Activatable material for sealing, baffling or reinforcing and method of forming same

• US 7,438,782 B2
• Filed: 06/07/2006
• Issued: 10/21/2008
• Est. Priority Date: 06/07/2006
• Status: Expired due to Fees

• Current Assignee: Zephyros, Inc.
• Original Assignee: Zephyros, Inc.
• Inventors: Sheasley, David, Kosal, David, Antrim, Jeanne
• Primary Examiner(s): Tucker; Philip C
• Assistant Examiner(s): Orlando; Michael N
• Application Number:
  US11/422,705
• Publication Number:
  US 20070284036A1
• Time in Patent Office: 867 Days
• Field of Search: 156/293, 525/524
• US Class Current: 156/293
• CPC Class Codes: C08G 2650/50 containing nitrogen, e.g. polyetheramines or Jeffamines(r)
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: C09J 163/00 Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• CPC Class Codes: C09J 2463/00 Presence of epoxy resin
• CPC Class Codes: C09J 5/06 involving heating of the applied adhesive

Abstract

An activatable material and articles incorporating the same is disclosed. The activatable material includes at least two of epoxy resin; impact modifier; blowing agent; curing agent; and filler. The activatable material is preferably used for sealing, baffling, adhering or reinforcing an article of manufacture such as an automotive vehicle.

Claims

1. A method of adhesion, the method comprising:

extruding a mass of a tack-free activatable material, the activatable material including;

i) between about 10 and about 20% by weight of an epoxy resin;

ii) an epoxy/elastomer adduct in an amount at least approximately 20 to less than about 30% by weight of the activatable material, wherein the adduct is a solid at a temperature of 23°

C.;

iii) between about 3 and about 7% by weight of one or more thermoplastic polyethers;

iv) between about 5 and about 10% by weight of the activatable material of a core/shell polymer impact modifier that includes a core of a first polymeric material and a shell of a second polymeric material, wherein second polymeric material is grafted onto and encapsulates the first polymeric material; and

the first polymeric material has a glass translation temperature of at least about 10°

C. below a glass transition temperature of the second polymeric material; and

v) between about 0.001 and about 7% by weight of a curing agent;

locating the activatable material adjacent a first surface and a second surface of an automotive vehicle, the first surface and second surface being part of a hem flange joint wherein the activatable material is located adjacent the first surface and the second surface as a substantially tack-free elongated strip; and

activating the activatable material to bond the activatable material to the first surface and second surface;

wherein the glass transition temperature of the first polymeric material is less than about 23°

C. and the glass transition temperature of the second polymeric material is at least about 23°

C.

2. A method as in claim 1 wherein the activatable material is activated in an e-coat or paint oven.

3. A method as in claim 1 wherein the activatable material includes a blowing agent.

4. A method as in claim 3 wherein the blowing agent is selected from an azodicarbonamide, a dinitrosopentamethylenetetramine, a 4,4_i-oxy-bis-(benzenesulphonylhydrazide), a trihydrazinotriazine or a N,N_i-dimethyl-N,N_i-dinitrosoterephthalamide.

5. A method as in claim 4 wherein the activatable material includes at least 35% by weight filler material.

6. A method as in claim 1 wherein the first surface is part of a first member of the article of manufacture and the second surface is part of a second member of the article of manufacture.

7. A method as in claim 6 wherein the core/shell impact modifier has a polymethyl methacrylate shell and butadiene styrene core.

14. The method of claim 1, wherein the adhesive material exhibits a T-peel strength according to ASTM D 1876-01 of at least about 2 N/mm.

15. The method of claim 1, wherein

the activatable material includes between about 20% and about 30% by weight of the epoxy/elastomer adduct;

the activatable material further comprises a blowing agent that is selected from an azodicarbonamide, a dinitrosopentamethylenetetramine, a 4,4_i-oxy-bis-(benzenesulphonylhydrazide), a trihydrazinotriazine or a N,N_i-dimethyl-N,N_i-dinitrosoterephthalamide;

the activatable material includes about 30 to about 50 % by weight of a filler material;

the one or more thermoplastic polyethers has a melt index that ranges from about 5 to about 100 g/10 min for under weight of 2.16 Kg at a temperature of about 190°

C.; and

the core/shell impact modifier has a polymethyl methacrylate shell and butadiene styrene core.

16. The method of claim 1, wherein the one or more thermoplastic polyethers are formed by reacting an amine with an average functionality of 2 or less with a glycidyl ether.

17. The method of claim 1, wherein the one or more thermoplastic polyethers are polyetheramines, poly(amino ethers), copolymers of monoethanolamine and diglycidyl ether, or any combinations thereof.

18. The method of claim 17, wherein the one or more thermoplastic polyethers are polyetheramines.

8. A method of adhesion, the method comprising:

extruding a mass of a tack-free activatable material, the activatable material including;

i) between about 10 and about 20% by weight of an epoxy resin;

ii) an epoxy/elastomer adduct in an amount that ranges from about 20 to about 30% by weight of the activatable material, wherein the adduct is a solid at a temperature of 23°

C.;

iii) between about 3 and about 7% by weight of one or more thermoplastic polyethers;

iv) between about 5 and about 10% by weight of the activatable material of a core/shell polymer impact modifier that includes a core of a first polymeric material and a shell of a second polymeric material, wherein second polymeric material is grafted onto and encapsulates the first polymeric material; and

the first polymeric material has a glass translation temperature of at least about 10°

C. below a glass transition temperature of the second polymeric material; and

v) between about 0.001 and about 7% by weight of a curing agent;

vi) at least 35% by weight of a filler material;

locating the activatable material adjacent a first metal surface of a first member of an automotive vehicle and a second metal surface of a second member of the automotive vehicle wherein the activatable material is located adjacent the first surface and second surface as a substantially tack-free elongated strip; and

activating the activatable material to bond the activatable material to the first member and the second;

wherein the glass transition temperature of the first polymeric material is less than about 23°

C. and the glass transition temperature of the second polymeric material is at least about 23°

C.

9. A method as in claim 8 wherein the first surface and second surface are part of a hem flange joint wherein the first member has an end portion that forms a cavity for receiving a free end of the second member.

10. A method as in claim 9 wherein the activatable material is located, during the locating step, within the cavity formed by the end portion of the first member as the substantially tack-free elongated strip.

11. A method as in claim 8 wherein the activatable material is activated in an e-coat or paint oven.

12. A method as in claim 8 wherein the activatable material includes a blowing agent.

13. A method as in claim 8 wherein the core/shell impact modifier has a polymethyl methacrylate shell and butadiene styrene core.

19. The method of claim 8, wherein the one or more thermoplastic polyethers are formed by reacting an amine with an average functionality of 2 or less with a glycidyl ether.

20. The method of claim 8, wherein the one or more thermoplastic polyethers are polyetheramines, poly(amino ethers), copolymers of monoethanolamine and diglycidyl ether, or any combinations thereof.