Optimized LNG system with liquid expander

• US 7,415,840 B2
• Filed: 11/18/2005
• Issued: 08/26/2008
• Est. Priority Date: 11/18/2005
• Status: Active Grant

• Current Assignee: Conocophillips Company (ConocoPhillips)
• Original Assignee: Conocophillips Company (ConocoPhillips)
• Inventors: Eaton, Anthony P., Qualls, Wesley R.
• Primary Examiner(s): Doerrler; William C
• Application Number:
  US11/283,475
• Publication Number:
  US 20070113584A1
• Time in Patent Office: 1,012 Days
• Field of Search: 626/11, 626/12
• US Class Current: 62/611
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0057 after expansion of the liquid refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0085 Ethane; Ethylene
• CPC Class Codes: F25J 1/0087 Propane; Propylene
• CPC Class Codes: F25J 1/021 using a deep flash recycle loop
• CPC Class Codes: F25J 1/0284 Electrical motor as the prime mechanical driver
• CPC Class Codes: F25J 1/0285 Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
• CPC Class Codes: F25J 1/0287 including an electrical motor
• CPC Class Codes: F25J 1/0292 Refrigerant compression by cold or cryogenic suction of the refrigerant gas
• CPC Class Codes: F25J 1/0294 Multiple compressor casings/strings in parallel, e.g. split arrangement
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream

Abstract

A process and apparatus for the liquefaction of natural gas including at least one liquid expander for providing expansion of a high-pressure stream and powering a generator capable of producing electricity to be used to drive a compressor located elsewhere in the liquefaction apparatus. Particularly, a liquid expander is used to expand a high-pressure refrigerant stream and to power an electrical generator. The electricity provided by the generator can be used to power a compressor located in the same or a different refrigeration cycle as the liquid expander.

Claims

1. A method of liquefying a natural gas stream in an LNG facility, said method comprising:

(a) cooling at least a portion of said natural gas stream in an upstream refrigeration cycle via indirect heat exchange with an upstream refrigerant to thereby provide a cooled natural gas stream;

(b) separating at least a portion of said cooled natural gas stream into a predominantly methane vapor overhead fraction and a predominantly liquid bottoms fraction in a first distillation column;

(c) cooling at least a portion of said predominantly methane vapor overhead fraction in a second refrigeration cycle via indirect heat exchange with a second refrigerant to thereby provide a cooled predominantly methane stream;

(d) passing at least a portion of said cooled predominantly methane stream through a first expander to generate work and to thereby provide a first expanded predominantly methane stream;

(e) separating at least a portion of said first expanded predominantly methane stream in a first separation vessel to thereby provide a first vapor stream and a first liquid stream;

(f)

(g) converting at least a portion of the work generated by said first expander into electricity; and

(h) using the electricity generated in step (g) to power a first compressor, wherein said first compressor is used to compress at least a portion of said first vapor stream.

2. The method according to claim 1, said LNG facility comprising a plurality of cascaded refrigeration cycles.

3. The method according to claim 2, said first compressor being located in the same refrigeration cycle as the first.

4. The method according to claim 2, said first refrigerant comprising a pure component refrigerant, said pure component refrigerant comprising predominantly propane, predominantly ethylene, predominantly ethane, or propylene.

5. The method according to claim 1;

and

(i) further compressing said at least a portion of said first vapor stream compressed by said first compressor with a second compressor downstream of the first compressor.

17. The method according to claim 1, further comprising, subsequent to step (e), cooling at least a portion of said first liquid stream to thereby provide a cooled liquid stream and, thereafter, passing at least a portion of said cooled liquid stream through a second expander to generate work, wherein at least a portion of the work generated from the second expander is converted to electricity and used to power said first compressor.

18. The method according to claim 1, wherein said second refrigerant comprises at least a portion of said first vapor stream.

19. The method of according to claim 1, wherein said second refrigerant comprises a pure component ethane refrigerant, a pure component ethylene refrigerant, or a predominantly methane refrigerant.

6. A method of liquefying a natural gas stream in a liquefied natural gas (LNG) facility, said method comprising:

(a) discharging a first compressed refrigerant stream from a first refrigerant compressor in a first upstream refrigeration cycle;

(b) using at Least a portion of said first compressed refrigerant stream to cool at least a portion of a predominantly methane stream to thereby provide a cooled predominantly methane stream and a first warmed refrigerant stream;

(c) discharging a second compressed refrigerant stream from a second refrigerant compressor in a second refrigeration cycle;

(d) using at least a portion of said second compressed refrigerant stream to cool at least a portion of said cooled predominantly methane stream to thereby provide a further cooled predominantly methane stream and a second warmed refrigerant stream;

(e) expanding at least a portion of said further cooled predominantly methane stream in a first expander to thereby provide an expanded predominantly methane stream;

(f) separating said expanded predominantly methane stream into a predominantly vapor fraction and a predominantly liquid fraction in a first separation vessel, wherein said second compressed refrigerant stream comprises said predominantly vapor fraction;

(g) passing at least a portion of said first compressed refrigerant stream and/or said second compressed refrigerant stream through a second and/or third expander prior to said cooling of steps (b) and/or (d) to generate work;

(h) converting at least a portion of the work generated by said second and/or third expander into electricity; and

(i) using the electricity generated in step (h) to power said first and/or said second refrigerant compressor and/or a booster compressor used to compress said first and/or said second warmed refrigerant streams before said first and/or second refrigerant streams are introduced into said first and/or said second refrigerant compressors.

7. The method according to claim 6, said LNG facility comprising a plurality of cascaded refrigeration cycles.

8. The method according to claim 6, said first refrigerant comprising a pure component refrigerant, wherein said pure component refrigerant comprises predominantly propane, predominantly ethylene, predominantly ethane, or predominantly propylene.

9. The method according to claim 6;

and

(j) controlling the flow of said first and/or said second compressed refrigerant stream through said second and/or said third expander by selectively opening or closing a by-pass valve.

10. The method according to claim 9, said by-pass valve comprising an expansion valve.

11. An apparatus for liquefying a natural gas stream, said apparatus comprising:

(a) a first refrigeration cycle comprising a first heat exchanger, said first heat exchanger comprising a first warm natural gas inlet, a first cool natural gas outlet, a first cool refrigerant inlet, and a first warm refrigerant outlet;

(b) a first distillation column located downstream of said first refrigeration cycle, said first distillation column comprising a first fluid inlet, a first vapor outlet, and a first liquid outlet, said first fluid inlet in fluid flow communication with said first cool natural gas outlet of said first refrigeration cycle;

(c) a second refrigeration cycle comprising a second heat exchanger, a third heat exchanger,

a first expander mechanically coupled with a first generator, and

a second expander mechanically coupled with a second generator; and

(d) a compressor mechanically coupled with a motor powered with electricity supplied by said first and second generators,

wherein said second and third heat exchangers respectively comprise second and third warm natural gas inlets and second and third cool natural gas outlets, wherein said second warm natural gas inlet of said second heat exchanger is in fluid flow communication with said first vapor outlet of said first distillation column;

wherein said first expander is fluidly disposed upstream of said second heat exchanger generally between said first vapor outlet of said first distillation column and said second warm natural gas inlet of said second heat exchanger,

wherein said second expander is fluidly disposed between said cool natural gas outlet of said second heat exchanger and said third warm natural gas inlet of said third heat exchanger.

12. The apparatus according to claim 11, said compressor located in the first refrigeration cycle.

13. The apparatus according to claim 11, said compressor located in said second refrigeration cycle.

14. The apparatus according to claim 11;

and

a first by-pass valve positioned in parallel with the first expander; and

a second by-pass valve positioned in parallel with the second expander.

15. The apparatus according to claim 14, said first and second by-pass valves operable to control the flow of the pressurized streams through the first and second liquid expanders.

16. The apparatus according to claim 14, said first and second by-pass valves being expansion valves.