Utilization of poly(ethylene terephthalate) plastic and composition-modified barium titanate powders in a matrix that allows polarization and the use of integrated-circuit technologies for the production of lightweight ultrahigh electrical energy storage units (EESU)
First Claim
1. An electrical-energy-storage unit fabricated by a method, the method comprising:
- a) cooling poly(ethylene terephthalate) plastic pellets to −
150°
C. by a cooling system;
b) feeding the poly(ethylene terephthalate) plastic pellets at −
150°
C. into a jet pulverizing mill to pulverize the poly(ethylene terephthalate) plastic pellets to a submicron size poly(ethylene terephthalate) plastic powder;
c) cooling aluminum powder to −
150°
C.;
d) feeding the aluminum powder into a jet pulverizing mill to pulverize the aluminum powder to a submicron size;
e) forming a first screen-printing ink from alumina-coated composition-modified barium titanate ceramic powder, the poly(ethylene terephthalate) plastic powder, and a binder, the binder including nitrocellulose, glycerol, and isopropyl alcohol;
f) forming a second screen-printing ink from the poly(ethylene terephthalate) plastic powder and the binder;
g) forming a third screen-printing ink from the aluminum powder and the binder;
h) wherein each ink is independently mixed in an associated tank that has the capability to mechanical mix, provide ultrasonic agitation, and high-impact multiple oppositely directed streams;
i) independently delivering each ink from its associated tank to an associated station of a screen-printing system via high-pressure pumps to a line manifold with several equal-spaced holes located at an edge of each printing screen;
j) screen-printing a basis layer of the second screen-printing ink onto a flat polytetrafluoroethylene coated stainless steel plate;
k) screen-printing a second layer of the third screen-printing ink via a stencil for an electrode layer;
l) screen-printing as part of the second layer and surrounding the electrode layer on three sides, the second screen-printing ink via a stencil onto the first layer;
m) screen-printing a third layer of the first screen-printing ink via a stencil onto the second layer, the third layer serving as an active dielectric layer;
n) screen-printing as part of the third layer and surrounding the active dielectric layer on four sides, the second screen-printing ink via a stencil onto the second layer;
o) screen-printing a fourth layer of the third screen-printing ink via a stencil onto the third layer, the fourth layer serving as an opposite electrode to the active dielectric layer;
p) screen-printing as part of the fourth layer and surrounding the opposite electrode on three sides, the second screen-printing ink via a stencil onto the third layer;
q) repeating steps m through p 100 times to fabricate multilayer sheets;
r) after each screen-printing, processing the multilayer sheets by an inline oven which has multiple temperature zones that range from 40°
C. to 150°
C. at a speed, such that the through times are 10 seconds for the electrode layers and 60 seconds for the dielectric layers;
s) dicing the multilayer sheets into individual elements;
t) placing the elements into indentations of coated stainless steel trays and inserting the trays into a hot isostatic pressing oven to process the elements at a temperature of 180°
C. and a pressure of 100 bar with a total time of 45 minutes;
u) bonding together ten of said elements with an adhesive having a curing temperature of 80°
C. for a duration of 10 minutes to create a component;
v) abrasively cleaning the component to expose alternately offset interleaved aluminum electrodes to each of the two opposite sides of the component and bonding aluminum end caps to the component sides that have the exposed electrodes;
w) placing the component into an oven and ramping the temperature to 180°
C. over 20 minutes, applying +2000 V to a first set of the electrodes and −
2000 V to a second set of the electrodes for 5 minutes;
x) assembling the component into a first level array;
y) stacking a number of the first level arrays on top of one another; and
z) packaging the array stack into the electrical energy storage unit.
1 Assignment
0 Petitions
Accused Products
Abstract
An electrical-energy-storage unit (EESU) has as a basis material a high-permittivity composition-modified barium titanate ceramic powder. This powder is single coated with aluminum oxide and then immersed in a matrix of poly(ethylene terephthalate) (PET) plastic for use in screen-printing systems. The ink that is used to process the powders via screen-printing is based on a nitrocellulose resin that provide a binder burnout, sintering, and hot isostatic pressing temperatures that are allowed by the PET plastic. These lower temperatures that are in the range of 40° C. to 150° C. also allows aluminum powder to be used for the electrode material. The components of the EESU are manufactured with the use of conventional ceramic and plastic fabrication techniques which include screen printing alternating multilayers of aluminum electrodes and high-permittivity composition-modified barium titanate powder, sintering to a closed-pore porous body, followed by hot-isostatic pressing to a void-free body. The 31,351 components are configured into a multilayer array with the use of a solder-bump technique as the enabling technology so as to provide a parallel configuration of components that has the capability to store at least 52.22 kW·h of electrical energy. The total weight of an EESU with this amount of electrical energy storage is 281.56 pounds including the box, connectors, and associated hardware.
116 Citations
16 Claims
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1. An electrical-energy-storage unit fabricated by a method, the method comprising:
-
a) cooling poly(ethylene terephthalate) plastic pellets to −
150°
C. by a cooling system;b) feeding the poly(ethylene terephthalate) plastic pellets at −
150°
C. into a jet pulverizing mill to pulverize the poly(ethylene terephthalate) plastic pellets to a submicron size poly(ethylene terephthalate) plastic powder;c) cooling aluminum powder to −
150°
C.;d) feeding the aluminum powder into a jet pulverizing mill to pulverize the aluminum powder to a submicron size; e) forming a first screen-printing ink from alumina-coated composition-modified barium titanate ceramic powder, the poly(ethylene terephthalate) plastic powder, and a binder, the binder including nitrocellulose, glycerol, and isopropyl alcohol; f) forming a second screen-printing ink from the poly(ethylene terephthalate) plastic powder and the binder; g) forming a third screen-printing ink from the aluminum powder and the binder; h) wherein each ink is independently mixed in an associated tank that has the capability to mechanical mix, provide ultrasonic agitation, and high-impact multiple oppositely directed streams; i) independently delivering each ink from its associated tank to an associated station of a screen-printing system via high-pressure pumps to a line manifold with several equal-spaced holes located at an edge of each printing screen; j) screen-printing a basis layer of the second screen-printing ink onto a flat polytetrafluoroethylene coated stainless steel plate; k) screen-printing a second layer of the third screen-printing ink via a stencil for an electrode layer; l) screen-printing as part of the second layer and surrounding the electrode layer on three sides, the second screen-printing ink via a stencil onto the first layer; m) screen-printing a third layer of the first screen-printing ink via a stencil onto the second layer, the third layer serving as an active dielectric layer; n) screen-printing as part of the third layer and surrounding the active dielectric layer on four sides, the second screen-printing ink via a stencil onto the second layer; o) screen-printing a fourth layer of the third screen-printing ink via a stencil onto the third layer, the fourth layer serving as an opposite electrode to the active dielectric layer; p) screen-printing as part of the fourth layer and surrounding the opposite electrode on three sides, the second screen-printing ink via a stencil onto the third layer; q) repeating steps m through p 100 times to fabricate multilayer sheets; r) after each screen-printing, processing the multilayer sheets by an inline oven which has multiple temperature zones that range from 40°
C. to 150°
C. at a speed, such that the through times are 10 seconds for the electrode layers and 60 seconds for the dielectric layers;s) dicing the multilayer sheets into individual elements; t) placing the elements into indentations of coated stainless steel trays and inserting the trays into a hot isostatic pressing oven to process the elements at a temperature of 180°
C. and a pressure of 100 bar with a total time of 45 minutes;u) bonding together ten of said elements with an adhesive having a curing temperature of 80°
C. for a duration of 10 minutes to create a component;v) abrasively cleaning the component to expose alternately offset interleaved aluminum electrodes to each of the two opposite sides of the component and bonding aluminum end caps to the component sides that have the exposed electrodes; w) placing the component into an oven and ramping the temperature to 180°
C. over 20 minutes, applying +2000 V to a first set of the electrodes and −
2000 V to a second set of the electrodes for 5 minutes;x) assembling the component into a first level array; y) stacking a number of the first level arrays on top of one another; and z) packaging the array stack into the electrical energy storage unit. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)
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Specification