Hydrogen generator cartridge

• US 7,438,732 B2
• Filed: 11/12/2005
• Issued: 10/21/2008
• Est. Priority Date: 06/11/2003
• Status: Expired due to Fees

• Current Assignee: Molly Alonso
• Original Assignee: Trulife Incorporated (Trulife)
• Inventors: Anderson, Howard, Ladd, Eric J., Shurtleff, James Kevin, Brydon, Chris A., Patton, John M.
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US11/270,947
• Publication Number:
  US 20060059778A1
• Time in Patent Office: 1,074 Days
• Field of Search: 422/239, 422/211, 48/61, 482/04
• US Class Current: 48/61
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: F17C 11/005 for hydrogen
• CPC Class Codes: H01M 8/04208 Cartridges, cryogenic media or cryogenic reservoirs
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/065 by dissolution of metals or alloys; by dehydriding metallic substances
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cartridge for a hydrogen generating system having a cartridge containing a substantially anhydrous chemical hydride reactant. A plurality of liquid conduits extends into the cartridge and each of the liquid conduits has a length and a plurality of liquid distribution apertures formed along the length. The liquid distribution apertures have a diameter of less than approximately 1 mm. The chemical hydride reactant forms a bed and the liquid conduits extend along at least half of a length of the bed.

Claims

1. A fuel cartridge for a hydrogen generating system, said cartridge comprising:

a housing comprising an end cap and containing a substantially anhydrous hydride reactant and an activating agent comprising a salt having a metal selected from the group consisting of alkaline earth metals and alkali metals;

at least one liquid conduit fixed to the end cap and extending into the anhydrous hydride reactant, the liquid conduit at least one liquid distribution aperture formed thereon, such that liquid reactant may pass in liquid form into the hydride reactant;

wherein the end cap comprises a liquid inlet port communicating with the liquid conduit and a gas outlet port, both the liquid inlet port and the gas outlet port being adapted to seal with a housing receiver.

2. The fuel cartridge according to claim 1, wherein the hydride reactant comprises about 20 percent by weight to about 65 percent by a weight of activating agent.

3. The fuel cartridge according to claim 1, wherein the activating agent is water soluble.

4. The fuel cartridge according to claim 1, wherein the activating agent comprises at least one material selected from the group consisting of BeF₂, BeCl₂, BcBr₂, Bel₂, MgF₂, MgBr₂, MgCl₂, Mgl₂, CaF₂, CaCl₂, CaBr₂, Cal₂, LiF, LiCl, LiBr, Lil, NaF, NaCl, NaBr, Nal, KF, KCl, KBr, Kl, Li₂S, and Li₂Se.

5. The fuel cartridge according to claim 1, wherein the hydride is enclosed in a fabric pouch having a substantially greater area than thickness, the fabric pouch configured to be inserted into the housing.

6. The fuel cartridge according to claim 1, further comprising a plurality of liquid conduits, wherein the plurality of liquid conduits are spaced radially from a center point of the end cap in a nonuniform configuration.

7. The fuel cartridge according to claim 1, wherein the anhydrous hydride reactant comprises an anhydrous hydride and the liquid reactant comprises a mixture of water and anhydrous activating agent.

8. The fuel cartridge of claim 1, wherein the anhydrous hydride reactant is selected from a group consisting of sodium borohydride, lithium borohydride, lithium aluminum hydride, lithium hydride, sodium hydride, and calcium hydride.

15. The apparatus of claim 1, wherein the liquid reactant has a lower freezing point temperature than water.

16. The apparatus of claim 15, wherein the liquid reactant comprises a freezing point lowering additive.

17. The apparatus of claim 16, wherein the freezing point lowering additive comprises an alcohol.

9. An apparatus for hydrogen generation, the apparatus comprising:

a housing configured to contain a mixture of anhydrous hydride reactant and an activating agent comprising a salt having a metal selected from the group consisting of alkaline earth metal and alkali metals;

at least one liquid conduit extending into the container configured to pass a liquid into the mixture; and

wherein the housing further comprises a liquid inlet port and a gas outlet port.

10. The apparatus of claim 9, wherein the hydride reactant comprises sodium borohydride.

11. The apparatus of claim 9, wherein the mixture comprises in the range of between about 20 percent by weight to about 65 percent by weight of the activating agent.

12. The apparatus of claim 9, wherein the activating agent comprises at least one material selected from the group consisting of BeF₂, BeCl₂, BeBr₂, Bel₂, MgF₂, MgBr₂, MgCl₂, Mgl₂, CaF₂, CaCl₂, CaBr₂, Cal₂, LiF, LiCl, LiBr, Lil, NaF, NaCl, NaBr, Nal, KF, KCl, KBr, KL, Li₂S, and Li₂Se.

13. The apparatus of claim 9, further comprising a plurality of liquid conduits, wherein the plurality of liquid conduits are spaced radially from a center point of an end of the housing in a nonuniform configuration.

14. The apparatus of claim 9, further comprising a fabric pouch having a substantially greater area than thickness configured to contain a portion of the mixture and promote a complete reaction of the mixture, the fabric pouch disposed with in the housing.