Method for producing basic metal nitrate

• US 7,462,342 B2
• Filed: 03/27/2002
• Issued: 12/09/2008
• Est. Priority Date: 03/29/2001
• Status: Active Grant

• Current Assignee: Daicel Chemical Industries Limited
• Original Assignee: Daicel Chemical Industries Limited
• Inventors: Tomiyama, Shogo, Zhou, Xingxi
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US10/468,039
• Publication Number:
  US 20040131529A1
• Time in Patent Office: 2,449 Days
• Field of Search: 423/395
• US Class Current: 423/395
• CPC Class Codes: C01G 1/08 Nitrates
• CPC Class Codes: C01G 3/08 Nitrates

Abstract

A process in which a basic metal nitrate is obtained in a high yield is provided.

A process for producing a basic metal nitrate, which comprises adding an aqueous solution of a metal nitrate or an aqueous solution of a mixture of a metal nitrate and a water-soluble additive and an alkali solution to a reaction vessel in which a reaction solvent whose pH at 20° C. is adjusted to 6 or less is present, and conducting the reaction with stirring.

Claims

1. A process for producing a basic copper nitrate, which comprises adding an aqueous solution of copper nitrate or an aqueous solution of a mixture of copper nitrate and ammonium nitrate and an aqueous solution of sodium hydroxide to a reaction vessel in which a reaction solvent, whose pH at 20°

C before starting the reaction is adjusted to between 1.5 and 2.5, is present, and conducting the reaction with stirring through a stirring unit so that the maximum pH value reaches 5.0 to 6.5 during the reaction.

2. The process for producing the basic copper nitrate according to claim 1, in which the concentration of the copper nitrate in the aqueous solution of copper nitrate or the aqueous solution of the mixture of copper nitrate and ammonium nitrate is 65% by weight or less.

3. The process for producing the basic copper nitrate according to claim 1, in which the concentration of ammonium nitrate in the aqueous solution of the mixture of copper nitrate and ammonium nitrate is 5% by weight or less.

4. The process for producing the basic copper nitrate according to claim 1, in which the concentration of the sodium hydroxide solution is 60% by weight or less.

5. The process for producing the basic copper nitrate according to claim 1, in which the reaction solvent is an acid aqueous solution or an aqueous solution of a mixture of an acid and a water-soluble additive.

6. The process for producing the basic copper nitrate according to claim 5, in which the acid is nitric acid.

7. The process for producing the basic copper nitrate according to claim 5, in which the concentration of the water-soluble additive in the reaction solvent is 5% by weight or less.

8. The process for producing the basic copper nitrate according to claim 1, in which a ratio S_1/S₂ of an addition rate Si (mo 1 /min) of the copper nitrate to an addition rate S₂ (mol/min) of the sodium hydroxide alkali is 0.2 to 3.0.

9. The process for producing the basic copper nitrate according to claim 1, in which the reaction temperature is 60°

C or less.

10. The process for producing the basic copper nitrate according to claim 1, in which the stirring rate with the stirring unit in the reaction is less than 200 rpm.

11. The process for producing the basic copper nitrate according to claim 1, in which a position where the aqueous solution of copper nitrate or the aqueous solution of the mixture of copper nitrate and ammonium hydroxide and the sodium hydroxide solution is added is in the vicinity of or next to the stirring unit in the solution.

12. A basic copper nitrate having the form of prism which is produced in accordance with the process which comprises

adding an aqueous solution of a copper nitrate or an aqueous solution of a mixture of a copper nitrate and a water-soluble additive and an aqueous solution of an alkali to a reaction vessel in which a reaction solvent is present, wherein the pH at 20°

C of the reaction solvent before starting the reaction is adjusted to between 1.5 and 2.5, and

conducting the reaction with stirring through a stirring unit so that the maximum pH value reaches 5.0 to 6.5 during the reaction, thereby precipitating a basic copper metal nitrate particulate product having the form of prisms.