Bio-battery

• US 7,410,709 B2
• Filed: 06/24/2004
• Issued: 08/12/2008
• Est. Priority Date: 06/24/2004
• Status: Expired due to Fees

• Current Assignee: Purdue Research Foundation (The Trustees of Purdue University (d/b/a Purdue University))
• Original Assignee: Purdue Research Foundation (The Trustees of Purdue University (d/b/a Purdue University))
• Inventors: Mosier, Nathan S., Ladisch, Michael R., Perkins, Eric M.
• Primary Examiner(s): Ryan; Patrick
• Assistant Examiner(s): Lee; Cynthia K.
• Application Number:
  US10/875,990
• Publication Number:
  US 20050287399A1
• Time in Patent Office: 1,510 Days
• Field of Search: 429/2
• US Class Current: 429/2
• CPC Class Codes: H01M 8/08 Fuel cells with aqueous electrolytes
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1023 having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
• CPC Class Codes: H01M 8/1039 halogenated, e.g. sulfonated polyvinylidene fluorides
• CPC Class Codes: H01M 8/16 Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
• CPC Class Codes: H01M 8/18 Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A bio-battery includes a biomolecular energy source, a first electrode and a second electrode. In some configurations, a bio-battery may also include a first cell containing the first electrode and the biomolecular energy source, and a second cell having a reducible substrate and the second electrode. The first cell can be in ionic communication with the second cell, for example by a proton exchange membrane. Various biomolecular energy sources can be used, including proton donor molecules or electrolytically oxidizable molecules. For example, the biomolecular energy source can be selected from the group consisting of Nicotinamide Adenine Dinucleotide (NADH), Nicotinamide Adenine Dinucleotide Phosphate (NADPH) and 5,10-Methylenetetrahydrofolate Reductase (FADH).

Claims

1. A bio-battery comprising:

a first cell having a biomolecular energy source including a biomolecule, and a first electrode; and

a second cell having a reducible substrate and a second electrode,

where the biomolecular energy source is in ionic communication with the reducible substrate,

the first electrode is in contact with the biomolecular energy source, and

the second electrode is in contact with the reducible substrate;

wherein the addition of an ionic transport medium to the first cell generates an electrical potential between the first electrode and the second electrode in the absence of an enzyme in the first cell.

2. The bio-battery of claim 1, where the biomolecule is selected from the group consisting of NADH, NADPH and FADH.

3. The bio-battery of claim 1, where the biomolecule is NADH.

4. The bio-battery of claim 1, where the first cell comprises an ion transport medium.

5. The bio-battery of claim 1, further comprising a proton exchange membrane between the first cell and the second cell.

6. The bio-battery of claim 1, where the first electrode is an anode and the second electrode is a cathode.

7. The bio-battery of claim 1, where the reducible substrate comprises oxygen.

8. A bio-battery comprising:

a first cell having a biomolecular energy source and a carbon anode; and

a second cell containing oxygen and a platinum cathode,

where the first cell is separated from the second cell by a proton exchange membrane,

the carbon anode is in oxidizing contact with the biomolecular energy source,

the platinum cathode is in reducing contact with the oxygen, and

the biomolecular energy source is a biomolecule selected from the group consisting of NADH, NADPH and FADH;

wherein the addition of an ionic transport medium to the first cell generates an electrical potential between the first electrode and the second electrode in the absence of an enzyme in the first cell.

9. A bio-battery comprising:

a first cell having a biomolecular energy source, an ion transport medium and a carbon anode in oxidizing contact with the biomolecular energy source; and

a second cell containing oxygen and a platinum cathode in reducing contact with the oxygen,

where the first cell is separated from the second cell by a proton exchange membrane,

and

the biomolecular energy source is a biomolecule selected from the group consisting of NADH, NADPH and FADH;

wherein the first cell generates an electrical potential between the first electrode and the second electrode in the absence of an enzyme in the first cell.

10. A bio-battery comprising:

a first cell having a biomolecular energy source and an anode; and

a second cell containing oxygen and a gold cathode,

where the first cell is separated from the second cell by a proton exchange membrane,

the anode is in oxidizing contact with the biomolecular energy source,

the gold cathode is in reducing contact with the oxygen, and

the biomolecular energy source is an electrolytically oxidizable biomolecule selected from the group consisting of NADH, NADPH and FADH;

wherein the addition of an ionic transport medium to the first cell generates an electrical potential between the first electrode and the second electrode in the absence of an enzyme in the first cell.

11. A bio-battery kit comprising:

a biomolecular energy source including a biomolecule, a first electrode and a second electrode;

wherein the introduction of an ion transport medium in contact with the first electrode generates an electrical potential between the first electrode and the second electrode in the absence of an enzyme when the first electrode is in ionic communication with the second electrode.

12. The bio-battery kit of claim 11, comprising a lyophilized biomolecular energy source.

13. The bio-battery kit of claim 11, further comprising a first cell including the first electrode and a second cell including the second electrode.

14. The bio-battery kit of claim 13, where the first cell comprises a biomolecular energy source.

15. The bio-battery kit of claim 13, further comprising a proton exchange membrane separating the first cell and the second cell.

16. The bio-battery kit of claim 11, further comprising an agent that promotes the biodegradation of the bio-battery after disposal.