Continuous counter-current organosolv processing of lignocellulosic feedstocks

• US 7,465,791 B1
• Filed: 01/30/2008
• Issued: 12/16/2008
• Est. Priority Date: 05/31/2007
• Status: Expired due to Fees

• Current Assignee: Suzano Canada Inc. (Suzano S.A.)
• Original Assignee: Lignol Innovations Ltd (Suzano S.A.)
• Inventors: Pye, Edward Kendall, Berlin, Alex, O'Connor, Donald, MacLachlan, John Ross, Hallberg, Christer, Gjennestad, Gordon, Rushton, Michael
• Primary Examiner(s): Tsang; Cecilia
• Assistant Examiner(s): BRADLEY, CHRISTINA
• Application Number:
  US12/022,831
• Publication Number:
  US 20080299629A1
• Time in Patent Office: 321 Days
• Field of Search: None
• US Class Current: 530/500
• CPC Class Codes: B01D 11/0226 with the general transport direction of the solids parallel to the rotation axis of the conveyor, e.g. worm
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: B01D 3/002 by continuous methods
• CPC Class Codes: B01D 3/14 Fractional distillation or use of a fractionation or rectification column
• CPC Class Codes: C02F 11/04 Anaerobic treatment; Production of methane by such processes
• CPC Class Codes: C02F 3/34 characterised by the microorganisms used
• CPC Class Codes: C07H 19/00 Compounds containing a hetero ring sharing one ring hetero atom with a saccharide radical; Nucleosides; Mononucleotides; Anhydro-derivatives thereof
• CPC Class Codes: C08H 6/00 Macromolecular compounds derived from lignin, e.g. tannins, humic acids
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C08L 3/02 Starch; Degradation products thereof, e.g. dextrin
• CPC Class Codes: C08L 5/04 Alginic acid; Derivatives thereof
• CPC Class Codes: C12M 21/04 for producing gas, e.g. biogas digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10
• CPC Class Codes: C12M 21/12 for producing fuels or solvents C12M21/04 takes precedence; liquid carbonaceous fuels C10L1/00, solid fuels C10L5/00
• CPC Class Codes: C12M 45/02 by mechanical forces; Stirring; Trituration; Comminuting crushing, pulverizing, disintegrating in general B02C
• CPC Class Codes: C12M 45/04 Phase separators; Separation of non fermentable material; Fractionation
• CPC Class Codes: C12M 45/06 by chemical means or hydrolysis
• CPC Class Codes: C12M 45/09 by enzymatic treatment
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 5/023 Methane
• CPC Class Codes: C12P 7/00 Preparation of oxygen-containing organic compounds
• CPC Class Codes: C12P 7/08 : produced as by-product or from waste or cellulosic material substrate
• CPC Class Codes: C12P 7/10 : substrate containing cellulosic material
• CPC Class Codes: C12P 7/40 : containing a carboxyl group including Peroxycarboxylic acids
• CPC Class Codes: C12P 7/54 : Acetic acid vinegar C12J
• CPC Class Codes: C13K 1/02 : obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: D21H 17/00 : Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
• CPC Class Codes: Y02E 50/10 : Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 : Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02W 10/20 : Sludge processing

Abstract

A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process comprises a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.

Claims

1. A modular process for organosolv fractionation of a lignocellulosic feedstock into component parts and further processing of said component parts;

the modular process comprising;

a first processing module provided with a first series of steps for receiving, physically screening, and physico-chemically digesting a lignocellulosic feedstock by commingling and circulating therethrough an organic solvent separately provided thereto thereby extracting component parts therefrom, and separating said component parts into a cellulosic solids fraction and a first liquid fraction;

a second processing module provided with a second series of steps for producing at least a fuel-grade ethanol and a stillage from said cellulosic solids fraction and separating a plurality of a first class of lignin derivatives from said stillage;

a third processing module provided with a third series of steps comprising at least a first step for separating the first liquid fraction into a first filtrate and a second solids fraction comprising a plurality of a second class of lignin derivatives, a second step for separating the first filtrate into a second filtrate and a third solids fraction comprising a plurality of a third class of lignin derivatives, and a third step for separating furfurals from said second filtrate, a fourth step for recovering a portion of the organic solvent from the second filtrate by distillation thereby producing a stillage; and

a fourth processing module provided with a fourth series of steps for separating the stillage from the third processing module into at least an acetic acid-containing liquid fraction, a plurality of a fourth class of lignin derivatives, a lipophylic extractives fraction, a monosaccharide sugar syrup, and a solid waste material.

2. A modular process according to claim 1, additionally provided with a fifth processing module comprising an anaerobic digestion module configured for processing at least one of the acetic acid-containing liquid fraction, the monosaccharide sugar syrup, and the solid waste material separated in the fourth processing module, into at least a collectable biogas and a liquid effluent.

3. A modular process according to claim 1, wherein the organic solvent comprises at least one solvent selected from the group containing short-chain alcohols and ketones.

4. A modular process according to claim 3, wherein the organic solvent comprises at least one short-chain alcohol selected from the group containing methanol, ethanol, butanol, propanol, and aromatic alcohols.

5. A modular process according to claim 3, wherein the organic solvent comprises at least acetone.

6. A modular process according to claim 1, wherein the first processing module is configured to continuously receive, physically process, and physico-chemically digest a lignocellulosic feedstock thereby continuously producing the cellulosic solids fraction and the first liquid fraction.

7. A modular process according to claim 6, wherein the first series of steps comprises steps for physically separating non-lignocellulosic materials from the lignocellulosic feedstock, delivering said lignocellulosic feedstock into a first end of a heatable and pressurizable digestion vessel, said vessel heated and pressurized, conveying said lignocellulosic feedstock to about a second end of the digestion vessel, commingling said lignocellulosic feedstock with said organic solvent and producing therefrom the cellulosic solids fraction and the first liquid fraction, discharging the solids fraction from about the second end of the digestion vessel, and discharging the first liquid fraction from about the first end of the digestion vessel.

8. A modular process according to claim 7, wherein the organic solvent is commingled and circulated through the lignocellulosic feedstock by a method selected from the group containing:

(a) a first method comprising counterflowing the organic solvent from about the second end to about the first end the digestion vessel, and (b) a second method comprising re-circulating the organic solvent therewithin and about the digestion vessel.

9. A modular process according to claim 7, wherein the first series of steps additionally comprises steps for first controllably saturating the lignocellulosic feedstock with a heated organic solvent for a selected period of time, and then for controllably removing the heated organic solvent from the lignocellulosic feedstock prior to delivering said lignocellulosic feedstock into about the first end of the digestion vessel.

10. A modular process according to claim 1, wherein the second series of steps comprises steps for controllably reducing the viscosity of the cellulosic solids fraction, controllably digesting the reduced-viscosity cellulosic solids fraction to produce a second liquid fraction comprising at least soluble sugars, controllably fermenting the second liquid fraction to produce a beer therefrom, distilling the beer to produce and separate the fuel-grade ethanol and the stillage, and separating the stillage into the first class of lignin derivatives and a de-lignified stillage.

11. A modular process according to claim 10, wherein the second series of steps additionally comprises a step for adding an enzyme preparation configured for controllably digesting the reduced-viscosity cellulosic solids fraction, said enzyme preparation comprising at least one enzyme selected from the group consisting of endo-β

-1,4-glucanases, cellobiohydrolases, cellulases, hemicellulases, β

-glucosidases, β

-xylosidases, xylanases, α

-amylases, β

-amylases, pullulases, and esterases.

12. A modular process according to claim 10, wherein the second series of steps additionally comprises a step for adding an inoculum preparation configured for controllably fermenting the second liquid fraction, the inoculum preparation comprising at least one microbial strain selected from a group containing yeast strains, fungal strains and bacterial strains.

13. A modular process according to claim 12, wherein the inoculum preparation comprises at least one microbial strain selected from a group containing naturally occurring and genetically engineered Saccharomyces spp. strains, Pichia spp. strains, Aspergillus spp. strains, Trichoderma spp. strains, Escherichia coli strains, Zymomonas spp. strains, Clostridium spp. strains, and Corynebacterium spp. strains.

14. A modular process according to claim 10, wherein said digestion step and said fermentation step are concurrently performed within a single vessel.

15. A modular process according to claim 10, wherein said de-lignified stillage is used to controllably reduce the viscosity of the cellulosic solids fraction.

16. A modular process according to claim 1, wherein the third series of steps additionally comprises steps for controllably intermixing at least a portion of the recovered organic solvent with a portion of the fuel-grade ethanol produced by the second series of steps, and then recycling the intermixed recovered organic solvent and fuel-grade ethanol into the first processing module.

17. A modular process according to claim 1, additionally provided with a sixth processing module comprising a fermentation module configured for receiving, fermenting and distilling therein said monosaccharide sugar syrup, and for separating therefrom a distillate comprising at least 1,3-propanediol and a stillage comprising at least lactic acid.

18. A modular process according to claim 2, wherein the anaerobic digestion module comprises a first step of biologically liquefying said solid waste material thereby producing a third liquid fraction, a second step of biologically acidifying the third liquid fraction thereby producing a liquid organic acid stream therefrom, a third step of biologically acetifying the liquid organic stream thereby producing at least acetic acid, and a fourth step of biologically producing at least a biogas and a liquid effluent from said acetic acid.

19. A modular process according to claim 18, wherein:

(a) the first step in the anaerobic digestion module is additionally provided with an inoculation step wherein an

inoculum comprising at least one microbial strain selected from a group containing at least naturally occurring and genetically engineered Enterobacter sp., is controllably commingled with said solid waste material;

(b) the second step in the anaerobic digestion module is additionally provided with an inoculation step wherein an inoculum comprising at least one microbial strain selected from a group containing at least naturally occurring and genetically engineered Bacillus sp., Lactobacillus sp. and Streptococcus sp., is controllably commingled with said third liquid fraction;

(c) the third step in the anaerobic digestion module is additionally provided with an inoculation step wherein an inoculum comprising at least one microbial strain selected from a group containing at least naturally occurring and genetically engineered Acetobacter sp., Gluconobacter sp., and Clostridium sp., is controllably commingled with said liquid organic acid stream; and

(d) the fourth step in the anaerobic digestion module is additionally provided with an inoculation step wherein an inoculum comprising at least one microbial strain selected from a group containing at least naturally occurring and genetically engineered Methanobacteria sp., Methanococci sp., and Methanopyri sp., is controllably commingled with said at least acetic acid.

20. A modular process according to claim 18, wherein a portion of the liquid monosaccharide sugar syrup produced in the fourth processing module is controllably delivered to the second step of the anaerobic digestion module for acidification therein.