Electrically switchable polymer-dispersed liquid crystal materials

• US 7,413,678 B1
• Filed: 04/03/2006
• Issued: 08/19/2008
• Est. Priority Date: 07/29/1998
• Status: Expired due to Fees

• Current Assignee: Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Tondiglia, Vince P., Sutherland, Richard L., Natarajan, Lalgudi V., Bunning, Timothy J.
• Primary Examiner(s): WU, SHEAN CHIU
• Application Number:
  US11/395,161
• Time in Patent Office: 869 Days
• Field of Search: 428/1.1, 252/299.01, 430/2, 430/20, 359/15, 385/15, 385/16
• US Class Current: 252/299.01
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: G02B 5/32 Holograms used as optical elements
• CPC Class Codes: G02B 6/2713 cascade of polarisation selective or adjusting operations
• CPC Class Codes: G02B 6/2931 Diffractive element operating in reflection
• CPC Class Codes: G02B 6/29311 Diffractive element operating in transmission
• CPC Class Codes: G02B 6/29314 by moving or modifying the diffractive element, e.g. deforming
• CPC Class Codes: G02B 6/29395 configurable, e.g. tunable or reconfigurable switching G02B6/35
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G02F 2201/305 diffraction grating
• CPC Class Codes: G03H 1/0005 Adaptation of holography to specific applications holographic optical element G02B5/32; holographic scanner G02B26/106; recognition using holographic mask G06V10/88; holographic memories G11B7/0065, G11C13/042
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 1/0248 Volume holograms
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2001/0264 Organic recording material
• CPC Class Codes: G03H 2001/2615 in physical contact, i.e. layered holograms
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound

Abstract

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains.

Claims

1. A method for forming a hologram, the method comprising the steps of:

providing a mixture comprising a polymerizable monomer and a second phase material;

inducing photopolymerization by illuminating the mixture with a light pattern; and

modulating a dielectric constant of the mixture.

2. The method of claim 1, wherein the mixture further comprises a photoinitiator dye.

3. The method of claim 1, wherein the mixture further comprises a coinitiator.

4. The method of claim 1, wherein the mixture further comprises a chain extender or a cross-linker.

5. The method of claim 1, wherein the mixture further comprises a surfactant.

6. The method of claim 1, wherein the polymerizable monomer comprises at least one of a di-, tri-, tetra-, and pentaacrylates.

7. The method of claim 1, wherein the polymerizable monomer comprises a mixture of urethane acrylates with functionalities 3, 4, 5, and 6.

8. The method of claim 6, wherein the polymerizable monomer is at least one acrylate selected from the group consisting of triethyleneglycol diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, pentaerythritol tetracrylate, and dipentaerythritol pentaacrylate.

9. The method of claim 6, wherein the polymerizable monomer is at least one acrylate selected from the group consisting of urethane acrylates with functionalities 3, 4, 5, and 6.

10. The method of claim 1, wherein the second phase material is selected from the group consisting of a mixture of cyanobiphenyls, 4′

-n-pentyl-4-cyanobiphenyl, 4′

-n-heptyl-4-cyanobiphenyl, 4′

-octaoxy-4-cyanobiphenyl, 4′

-pentyl-4-cyanoterphenyl, and α

-methoxybenzylidene-4′

-butylaniline, or the class of fluoro and chloro substituted biphenyls and triphenyls.

11. The method of claim 4, wherein the chain extender is at least one member selected from the group consisting of N-vinyl pyrrolidone;

N-vinyl pyridine, acrylonitrile, and N-vinyl carbazole.

12. The method of claim 3, wherein the coinitiator is at least one member selected from the group consisting of N-phenylglycine, triethylene amine, triethanolamine, N,N-dimethyl-2,6-diisopropyl aniline, halogenated N-phenylglycine, 3,3,4,4′

-tetrakis(t-butyl peroxy carbonyl)-benzophenone, trimethylfuran, and triaayl alkyl borate salt.

13. The method of claim 2, wherein the photoinitiator dye is at least one member selected from the group consisting of rose bengal ester, rose bengal sodium salt, eosin, eosin sodium salt, 4,5-diiodosuccinyl fluorescein, camphorquinone, methylene blue, cationic cyanine dyes with trialkylborate anions, merocyanine dyes derived from spiropyran, benzophenone, 2,2-dimethyl-2 hydroxyacetophenone, diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide, 2-benzyl-2-dimethylamino-1-(4-monopholinophenyl)-butan-1-one, bis(pentafluorophenyl)titanocene, metallo-benzoporphyrins, 3-substituted keto coumarin dye, thioxanthene dye, and diphenyl iodonium salts.

14. The method of claim 1, wherein the light pattern is obtained from at least four beams of coherent light.

15. The method of claim 5, wherein the surfactant is selected from the group consisting of octanoic acid, decanoic acid and dodecanoic acid.

16. The method of claim 1, wherein the polymerizable monomer comprises dipentaerythritol pentaacrylate, second phase material comprises the at least one liquid crystal comprising cyanobiphenyls the mixture further comprises, the chain-extending monomer being N-vinyl pyrrolidone, the coinitiator being N-phenylglycine, and the photoinitiator being rose bengal sodium salt.

17. A method for making an anisotropic spatial distribution of phase-separated liquid crystal droplets within a photochemically cured polymer matrix, the method comprising the steps of:

disposing between at least two optically transparent electrode plates, a mixture that comprises, before exposure;

(a) a polymerizable monomer comprising multifunctional aliphatic and aromatic thiols;

(b) an allyl ether or multifunctional acrylate;

(c) a liquid crystal; and

(d) a photoinitiator; and

exposing this mixture to light in an interference pattern.

18. The method of claim 17, wherein the liquid crystal droplets separate at crystal lattice or interstitial points within the polymer matrix.

19. The method of claim 17, wherein the liquid crystal droplets are up to approximately 50 nm in diameter.