/0244 the reforming step being an autothermal reforming step, e.g. secondary reforming processes
• CPC Class Codes: C01B 2203/043 Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
• CPC Class Codes: C01B 2203/0465 Composition of the impurity
• CPC Class Codes: C01B 2203/047 the impurity being carbon monoxide
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/048 the impurity being an organic compound
• CPC Class Codes: C01B 2203/0485 the impurity being a sulfur compound
• CPC Class Codes: C01B 2203/0495 the impurity being water
• CPC Class Codes: C01B 2203/1642 Controlling the product
• CPC Class Codes: C01B 2203/169 : Controlling the feed
• CPC Class Codes: C01B 3/382 : Multi-step processes
• CPC Class Codes: C01B 3/56 : by contacting with solids; Regeneration of used solids C01B3/508 takes precedence

Abstract

An apparatus and method for producing hydrogen. The apparatus includes a fuel processor, a purification unit and a system controller. The controller determines a calculated flow of reformate from the fuel processor and operates the purification unit based on the calculated flow. The calculated flow is derived from a process model of the fuel processor and known feed(s) to the fuel processor. The calculated flow of reformate is used to control the flow of reformate to adsorbent beds within the purification unit and can be used to control other materials flows within the apparatus. Means for reducing fluctuations in the pressure and/or flow rate of reformate flowing from the fuel processor to the purification unit are also disclosed. The purity of the hydrogen produced can be maintained by adjusting the operation of the purification unit in response to changes in reformate composition, pressure and/or flow rate.

Claims

1. An apparatus for producing hydrogen comprising:

a fuel processor for producing a flow of intermediate reformate comprising hydrogen and an impurity;

a purification unit disposed downstream of the fuel processor for removing impurity from the flow of intermediate reformate to produce a flow of hydrogen-enriched reformate;

a controller for determining a calculated flow of intermediate reformate from a process model of the fuel processor and operating the purification unit in part in response to the calculated flow of intermediate reformate.

2. The apparatus of claim 1, wherein the fuel processor comprises an oxidizer and a reformer.

3. The apparatus of claim 1, wherein the purification unit comprises a plurality of adsorbent beds and a valve assembly for selectively controlling the flow of intermediate reformate to one or more of the plurality of adsorbent beds.

4. The apparatus of claim 3, wherein the plurality of adsorbent beds comprises an adsorbent material for selectively adsorbing impurity from the flow of intermediate reformate.

5. The apparatus of claim 3, wherein the purification unit comprises a variable-speed motor for creating rotation between the valve assembly and the plurality of adsorbent beds.

6. The apparatus of claim 1, further comprising a product sensor disposed downstream of the purification unit for sensing the hydrogen-enriched reformate and/or a hydrogen-depleted reformate to generate sensed product data, and wherein the controller operates the purification unit in part in response to the sensed product data.

7. The apparatus of claim 1, further comprising a product valve downstream of the purification unit for controlling the flow of hydrogen-enriched reformate out of the purification unit, the product valve comprising a variable opening valve operated in part in response to the calculated flow of intermediate reformate.

8. The apparatus of claim 1, further comprising a compression unit disposed downstream from the fuel processor, the compression unit for receiving the flow of intermediate reformate and producing a flow of compressed intermediate reformate for delivery to the purification unit.

9. The apparatus of claim 8, wherein the compression unit comprises a variable or fixed speed compressor and wherein the controller operates the purification unit independent of the speed of the compressor.

10. The apparatus of claim 8, further comprising a conduit having a variable opening valve for controlling a flow of supplemental fluid through the conduit to an inlet of the compression unit and wherein the controller operates the variable opening valve in part in response to the calculated flow of intermediate reformate.

11. The apparatus of claim 8, further comprising a sensor disposed upstream of the compression unit for sensing the pressure and/or flow rate of the intermediate reformate, and wherein the variable opening valve is operated in response to a sensed pressure and/or flow rate.

12. The apparatus of claim 11, and wherein the controller operates the purification unit in part in response to the sensed pressure and/or flow rate.

13. The apparatus of claim 1, further comprising a buffer disposed intermediate the fuel processor and purification unit for buffering the flow of intermediate reformate.

14. The apparatus of claim 1, further comprising a tank disposed downstream from the purification unit capable of receiving and storing the hydrogen-enriched reformate.

15. The apparatus of claim 1, further comprising a feed to the fuel processor comprising a fuel, air, water and mixtures thereof, and a feed sensor for sensing the feed and relaying feed data to the controller.