Golf balls containing interpenetrating polymer networks

• US 7,429,220 B2
• Filed: 04/13/2001
• Issued: 09/30/2008
• Est. Priority Date: 04/13/2001
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Wu, Shenshen, Bulpett, David A., Lutz, Mitchell E., Kuntimaddi, Manjari, Rajagopalan, Murali, Harris, Kevin M.
• Primary Examiner(s): Kim; Gene
• Assistant Examiner(s): Hunter; Alvin A
• Application Number:
  US09/833,667
• Publication Number:
  US 20020187857A1
• Time in Patent Office: 2,727 Days
• Field of Search: 473351-377, 525/196, 525/131, 525/455, 525/421, 525/528, 525/123
• US Class Current: 473/374
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/00221 characterised by the material
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/003 Coefficient of restitution
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0034 Deflection or compression
• CPC Class Codes: A63B 37/0037 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0074 Two piece balls, i.e. cover and core
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/06 Elastic cores
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/3206 aliphatic
• CPC Class Codes: C08G 2270/00 Compositions for creating interpenetrating networks
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

The present invention is directed to a golf ball that contains an interpenetrating polymer network, or IPN, including at least two polymeric components. These IPNs may be present in any golf ball layer, although in an intermediate or cover layer in one preferred embodiment. The present invention is also directed to methods of forming a golf ball containing an IPN in one or more of the layers.

Claims

1. A golf ball comprising a center, an intermediate layer disposed over the center, and a cover disposed about the intermediate laver, wherein at least one interpenetrating polymer network is present in the cover, wherein the interpenetrating polymer network is formed from a material consisting essentially of a urethane, an epoxy homopolymer or copolymer, a homopolymer or copolymer having backbone or pendant ester groups, a polyimide or copolymer including imide groups, a polysilane homopolymer or copolymer, a silicone homopolymer or copolymer, a polysiloxane homopolymer or copolymer, and combinations thereof, and wherein the shear resistance rating of the cover is at least 1 rating category lower than that measured for a cover comprising a polymer blend or mixture that is substantially free of IPN and that is made of the same components as the IPN, and wherein at least one of the center, the intermediate layer, and the cover has a foamed structure.

2. The golf ball of claim 1, wherein the cover has at least one of a dimple coverage of greater than about 60 percent, a hardness of greater than about 15 Shore A, or a flexural modulus of greater than about 500 psi, and wherein the golf ball has at least one of a compression no greater than about 120 or a coefficient of restitution of greater than about 0.7.

3. The golf ball of claim 1, wherein the center comprises a solid sphere or a fluid-filled sphere.

4. The golf ball of claim 1, wherein the intermediate layer comprises a tensioned elastomeric material.

5. The golf ball of claim 1, wherein the cover comprises at least an inner cover layer and an outer cover layer.

6. A golf ball comprising a core, a cover, and an intermediate layer, wherein at least one of the cover or intermediate layer comprises a non-ionomeric interpenetrating polymer network, wherein the interpenetrating polymer network is formed from at least two polymeric components selected from the group consisting of a urethane, an epoxy homopolymer or copolymer, a homopolymer or copolymer having backbone or pendant ester groups, a polyimide or copolymer including imide groups, a polysilane homopolymer or copolymer, a silicone homopolymer or copolymer, a polysiloxane homopolymer or copolymer, a homopolymer or copolymer including halogen groups, a homopolymer or copolymer including a uretdione group, and combinations thereof, and wherein the IPN exhibits a Δ

T_g between any two of the polymeric components at least about 5% less than the Δ

T_g between a polymer blend comprising the same polymeric components.

7. The golf ball of claim 6, wherein the IPN exhibits only one observable T_g for any two of the polymeric components.

8. A golf ball comprising a core, a cover, and an intermediate layer, wherein at least one of the cover or intermediate lava comprises a non-ionomeric interpenetrating polymer network, wherein the interpenetrating polymer network is formed from at least two polymeric components selected from the group consisting of a urethane, an epoxy homopolymer or copolymer, a homopolymer or copolymer having backbone or pendant ester groups, a polyimide or copolymer including bride groups, a polysilane homopolymer or copolymer, a silicone homopolymer or copolymer, a polysiloxane homopolymer or copolymer, a homopolymer or copolymer including halogen groups, a homopolymer or copolymer including a uretdione group, and combinations thereof, wherein the IPN exhibits a Δ

T_g between any two of the polymeric components at least about 20% less than the Δ

T_g between a polymer blend comprising the same polymeric components.

9. The golf ball of claim 8, wherein the IPN exhibits a Δ

T_g between any two of the polymeric components at least about 50% less than the Δ

T_g between a polymer blend comprising the same at least two polymeric components.

10. The golf ball of claim 8, wherein the IPN exhibits only one observable T_g for any two of the polymeric components.

11. A golf ball comprising a core, a cover, and an intermediate layer, wherein at least one of the cover or intermediate layer comprises a non-ionomeric interpenetrating polymer network formed from at least two polymeric components selected from the group consisting of a urethane, an epoxy homopolymer or copolymer, a homopolymer or copolymer having backbone or pendant ester groups, a polyimide or copolymer including imide groups, a polysilane homopolymer or copolymer, a silicone homopolymer or copolymer, a polysiloxane homopolymer or copolymer, a homopolymer or copolymer including halogen groups, a homopolymer or copolymer including a uretdione group, and combinations thereof, wherein the IPN exhibits a Δ

T_g between any two of the polymeric components at least about 5% less than the Δ

T_g between a polymer blend comprising the same polymeric components, and wherein at least one of the at least two polymeric components is a crystallizable polymeric component that exhibits an area under a melting endotherm of at least about 2% less than the area under the melting endotherm of a homopolymer of the same crystallizable polymeric component.

12. The golf ball of claim 11, wherein the crystallizable polymeric component exhibits an area under a melting endotherm of at least about 10% less than the area under the melting endotherm of the homopolymer of the same crystallizable polymeric component.

13. A golf ball comprising a core, a cover, and an intermediate layer, wherein at least one of the core, cover, or intermediate layer comprises an interpenetrating polymer network formed from at least two polymeric components selected from the group consisting of a urethane, an epoxy homopolymer or copolymer, a homopolymer or copolymer having backbone or pendant ester groups, a polyimide or copolymer including imide groups, a polysilane homopolymer or copolymer, a silicone homopolymer or copolymer, a polysiloxane homopolymer or copolymer, a homopolymer or copolymer including halogen groups, a homopolymer or copolymer including a uretdione group, and combinations thereof, wherein at least one of the at least two polymeric components exhibits an average phase size at least about 10% less than the average phase size of tat phase separated component in a blend or mixture of the at least two components.

14. The golf ball of claim 13, wherein at least one of the at least two polymeric components exhibits an average phase size at least about 20% less than the average phase size of that phase separated component in a blend or mixture of the at least two components.

15. The golf ball of claim 13, wherein the cover comprises the interpenetrating network.