High-impact, transparent, distortion-free polymeric sheet and windshield

• US 7,425,369 B2
• Filed: 11/20/2002
• Issued: 09/16/2008
• Est. Priority Date: 08/13/2001
• Status: Active Grant

• Current Assignee: Clear Armor, LLC, PH Realty, LLC
• Original Assignee: Edwin J. Oakey, Rodney M. Tinney
• Inventors: Tinney, Rodney M, Oakey, Edwin J
• Primary Examiner(s): Chaney; Carol
• Assistant Examiner(s): ROBINSON, ELIZABETH A
• Application Number:
  US10/300,329
• Publication Number:
  US 20030071381A1
• Time in Patent Office: 2,127 Days
• Field of Search: 269/190.1, 269/84.1, 428/412, 425/388
• US Class Current: 428/412
• CPC Class Codes: B29C 2035/1658 using gas
• CPC Class Codes: B29C 2791/006 Using vacuum
• CPC Class Codes: B29C 2791/007 Using fluid under pressure
• CPC Class Codes: B29C 2793/00 Shaping techniques involving a cutting or machining operation
• CPC Class Codes: B29C 51/008 without using a mould, e.g. ballooning as prestretching step B29C51/06
• CPC Class Codes: B29C 51/04 Combined thermoforming and prestretching, e.g. biaxial stretching
• CPC Class Codes: B29C 51/082 by shaping between complementary mould parts
• CPC Class Codes: B29C 51/10 Forming by pressure difference, e.g. vacuum
• CPC Class Codes: B29C 51/262 Clamping means for the sheets, e.g. clamping frames
• CPC Class Codes: B29C 51/32 having cutting means
• CPC Class Codes: B29C 51/421 of preforms, specially adapted for thermoforming preheating sheets in general B29B13/023; B29C51/427 takes precedence
• CPC Class Codes: B29C 51/427 Cooling of the material with a fluid blast
• CPC Class Codes: B29C 51/428 of moulds or mould parts
• CPC Class Codes: B29C 51/46 Measuring, controlling or regulating
• CPC Class Codes: B29K 2033/08 Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
• CPC Class Codes: B29K 2069/00 Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

A base sheet of transparent polycarbonate material has a formed shape including a center portion and a peripheral portion. The center portion is formed by a non-contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the transparent polycarbonate material, thereby resulting in the center portion of the base sheet being free of visual distortion. A top coat layer is disposed over the base sheet. The top coat layer has a greater resistance to abrasion than the polycarbonate material and provides UV protection to the base sheet. A primer coating is disposed between the base sheet and the top coat layer to facilitate bonding therebetween. The peripheral portion can have a shape created by a contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the polycarbonate material.

Claims

1. A high-impact, transparent sheet comprising:

a base sheet of transparent polycarbonate material having a glass transition temperature and a melt temperature, the base sheet having a non-planar shape comprising a first portion and a second portion;

wherein the first portion has a shape created by a non-contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the transparent polycarbonate material; and

wherein the second portion is a peripheral portion, said second portion has a non-planar shape at its outermost edge created by a contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the polycarbonate material, said second portion non-planar outermost edge having a non-planar contour; and

wherein when said sheet rests on a plane, said second non-planar portion contour is spaced away from said plane such that portions of the periphery including said second non-planar portion contour are raised above and not in contact with said plane.

2. A high-impact, transparent sheet according to claim 1, wherein the first portion of the base sheet has opposing major surfaces, and further comprising:

a topcoat layer disposed over at least one of the opposing surfaces, the topcoat layer having a greater resistance to abrasion than the base sheet of polycarbonate material and providing UV protection for the first portion of the base sheet.

3. A high-impact, transparent sheet according to claim 2, further comprising a primer coating disposed between the base sheet and the topcoat layer, the primer coating facilitating bonding therebetween.

4. A high-impact, transparent sheet according to claim 1, wherein the first portion is a center portion of the base sheet having opposing major surfaces, and further comprising:

a topcoat layer disposed over each of the opposing surfaces, the topcoat layer having a greater resistance to abrasion than the base sheet of polycarbonate material and providing UV protection for the center portion of the base sheet; and

a primer coating disposed between each of the opposing surfaces and the topcoat layer disposed over each of the opposing surfaces, the primer coating facilitating bonding therebetween.

5. A high-impact, transparent sheet according to claim 1, wherein said second peripheral portion has said outermost edge defined by a pair of opposing surfaces and a terminal end surface connecting the pair of opposing surfaces at the outermost edge, and said opposing surfaces are on a non-perpendicular angle with respect to said end surface.

6. A high-impact, transparent windshield comprising:

a base sheet of transparent polycarbonate material having a glass transition temperature and a melt temperature, the base sheet being a windshield comprising a first portion and a second portion;

wherein the first portion has a shape created by a non-contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the transparent polycarbonate material; and

wherein the second portion is a peripheral portion, said second portion has a non-planar shape as its outermost edge created by a contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the polycarbonate material, said second portion non-planar outermost edge having a non-planar contour; and

wherein when said sheet rests on a plane, said second non-planar portion contour is spaced away from said plane such that portions of the periphery including said second non-planar portion contour are raised above and not in contact with said plane.

7. A high-impact, transparent windshield according to claim 6, wherein the first portion of the base sheet has opposing major surfaces, and further comprising:

a topcoat layer disposed over at least one of the opposing surfaces, the topcoat layer having a greater resistance to abrasion than the base sheet of polycarbonate material and providing UV protection for the first portion of the base sheet.

8. A high-impact, transparent windshield according to claim 7, further comprising a primer coating disposed between the base sheet and the topcoat layer, the primer coating facilitating bonding therebetween.

9. A high-impact, transparent windshield according to claim 6, wherein the first portion is a center portion of the base sheet having opposing major surfaces, and further comprising:

a topcoat layer disposed over each of the opposing surfaces, the topcoat layer having a greater resistance to abrasion than the base sheet of polycarbonate material and providing UV protection for the center portion of the base sheet; and

a primer coating disposed between each of the opposing surfaces and the topcoat layer disposed over each of the opposing surfaces, the primer coating facilitating bonding therebetween.

10. A high-impact, transparent windshield according to claim 6, wherein said second peripheral portion has said outermost edge defined by a pair of opposing surfaces and a terminal end surface connecting the pair of opposing surfaces at the outermost edge, and said opposing surfaces are on a non-perpendicular angle with respect to said end surface.

11. A high-impact, transparent windshield comprising:

a base sheet of transparent polycarbonate material having a glass transition temperature and a melt temperature, the base sheet being a contoured non-planar windshield comprising a first portion and a second portion;

wherein the first portion has a shape created by a non-contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the transparent polycarbonate material;

wherein the second portion has a shape created by a contact forming operation occurring at a temperature above the glass transition temperature and below the melt temperature of the polycarbonate material;

said second peripheral portion has an outermost edge defined by a pair of opposing surfaces and a terminal end surface connecting the pair of opposing surfaces at the outermost edge, and said opposing surfaces are on a non-perpendicular angle with respect to said end surface; and

wherein when said sheet rests on a plane, said second non-planar portion contour is spaced away from said plane such that portions of the periphery including said second non-planar portion contour are raised above and not in contact with said plane.