Coated substrates that include an undercoating

• US 7,431,992 B2
• Filed: 08/09/2004
• Issued: 10/07/2008
• Est. Priority Date: 08/09/2004
• Status: Active Grant

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Lu, Songwei, Kutilek, Luke A., Athey, Patricia R., Harris, Caroline
• Primary Examiner(s): Speer; Timothy M
• Application Number:
  US10/914,356
• Publication Number:
  US 20060029813A1
• Time in Patent Office: 1,520 Days
• Field of Search: 428/411.1, 428/426, 428/428, 428/432
• US Class Current: 428/426
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride

Abstract

A coated substrate is disclosed. The coated substrate includes a substrate; an undercoating having one or more materials selected from tin oxide, silica, titania, alumina, zirconia, zinc oxide and alloys and mixtures thereof nitrides of titanium, zirconium, hafnium, silicon, aluminum and mixtures thereof, and oxy-nitrides of titanium, zirconium, hafnium, silicon, aluminum and mixtures thereof overlaying at least a portion of the substrate; and a functional coating overlaying at least a portion of the undercoating. As a result of the undercoating, the coated substrate can exhibit improved properties such as improved aesthetic properties, increased durability, photocatalytic activity, mechanical durability, etc.

Claims

1. A coated substrate comprising:

a. a substrate having an index of refraction;

b. an undercoating comprising a graded layer comprising a mixture of at least two materials selected from titania and at least one of tin oxide, silica, and alumina deposited on at least a portion of the substrate, wherein the undercoating consists of inorganic materials; and

c. an outermost functional coating having an index of refraction deposited on at least a portion of the undercoating, wherein the functional coating is a single layer, photocatalytic coating comprising anatase crystalline titania, and

wherein the undercoating is configured such that the coated substrate has a visible reflectance of no greater than 25% as measured from the coated side of the substrate.

2. The coated substrate according to claim 1, wherein the undercoating comprises a graded mixture of silica and titania having an index of refraction that is equal to or higher than the index of refraction of the substrate.

3. A coated substrate according to claim 1, wherein the undercoating is a gradient layer comprising titania and at least one of alumina and silica.

4. A coated substrate according to claim 1, wherein the undercoating is applied using a CVD method.

5. A coated substrate according to claim 1, wherein the functional coating is applied using a CVD method.

6. A coated substrate according to claim 1, wherein the substrate is glass.

7. A coated substrate according to claim 6, wherein the substrate is a float glass ribbon.