Configurations and methods of acid gas removal

• US 7,424,808 B2
• Filed: 09/17/2002
• Issued: 09/16/2008
• Est. Priority Date: 09/17/2002
• Status: Expired due to Term

• Current Assignee: Fluor Enterprises Incorporated (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Mak, John
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US10/526,817
• Publication Number:
  US 20060110300A1
• Time in Patent Office: 2,191 Days
• Field of Search: 62/512, 626/25, 626/32, 626/34, 962/43, 962/34, 951/56, 951/87, 952/23, 952/35, 952/36, 423/220
• US Class Current: 62/625
• CPC Class Codes: B01D 2259/652 using side coolers
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A plant includes an absorber (105) that receives a feed gas (10) at a pressure of at least 400 psig and comprising at least 5 mol % carbon dioxide, wherein the absorber (105) is operated at an isothermal or decreasing top-to-bottom thermal gradient, and wherein the absorber (105) employs a physical solvent to at least partially remove an acid gas from the feed gas (10). Such configuration advantageously provide cooling (108) by expansion of the rich solvent (21) generated in the absorber (105), wherein both a semi-rich solvent (13) generated and recycled to the absorber (105) and the feed gas (10) are cooled by expansion of the rich solvent (21).

Claims

1. A method of removing an acid gas from a feed gas comprising:

feeding into an absorber the feed gas at a pressure of at least 400 psig, wherein the feed gas comprises at least 5 mol % carbon dioxide, wherein the absorber is operated at an isothermal or decreasing top-to-bottom thermal gradient,

wherein the absorber employs a physical solvent to at least partially remove an acid gas from the feed gas to thereby produce an absorber overhead product, a semi-rich solvent, and a rich solvent;

cooling the semi-rich solvent using refrigeration content of at least partially expanded rich solvent; and

cooling the feed gas using refrigeration content of the at least partially expanded rich solvent and the absorber overhead product.

2. The method of claim 1 wherein the rich solvent is expanded in at least two steps, wherein expansion in one step produces work, and wherein expansion in another step provides refrigeration for the semi-rich solvent and optionally a carbon dioxide product.

3. The method of claim 1 wherein the rich solvent is expanded in at least three steps, wherein expansion in the at least three steps produces at least three recycle streams, respectively, and wherein the at least three recycle streams are fed into the absorber.

4. The method of claim 3 wherein the at least three recycle streams are compressed to form a compressed recycle stream, and wherein further refrigeration is provided by Joule-Thomson cooling of compressed recycle stream.

5. The method of claim 1 wherein the feed gas is cooled by the at least partially expanded rich solvent.

6. The method of claim 5 wherein the feed gas is further cooled by the absorber overhead product.

7. The method of claim 1 wherein at least part of the acid gas is removed from the physical solvent at a pressure of between about 1 psia to 10 psia.

8. The method of claim 1 wherein the feed gas has a pressure between about 400 psig to about 3000 psig, and wherein the feed gas is at least partially dehydrated.

9. The method of claim 1 wherein the feed gas has an acid gas content of between about 10 mol % to about 75 mol %.

10. The method of claim 1 wherein the feed gas comprises natural gas.

11. The method of claim 1 wherein the absorber is operated at a bottom temperature of about −

25°

F. to about −

45°

F.

12. The method of claim 1 wherein the rich solvent is expanded to provide refrigeration for a carbon dioxide product.

13. The method of claim 1 wherein the feed gas has a pressure of at least 1000 psig, and wherein at least a portion of the acid gas in the feed gas is removed from the feed gas using a membrane separator.

20. The method of claim 1 further comprising a conduit fluidly coupled to a recycle gas cooler to allow withdrawal of a hydrocarbon liquid stream as a liquid product from the recycle gas.

14. A plant comprising:

a gas source that is configured to provide natural gas comprising at least 5 mol % acid gas at a pressure of at least 400 psig;

an absorber fluidly coupled to the gas source and configured to receive the natural gas and further configured to form a semi-rich solvent from a physical solvent;

a cooler fluidly coupled to the absorber and configured to cool the semi-rich solvent and to provide the cooled semi-rich solvent back to the absorber at a temperature suitable to absorb at least another portion of the acid gas to thereby allow formation of a rich solvent in the absorber;

first and second expansion devices fluidly coupled to the absorber and further fluidly coupled to respective first and second heat exchangers, wherein the first and second expansion devices and heat exchangers are configured to allow cooling of the the natural gas and the semi-rich solvent in the first and second heat exchangers, respectively, by expansion of the rich solvent; and

wherein the first and second expansion devices and heat exchangers are further configured to allow operation of the absorber with an isothermal or decreasing top-to-bottom thermal gradient.

15. The plant of claim 14 wherein the first and second heat exchangers are configured such that cooling of the natural gas and the semi-rich solvent provides an isothermal or decreasing top-to-bottom thermal gradient in the absorber.

16. The plant of claim 14 wherein the first and second expansion devices are configured to allow formation of at least one hydrocarbon containing recycle stream from the rich solvent, and further comprising a recycle compressor that is configured to receive and compress the recycle stream to a pressure suitable for feeding the recycle stream back to the absorber.

17. The plant of claim 16 further comprising a JT valve that is coupled to the recycle compressor and configured to expand the compressed recycle stream to thereby provide refrigeration to the compressed recycle stream.

18. The plant of claim 16 further comprising a vacuum stripper that is configured to strip the solvent at a pressure of about 1 psia to about 10 psia to thereby produce a lean solvent.

19. The plant of claim 14 wherein the gas source is configured to provide the natural gas at a pressure of at least about 1000 psig, and further comprising a membrane separator that is coupled to the gas source and configured to allow removal of at least a portion of the acid gas in the natural gas.

21. The plant of claim 14 further comprising a third expansion device that is configured to receive the rich solvent and to allow for production of at least one of work and refrigeration for a carbon dioxide product.