Adsorbents, methods of preparation, and methods of use thereof

• US 7,442,232 B2
• Filed: 06/19/2003
• Issued: 10/28/2008
• Est. Priority Date: 06/19/2002
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc), Georgia Tech Research Corporation (University System of Georgia)
• Original Assignee: Georgia Tech Research Corporation (University System of Georgia)
• Inventors: White, Mark G., Weigel, Scott Jeffrey, Brzozowski, Jeffrey Richard, Iretski, Alexei V, Chiang, Robert Ling
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US10/518,188
• Publication Number:
  US 20060144227A1
• Time in Patent Office: 1,958 Days
• Field of Search: 95/96, 951/06, 951/15, 95118-120, 951/26, 951/39, 959/00, 423/230, 502/34, 502/56, 502/102, 502/103, 502/414
• US Class Current: 95/96
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/40086 by using a purge gas B01D2259/4009 takes precedence
• CPC Class Codes: B01D 2259/401 using a single bed
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/06 with moving adsorbents, e.g. rotating beds B01D53/025 takes precedence
• CPC Class Codes: B01D 53/12 according to the "fluidised technique"
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/06 comprising oxides or hydroxides of metals not provided for in group B01J20/04
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/3433 of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
• CPC Class Codes: B01J 20/3483 by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
• CPC Class Codes: B01J 20/3491 by pressure treatment
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 95/90 Solid sorbent

Abstract

Adsorbents and methods of use thereof are provided. One representative, among others, includes an adsorbent having an alkali metal promoted, mixed trivalent layered double hydroxide (LDH) composition. When the mixed trivalent layered double hydroxide (LDH) composition is heated to a temperature ranging from about 300° C. to 450° C., an the adsorbent having an adsorption capacity of at least 0.8 millimoles of CO₂ adsorbed per gram of adsorbent is formed.

Claims

1. An adsorbent comprising an alkali metal promoted, mixed trivalent layered double hydroxide (LDH) composition, wherein the mixed trivalent layered double hydroxide (LDH) composition is heated to a temperature ranging from about 300°

C. to 450°

C. to provide the adsorbent, and wherein the alkali metal promoted, mixed trivalent metal LDH composition has the following general formula;

[M1<sub>1−

x</sub>(M2_yM3<sub>(1−

y)</sub>)_x(OH)2(A)_x/2.z H₂O].v [M4_wCO₃]

wherein the subscript “

x”

is a number between 0 and 1;

the subscript “

y”

is a number ranging from greater than 0 to about 0.05;

“

z”

is a number ranging from 0 to about 8;

the subscript “

w”

is the integer 1 or 2, wherein when “

w”

is the integer 1 the CO₃ becomes HCO₃;

“

v”

is a number ranging from 0 to about 0.01;

“

M1”

is a divalent metal selected from magnesium (Mg), calcium (Ca), strontium (Sr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), and zinc (Zn);

“

M2” and

“

M3”

are each a trivalent metal selected from aluminum (Al), chromium (Cr), Mn, Fe, Co, lanthanum (La), cerium (Ce), galium (Ga), indium (In), the lanthanide series of metals, and mixtures thereof;

“

A”

is an anion selected from CO₃, SO₄, and HPO₄; and

“

M4”

is an alkali metal selected from sodium (Na), potassium (K), robidium (Rb), cesium (Cs), and lithium (Li).

2. The adsorbent of claim 1, wherein “

M1”

is Mg.

3. The adsorbent of claim 1, wherein “

M2”

is selected from Al, Ga, and La.

4. The adsorbent of claim 1, wherein “

M3”

is a trivalent metal selected from Ga, La, In, and the lanthanide series of metals.

5. The adsorbent of claim 1, wherein at least one of “

M2” and

“

M3”

is Al.

6. The adsorbent of claim 1, wherein “

M4”

is K.

7. The adsorbent of claim 1, wherein the alkali metal promoted, mixed trivalent layered double hydroxide (LDH) composition is represented by the formula:

[Mg₆Al_{2 (1-o)} Ga_2o(OH)₁₆CO₃.4H₂O].p(K₂CO₃), wherein p is in the range from greater than 0 to about 0.02, and wherein o is in the range from greater than 0 to about 0.3.

8. The adsorbent of claim 1,wherein the alkali metal promoted, mixed trivalent layered double hydroxide (LDH) composition is represented by the formula:

[Mg₆Al_2(1-q)La_2q(OH)₁₆CO₃.4H₂O].r(K₂CO₃), wherein r is in the range from greater than 0 to about 0.02, and wherein q is in the range from greater than 0 to about 0.1.

9. The adsorbent of claim 1, wherein the adsorbent has a working capacity of at least about 0.05 millimoles CO₂ per gram of adsorbent.

10. The adsorbent of claim 1, wherein the adsorbent has a working capacity of at least 0.5 millimoles per gram CO₂ per gram of adsorbent.

11. A method of separating carbon dioxide from a gas mixture comprising carbon dioxide and water vapor, the method comprising:

providing at least one adsorption zone comprising an alkali metal promoted, trivalent metal layered double hydroxide (LDH) adsorbent having an adsorption capacity of at least 0.8 millimoles of CO₂ adsorbed per gram of LDH adsorbent;

passing the gas mixture comprising water vapor and carbon dioxide through the at least one adsorption zone wherein the alkali metal promoted, mixed trivalent metal LDH adsorbent adsorbs at least part of the carbon dioxide from the mixture to provide a carbon dioxide-depleted gas; and

regenerating the alkali metal promoted trivalent metal LDH adsorbent to provide a a carbon dioxide-rich gas.

12. The method of claim 11, wherein the passing step is at least one process selected from pressure swing adsorption, temperature swing adsorption, and combinations thereof.

13. The method of claim 11, wherein the adsorption zone comprises at least one member selected from a single adsorption bed, a plurality of adsorption beds, a rotating kiln adsorption unit, and combinations thereof.

14. The method of claim 11, wherein the gas mixture further comprises at least one gas selected from hydrocarbons, carbon monoxide, H₂, O₂, N₂, and combinations thereof.

15. The method of claim 14, wherein the gas mixture comprises at least one hydrocarbon selected from naphtha, methane, ethane, ethene, and combinations thereof.

16. A method of separating carbon dioxide from a gas mixture using an adsorption process comprising:

passing the gas mixture comprising water vapor through at least one adsorption zone comprising an alkali metal promoted, mixed trivalent metal layered double hydroxide (LDH) adsorbent wherein the adsorption zone being at a first temperature and a first pressure, and wherein the alkali metal promoted, mixed trivalent metal LDH adsorbent adsorbs at least part of the carbon dioxide from the gas mixture;

separating a portion of the carbon dioxide from the gas mixture to form a carbon dioxide-depleted gas; and

regenerating the alkali metal promoted, mixed trivalent metal LDH adsorbent, wherein the adsorption zone being at a second temperature and a second pressure.

17. The method of claim 16, wherein the adsorption process is a cyclic adsorption process.

18. The method of claim 16, wherein the cyclic adsorption process is selected from a pressure swing adsorption process, a temperature swing adsorption process, and combinations thereof.

19. The method of claim 16, wherein the first temperature is less than the second temperature.

20. The method of claim 16, wherein the first pressure is greater than the second pressure.