Method of deacidizing a gas with a fractional regeneration absorbent solution

• US 7,419,646 B2
• Filed: 11/02/2005
• Issued: 09/02/2008
• Est. Priority Date: 11/12/2004
• Status: Active Grant

• Current Assignee: Institut Francais Du Petrole
• Original Assignee: Institut Francais Du Petrole
• Inventors: Cadours, Renaud, Mougin, Pascal, Carrette, Pierre-Louis, Boucot, Pierre
• Primary Examiner(s): Vanoy; Timothy C
• Application Number:
  US11/264,040
• Publication Number:
  US 20060104877A1
• Time in Patent Office: 1,035 Days
• Field of Search: 423/220, 423/226, 423/228, 423/242.1, 423/242.2, 423/242.3, 423/242.7, 423/243.01, 423/243.08, 423/243.11
• US Class Current: 423/220
• CPC Class Codes: B01D 2252/103 Water
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/48 Sulfur compounds
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/75 Multi-step processes
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The gaseous effluent flowing in through line 1 is contacted in absorption zone ZA with the liquid absorbent solution flowing in through line 9. The gaseous effluent depleted in acid compounds is discharged through line 2. The absorbent solution laden with acid compounds is discharged through line 3. The absorbent solution once laden with acid compounds comprises two phases: a first phase poor in acid compounds and a second phase rich in acid compounds. The two phases are separated in zone ZS. The first phase is recycled through lines 5 and 9 to absorption zone ZA. The second phase is fed through line 4 into regeneration zone ZR. In zone ZR, the acid compounds are separated from the absorbent solution. The acid compounds are discharged through line 7. The regenerated absorbent solution is recycled through lines 6 and 9 to zone ZA.

Claims

1. A method of deacidizing a gaseous effluent comprising at least one acid compound of the group consisting of hydrogen sulfide (H₂S), mercaptans, carbon dioxide (CO₂), sulfur dioxide (SO₂), carbon oxysulfide (COS) and carbon disulfide (CS₂), wherein the following stages are carried out:

a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds,

b) separating the absorbent solution laden with acid compounds into two fractions;

a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds,

c) regenerating the second fraction so as to release part of the acid compounds,

d) recycling the first absorbent solution fraction obtained in stage b) and the regenerated absorbent solution obtained in stage c) as the absorbent solution to stage a).

2. A method as claimed in claim 1, wherein the absorbent solution comprises a compound that reacts with at least one of said acid compounds, the reactive compound being selected from the group consisting of amines, alkanolamines, amino-acids, amino-acid alkaline salts, amides, ureas, alkaline metal phosphates, carbonates and borates.

3. A method as claimed in claim 2, wherein the absorbent solution comprises a solvation compound selected from the group consisting of water, glycols, polyethylene glycols, polypropylene glycols, ethylene glycol-propylene glycol copolymers, glycol ethers, alcohols, ureas, lactames, N-alkylated pyrrolidones, N-alkylated piperidones, cyclotetramethylene sulfones, N-alkylformamides, N-alkylacetamides, ether-ketones, alkyl phosphates and derivatives thereof.

4. A method as claimed in claim 2, wherein the absorbent solution comprises a salt selected from the group consisting of alkaline salts, alkaline-earth salts, metal salts and amine salts.

5. A method as claimed in claim 1, wherein, in stage b), one of the following separation techniques is used:

decantation, centrifugation, filtration.

6. A method as claimed in claim 1, wherein, in stage c), the second absorbent solution fraction is distilled so as to produce a regenerated absorbent solution depleted in acid compounds by releasing acid compounds in gaseous form.

7. A method as claimed in claim 1, wherein, in stage c), the second fraction is expanded so as to produce a liquid by releasing acid compounds in gaseous form, then the acid compounds released are discharged and the liquid is separated into a first regenerated absorbent solution portion that is depleted in acid compounds and a third absorbent solution fraction.

8. A method as claimed in claim 7, wherein the third absorbent solution fraction is expanded so as to produce a second regenerated absorbent solution portion depleted in acid compounds and acid compounds released in gaseous form by expansion.

9. A method as claimed in claim 7, wherein the third absorbent solution fraction is distilled so as to produce a second regenerated absorbent solution portion depleted in acid compounds by releasing acid compounds in gaseous form.

10. A method as claimed in claim 1, wherein the gaseous effluent is selected from the group consisting of natural gas, synthesis gas, combustion fumes, refinery gas, Claus tail gas, biomass fermentation gas.

11. A method as claimed in claim 1, applied to the absorption of carbon dioxide present in combustion fumes or natural gas, to the treatment of Claus tail gas or to the desulfurization of natural gas and of refinery gas, wherein an absorbent solution comprising one of the following reactive compound/solvation compound pairs is used:

N,N,N′

,N′

,N″

-pentamethyldiethylenetriamine/water, N,N,N′

,N′

,N″

-pentamethyldipropylenetriamine/water, N,N-Bis(2,2-diethoxyethyl)methyl amine/water, N,N-dimethyldipropylenetriamine/tetraethyleneglycol dimethylether and N,N-dimethyl-dipropylenetriamine/water.

12. A method of deacidizing a gaseous effluent comprising at least one acid compound of the group consisting of hydrogen sulfide (H2S), mercaptans, carbon dioxide (CO2), sulfur dioxide (SO2), carbon oxysulfide (COS) and carbon disulfide (CS2), wherein the following stages are carried out:

a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds,

b) separating the absorbent solution laden with acid compounds into two fractions;

a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds,

c) regenerating the second fraction so as to release part of the acid compounds,

d) recycling the first absorbent solution fraction obtained in stage b) and the regenerated absorbent solution obtained in stage c) as absorbent solution to stage a).

13. A method as claimed in claim 12, wherein the first absorbent solution fraction obtained in stage b), the regenerated absorbent solution obtained in stage c) and a makeup absorbent solution are used as the absorbent solution to stage a).

14. A method as claimed in claim 13, wherein the makeup absorbent solution replaces absorbent solution lost in stage c).