Calcium hypochlorite composition

• US 7,465,412 B2
• Filed: 02/24/2005
• Issued: 12/16/2008
• Est. Priority Date: 10/28/2004
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Pickens, Stanley R., Abraham, Fred, DuBois, Donald W.
• Primary Examiner(s): Eashoo; Mark
• Assistant Examiner(s): Godenschwager; Peter F
• Application Number:
  US11/065,231
• Publication Number:
  US 20060091356A1
• Time in Patent Office: 1,391 Days
• Field of Search: 252/187.24, 252/187.1
• US Class Current: 252/187.28
• CPC Class Codes: C11D 3/3953 Inorganic bleaching agents C11D3/3951 takes precedence

Abstract

Calcium hypochlorite compositions that are classified as a Packing Group III Division 5.1 oxidizer material or as a non-Division 5.1 oxidizer material are described. In one embodiment, the compositions comprise an admixture of particulate calcium hypochlorite and particulate metaboric acid. The calcium hypochlorite is present in the composition in an amount and is of a concentration such that the composition would be classified as a Packing Group II Division 5.1 oxidizer in the absence of said particulate metaboric acid. Other embodiments described are solid shaped articles, e.g., tablets, comprising the described calcium hypochlorite-metaboric acid composition.

Claims

1. A solid calcium hypochlorite composition consisting essentially of an admixture of particulate calcium hypochlorite, particulate metaboric acid, and optionally an inert hygroscopic inorganic material, wherein said metaboric acid is present in said composition in an amount such that the composition is classified as a Packing Group III Division 5.1 oxidizer or as a non-Division 5.1 oxidizer, and wherein said calcium hypochlorite is present in an amount and is of a concentration such that calcium hypochlorite composition would be classified as a Packing Group II Division 5.1 oxidizer in the absence of said particulate metaboric acid.

2. The composition of claim 1 wherein said calcium hypochlorite provides from 39% to 80% by weight free available chlorine, based oil the total weight of said composition.

3. The composition of claim 1 wherein the amount of metaboric acid in the composition ranges from 2 to 30 weight percent.

4. The composition of claim 1 wherein the amount of water associated with said calcium hypochlorite is less than 8.5 weight percent.

5. The composition of claim 1 further comprising less than 5 weight percent of said inert hygroscopic inorganic material.

6. The composition of claim 5 wherein said inert hygroscopic inorganic material is amorphous silica.

7. A solid shaped article prepared from the composition of claim 1.

8. The solid shaped article of claim 7 wherein the article is in the form of a tablet, said tablet having a mass of from 300 to 350 grams.

9. The solid shaped article of claim 7 wherein the calcium hypochiorite provides from 39% to 75% by weight of free available chlorine, based on the total weight of the composition, and the metaboric acid is present in the article in an amount of from 2 to 30 weight percent.

10. The composition of claim 1 wherein said calcium hypochlorite provides from 39% to 75% by weight free available chlorine, based on the total weight of said composition, wherein the amount of water associated with said calcium hypochlorite is less than 8.5%, and the amount of metaboric acid in the composition ranges from 15 to 30 weight percent.

11. The composition of claim 10 wherein the calcium hypochlorite composition is in the form of a solid shaped article, said shaped article having a mass of from 1 to 350 grams.

12. A solid calcium hypochlorite composition consisting essentially of an admixture of particulate calcium hypochlorite, particulate metaboric acid and particulate, inert inorganic material, said metaboric acid and inert inorganic material being present in amounts such that the composition is classified as a Packing Group III Division 5.1 oxidizer or as a non-Division 5.1 oxidizer, said calcium hypochlorite being present in amounts sufficient to provide at least 39 percent by weight of free available chlorine.

13. The composition of claim 12 wherein the particulate, inert inorganic material is selected from sodium chloride, potassium chloride, lithium chloride, calcium chloride, calcium oxide, calcium hydroxide, magnesium hydroxide, aluminum hydroxide, anhydrous sodium sulfate and mixtures of said particulate, inert inorganic materials.

14. The composition of claim 13 wherein the inert inorganic material is an anhydrous, pH neutral salt.

15. The composition of claim 13 wherein the metaboric acid is present in amounts of from 2 to 30 weight percent, the particulate, inert inorganic material is present in amounts of from 10 to 25 weight percent and the calcium hypochlorite is present in amounts sufficient to provide at least 39% by weight of free available chlorine.

16. A calcium hypochlorite package comprising (i) a solid calcium hypochlorite composition consisting essentially of an admixture of calcium hypochlorite, particulate metaboric acid, and optionally particulate, inert inorganic material, wherein said metaboric acid is present in said composition in amounts such that the composition is classified as a Packing Group III Division 5.1 oxidizer or as a non-Division 5.1 oxidizer, and wherein said calcium hypochiorite is present in amounts sufficient to provide at least 39 percent by weight of free available chlorine, and (ii) at least one separate package that contains a desiccant.

17. The calcium hypochiorite package of claim 16 wherein the calcium hypochlorite provides from 39% to 75% by weight flee available chlorine, based on the total weight of the calcium hypochlorite composition, and the amount of metaboric acid in the composition ranges from 2 to 30 weight percent.

18. The calcium hypochiorite package of claim 16 wherein the calcium hypochlorite composition further comprises said particulate, inert inorganic material.

19. The calcium hypochlorite package of claim 18 wherein the inert inorganic salt is sodium chloride.

20. The calcium hypochlorite package of claim 19 wherein the metaboric acid is present in amounts of from 2 to 30 weight percent, the sodium chloride is present in amounts of from 10 to 25 weight percent and the calcium hypochlorite is present in amounts sufficient to provide at least 39% by weight of free available chlorine.