System and method for sensing using diamond based microelectrodes

• US 7,407,566 B2
• Filed: 08/11/2003
• Issued: 08/05/2008
• Est. Priority Date: 08/04/2003
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Jones, Timothy Gareth John, Hall, Clive Edward, Jiang, Li
• Primary Examiner(s): Olsen; Kaj K
• Application Number:
  US10/638,610
• Publication Number:
  US 20050029125A1
• Time in Patent Office: 1,821 Days
• Field of Search: 204/412, 204/406, 204/400, 204/408, 204/409, 204/410, 204/411, 204/415, 204/416, 204/421, 204/422, 204/433, 204/434, 204/280, 205/775, 205/782.5, 205/786.5, 205/787.5, 205/793, 205/794.5
• US Class Current: 204/400
• CPC Class Codes: E21B 49/082 Wire-line fluid samplers E21B49/083 takes precedence
• CPC Class Codes: G01N 27/403 Cells and electrode assemblies

Abstract

A method and system is disclosed for monitoring one or more characteristics associated with a fluid. An insulating layer comprising non-conducting diamond is positioned within a housing and has a surface exposed directly or indirectly to the fluid. A plurality of microelectrodes made of electrically conducting diamond each have a surface exposed directly or indirectly to the fluid. An electrical circuit in electrical communication with each of the microelectrodes is adapted to convert electrical signals from the microelectrodes into at least one signal associated with a characteristic being monitored. The sensing system is well suited to hydrocarbon wellbore related applications, but can also be used in other applications.

Claims

1. A sensor for monitoring one or more characteristics associated with a fluid, comprising:

a housing;

an insulating layer comprising non-conducting diamond positioned within said housing and having a surface exposed directly or indirectly to the fluid;

a plurality of microelectrodes each comprising electrically conducting diamond and having a surface exposed directly or indirectly to the fluid, wherein a thickness of each of the microelectrodes is greater than 1 mm; and

an electrical circuit in electrical communication with each of the microelectrodes adapted to convert electrical signals from the microelectrodes into at least one signal associated with a characteristic being monitored.

2. The sensor according to claim 1 wherein the size of the exposed surface of each microelectrode is less than 8000 sq. microns.

3. The sensor according to claim 2 wherein the size of the exposed surface of each microelectrode is less than 2000 sq. microns.

4. The sensor according to claim 3 wherein the size of the exposed surface of each microelectrode is less than 500 sq. microns.

5. The sensor according to claim 4 comprising at least seven microelectrodes.

6. The sensor according to claim 5 comprising at least 19 microelectrodes.

7. The sensor according to claim 6 comprising at least 50 microelectrodes.

8. The sensor according to claim 5 wherein the microelectrodes are arranged within the insulating layer such that the exposed surfaces of the microelectrodes form an irregular pattern.

9. The sensor according to claim 5 wherein a distance between two adjacent microelectrodes is at least five times the diameter of a circle having an area equal to an area of an exposed surface of each microelectrode.

10. The sensor according to claim 9 wherein the distance between two adjacent microelectrodes is at least ten times the diameter of a circle having an area equal to the area of the exposed surface of each microelectrode.

11. The sensor according to claim 4 wherein the microelectrodes are arranged within the insulating layer such that the exposed surfaces of the microelectrodes form a regular pattern.

12. The sensor according to claim 11 wherein said pattern is a hexagonal pattern.

13. The sensor according to claim 12 wherein said pattern is a square pattern.

14. The sensor according to claim 1 where the microelectrodes are positioned within the insulating layer and the exposed surface of each of the microelectrodes is co-planar with the exposed surface of the insulating layer.

15. The sensor according to claim 1 further comprising a counter electrode mounted within the housing and having a surface exposed directly or indirectly to the fluid, and wherein the microelectrodes form a working electrode.

16. The sensor according to claim 15 further comprising a reference electrode mounted within the housing and having a surface exposed directly or indirectly to the fluid flowing in the flow channel.

17. The sensor according to claim 15 further comprising a gas permeable membrane mounted between the fluid and the exposed surfaces of the insulating layer and the microelectrodes, wherein the sensor is adapted to sense characteristics associated with a gas that is allowed to pass though the membrane.

18. The sensor according to claim 1 wherein the housing is made from polyetheretherketone.

19. The sensor according to claim 1 wherein a characteristic associated with the fluid being monitored is a chemical property of the fluid.

20. The sensor according to claim 19 wherein the chemical property being monitored by the sensor is a pH of the fluid.

21. The sensor according to claim 20 wherein the exposed surface of each microelectrode is modified so as to be sensitive to pH.

22. The sensor according to claim 1 wherein a characteristic associated with the fluid being monitored is the presence of a chemical species within the fluid.

23. The sensor according to claim 22 wherein a characteristic associated with the fluid being monitored is the concentration of a chemical species within the fluid.

24. The sensor according to claim 22 wherein the chemical species is hydrogen sulphide.

25. The sensor according to claim 24 wherein the exposed surface of at least one of the microelectrodes is modified using N,N′

-dimethyl-phenylenediamine, or a structural analogue.

26. The sensor according to claim 1 wherein a characteristic associated with the fluid being monitored is the resistivity of the fluid.

27. The sensor according to claim 26 wherein the fluid is a highly resistive liquid.

28. A wellbore sensor system for monitoring fluids produced from one or more wellbores comprising the sensor according to claim 1.

29. The wellbore sensor system according to claim 28 further comprising a wellbore fluids sampling tool, wherein the sensor is mounted within the sampling tool.

30. The wellbore sensor system according to claim 29 wherein the sampling tool is adapted to sample wellbore fluids in open hole sections of a wellbore.

31. The wellbore sensor system according to claim 29 wherein the sampling tool is adapted to sample wellbore fluids in cased hole sections of a wellbore.

32. The wellbore sensor system according to claim 29 further comprising a production logging tool, wherein the sensor is mounted on a portion of the production logging tool.

33. The wellbore sensor system according to claim 28 further comprising a subassembly for sensing characteristics within a wellbore during the drilling process, wherein the sensor is mounted with the subassembly which is adapted to be part of a bottom hole assembly.

34. The wellbore sensor system according to claim 28 wherein the one or more wellbores are drilled in a water reservoir.

35. The wellbore sensor system according to claim 28 wherein the one or more wellbores are used for CO2 sequestration, and the sensor is used to monitor pH.

36. The wellbore sensor system according to claim 28 wherein the sensor is coupled with a conduit through which the produced fluids flow.