Multi-layer core golf ball

• US 7,438,651 B2
• Filed: 06/20/2007
• Issued: 10/21/2008
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Sullivan, Michael J., DeSimas, Antonio U., Ladd, Derek A.
• Primary Examiner(s): GORDEN, RAEANN
• Application Number:
  US11/765,763
• Publication Number:
  US 20070243954A1
• Time in Patent Office: 489 Days
• Field of Search: 473/373, 473/374, 473/376, 473/377, 473/368
• US Class Current: 473/373
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0043 Hardness
• CPC Class Codes: A63B 37/0045 Thickness
• CPC Class Codes: A63B 37/0046 Deflection or compression
• CPC Class Codes: A63B 37/0047 Density; Specific gravity
• CPC Class Codes: A63B 37/005 Cores
• CPC Class Codes: A63B 37/0061 Coefficient of restitution
• CPC Class Codes: A63B 37/0062 Hardness
• CPC Class Codes: A63B 37/0064 Diameter
• CPC Class Codes: A63B 37/0065 Deflection or compression
• CPC Class Codes: A63B 37/0066 Density; Specific gravity
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0091 Density distribution amongst the different ball layers
• CPC Class Codes: A63B 37/02 Special cores balls with finger holes A63B37/0001, golf ball cores A63B37/005
• CPC Class Codes: A63B 37/04 Rigid cores
• CPC Class Codes: A63B 45/00 Apparatus or methods for manufacturing balls working of plastics or substances in a plastic state B29
• CPC Class Codes: B29C 2043/3644 Vacuum bags; Details thereof, e.g. fixing or clamping
• CPC Class Codes: B29C 43/146 for making multilayered articles
• CPC Class Codes: B29C 43/18 : incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles B29C43/206 takes precedence
• CPC Class Codes: B29C 43/305 : Making multilayered articles
• CPC Class Codes: B29C 70/70 : Completely encapsulating inserts B29C70/86 takes precedence
• CPC Class Codes: B29D 99/0042 : Producing plain balls hollow balls B29D22/04
• CPC Class Codes: B29K 2105/256 : Sheets, plates, blanks or films
• CPC Class Codes: B29L 2031/52 : Sports equipment ; Games; Articles for amusement; Toys B29L2031/54 takes precedence
• CPC Class Codes: B29L 2031/54 : Balls
• CPC Class Codes: C08L 23/08 : Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 2666/04 : Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 : Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 : Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/02 : of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 75/02 : Polyureas
• CPC Class Codes: C08L 75/04 : Polyurethanes
• CPC Class Codes: C08L 9/00 : Compositions of homopolymers or copolymers of conjugated diene hydrocarbons

Abstract

The present invention is directed to an improved golf ball displaying the desired spin profile and having a generally rigid, thermoset polybutadiene outer core surrounding a relatively soft, low compression inner core. In general, this golf ball has an inner core and at least one outer core layer surrounding the inner core. The inner core has a hardness less than a hardness of the outer core and a specific gravity less than or equal to the outer core specific gravity. Overall the inner core compression and outer core are formulated to provide a combined overall core compression of greater than about 50, preferably greater than about 70. A cover layer is provided to surround and to cover the outer core layer. A moisture barrier layer is provided between the outer core layer and the cover layer to protect the inner and outer cores from degradation due to exposure to water. The moisture vapor transmission rate of the moisture barrier layer is selected to be less than the moisture vapor transmission rate of the cover layer.

Claims

1. A golf ball comprising:

a multi-layer core having a diameter of greater than 1.58 inches and comprising

an inner core having a Shore C hardness of less than 80 and a compression of less than 70; and

at least one outer core layer having a Shore C hardness of greater than 80 and formed from a composition comprising greater than 35 pph of zinc diacrylate; and

two or more cover layers, at least one cover layer having a Shore D hardness of less than 65;

wherein the outer core layer has a moisture vapor transmission rate that is lower than that of the cover layers.

2. The golf ball of claim 1, wherein the outer core layer has a Shore C hardness of greater than 90.

3. The golf ball of claim 1, wherein the outer core layer composition comprises greater than 40 pph of zinc diacrylate.

4. The golf ball of claim 1, wherein the multi-layer core has a diameter of greater than 1.60 inches.

5. The golf ball of claim 1, wherein at least one cover layer is formed from a composition selected from the group consisting of cast polyurethanes, polyureas, polyurethane ionomers, thermoplastic polyurethanes, polyamides, polyesters, single-site catalyzed polymers, and partially- and fully-neutralized ionomers.