Zinc recovery process

• US 7,465,334 B2
• Filed: 09/12/2002
• Issued: 12/16/2008
• Est. Priority Date: 09/13/2001
• Status: Expired due to Fees

• Current Assignee: Intec International Projects Pty., Ltd. (SciDev Ltd.)
• Original Assignee: Intec Incorporated (Gaf Fiberglass Corp.)
• Inventors: Moyes, John, Houllis, Frank
• Primary Examiner(s): King; Roy
• Assistant Examiner(s): MCGUTHRY BANKS, TIMA MICHELE
• Application Number:
  US10/488,916
• Publication Number:
  US 20040237720A1
• Time in Patent Office: 2,287 Days
• Field of Search: 757/25, 757/42, 757/43, 423/101, 423/109, 205/606
• US Class Current: 75/743
• CPC Class Codes: C22B 19/22 with leaching with acids
• CPC Class Codes: C22B 19/26 Refining solutions containing zinc values, e.g. obtained by leaching zinc ores treatment or purification of solutions by liquid-liquid extraction, by ion exchange or by adsorption C22B3/00
• CPC Class Codes: C22B 3/10 Hydrochloric acid , other halogenated acids or salts thereof
• CPC Class Codes: C25C 1/16 of zinc, cadmium or mercury
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

A process for the recovery of zinc metal from a zinc mineral includes the steps of leaching the zinc mineral in a solution including a halide species formed from two or more different halides, to leach the zinc into the solution. The zinc-bearing solution is then electrolyzed to yield zinc metal and to generate the halide species. The electrolyzed solution including the halide species is then returned to the leaching step. A portion of the electrolyzed solution can be removed as a bleed stream from a cathode compartment of an electrolytic cell of the electrolysis process and processed to remove manganese as manganese dioxide precipitate by adding thereto limestone, and the halide species from an anode compartment of the electrolysis process. In this regard, the pH and Eh of the solution can regulated in a manner that favors the formation of the manganese dioxide precipitate over the formation of a precipitate of zinc.

Claims

1. A process for the recovery of zinc metal from a zinc mineral which may have iron therein, comprising the steps of:

(i) leaching the zinc mineral wherein the zinc leaching step consists of a single stage using a solution including a halide species formed from two or more different halides, to leach the zinc into the solution

(ii) passing the solution from (i) to an aeration stage in which air is introduced to oxidize and precipitate iron present in the mineral;

(iii) electrolysing the zinc-bearing solution from (ii) to yield zinc metal and to generate the halide species; and

(iv) returning the electrolysed solution including the halide species to the leaching step.

2. A process as claimed in claim 1 wherein the halide species is anodically formed in the electrolysis step.

3. A process as claimed in claim 2 wherein the halide species is formed at an oxidation potential lower than that for the formation of insoluble forms of impurities in the solution.

4. A process as claimed in claim 1 wherein the two or more different halides are chlorine and bromine and the halide species is a soluble halide complex.

5. A process as claimed in claim 4 wherein the halide species is BrCl₂ and/or BrCl gas.

6. A process as claimed in claim 1 wherein the leaching of the mineral by the halide species is facilitated by a catalyst which catalyses the oxidation of the mineral.

7. A process as claimed in claim 6 wherein the catalyst is a metal catalyst which is either present in the zinc mineral or is introduced into the leaching process.

8. A process as claimed in claim 6 wherein the catalyst is copper.

9. A process as claimed in claim 1 wherein the mineral comprises sulphur and the process comprises the further step of adding limestone to balance the generation of sulphuric acid as a result of sulphur oxidation in the leaching stage, as calcium sulphate.

10. A process as claimed in claim 9 wherein leachate from the leaching process, prior to electrolysis, has any gold and platinum group metals present therein removed therefrom by passing the leachate over activated carbon to absorb the gold and platinum group metals onto the carbon.

11. A process as claimed in claim 10 wherein leachate from the leaching process, prior to electrolysis, is passed to a series of cementation processes in which zinc dust is added to the leachate to cement out any copper, silver, lead and other impurities present in the leachate.

12. A process as claimed in claim 1 wherein the leachate from the leaching process, prior to electrolysis, is passed to a further iron removal stage in which limestone and a halide species from the electrolysis step are added to oxidize and precipitate iron as ferric oxide.

13. A process as claimed in claim 12 wherein a portion of the electrolysed solution is removed and processed to remove manganese therefrom.

14. A process as claimed in claim 13 wherein said portion is a bleed stream from a cathode compartment of an electrolytic cell of the electrolysis process, with the bleed stream having added thereto limestone and the halide species from an anode compartment of the electrolysis process, to precipitate manganese dioxide.

15. A process as claimed in claim 14 where in the pH and Eh of the solution are regulated in a manner that favors the formation of the manganese dioxide precipitate over the formation of a precipitate of zinc.

16. A process as claimed in claim 15 wherein the pH is regulated by the incremental addition of the limestone to raise the solution pH to a level at which the Eh can be increased by the halide species to a level at or above which MnO₂ formation is favored.

17. A process as claimed in claim 16 wherein the amount of limestone added is less than the stoichiometric amount required for MnO₂ formation, such that less of the zinc is precipitated.

18. A process as claimed in claim 17 wherein, prior to returning the electrolysed leachate to the leaching process, a portion of the electrolysed leachate from a cathode compartment of the electrolysis process is passed to a magnesium removal stage in which slaked lime is added to firstly remove any zinc (which is returned to the leaching process) and then to remove the magnesium as a magnesium oxide precipitate.

19. A process as claimed in claim 12 wherein when the leachate from the leaching process, prior to electrolysis, is passed to the iron removal stage, the limestone and halide species oxidize and precipitate at least a portion of the manganese present as manganese dioxide.