Apparatus and method for producing biodiesel fuel
First Claim
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1. A process for the production of biodiesel grade, fatty acid alkyl esters comprising:
- (a) reacting triglyceride, alcohol and catalyst in a first reaction zone to form a first intermediate reacted mixture which includes trans-esterified fatty acid ester product, glycerol, unreacted alcohol, and unreacted and partially reacted triglyceride;
(b) removing glycerol and unreacted alcohol from the first intermediate reacted mixture to form a second intermediate reacted mixture;
(c) feeding the second intermediate reacted mixture to a second reaction zone;
(d) adding a fresh feed of alcohol and catalyst into the second reaction zone to form fatty acid alkyl esters and glycerol from the second intermediate reacted mixture to form a third intermediate reacted mixture;
(e) separating alcohol, glycerol and a fraction of the fatty acid alkyl esters from the third intermediate reacted mixture to produce a recycle stream; and
(f) recycling alcohol, glycerol and fatty acid alkyl esters recovered from said recycle stream from the third intermediate reacted mixture to the first reaction zone in an amount sufficient to act as a co-solvent of the reaction process, and further, wherein said recycle stream includes at least 20% by volume of alkyl ester.
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Abstract
A continuous method and apparatus for making biodiesel fuel from glycerides such as vegetable oil employs a two-stage reactor provided with recycle. Yields of 95% and greater are readily achieved in a continuous mode of operation.
42 Citations
19 Claims
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1. A process for the production of biodiesel grade, fatty acid alkyl esters comprising:
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(a) reacting triglyceride, alcohol and catalyst in a first reaction zone to form a first intermediate reacted mixture which includes trans-esterified fatty acid ester product, glycerol, unreacted alcohol, and unreacted and partially reacted triglyceride; (b) removing glycerol and unreacted alcohol from the first intermediate reacted mixture to form a second intermediate reacted mixture; (c) feeding the second intermediate reacted mixture to a second reaction zone; (d) adding a fresh feed of alcohol and catalyst into the second reaction zone to form fatty acid alkyl esters and glycerol from the second intermediate reacted mixture to form a third intermediate reacted mixture; (e) separating alcohol, glycerol and a fraction of the fatty acid alkyl esters from the third intermediate reacted mixture to produce a recycle stream; and (f) recycling alcohol, glycerol and fatty acid alkyl esters recovered from said recycle stream from the third intermediate reacted mixture to the first reaction zone in an amount sufficient to act as a co-solvent of the reaction process, and further, wherein said recycle stream includes at least 20% by volume of alkyl ester. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
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16. A process for the production of biodiesel fuel fatty acid alkyl esters comprising:
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(a) feeding a fatty acid triglyceride, an alkanol and catalyst to a first tubular reaction zone; (b) transesterifying the fatty acid triglyceride in the first tubular reaction zone to produce a first intermediate stream comprising fatty acid alkyl ester and glycerol; (c) removing glycerol from said first intermediate stream to produce a second intermediate stream; (d) feeding the second intermediate stream along with additional catalyst and additional alkanol to a second tubular reaction zone; (e) transesterifying fatty acid triglyceride to produce fatty acid alkyl ester in said second tubular reaction zone to produce a third intermediate stream; (f) separating the third intermediate stream into a crude product stream and an alkyl ester containing recycle stream; and (g) recycling in an amount sufficient to act as a co-solvent for the reaction process, the recycle stream to the first reaction zone, wherein the overall conversion of triglyceride to fatty acid alkyl ester in the process is greater than 95%, and wherein said recycle stream includes at least 20% by volume of alkyl ester. - View Dependent Claims (17, 18, 19)
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Specification