Polarizing, photochromic devices and methods of making the same

• US 7,471,436 B2
• Filed: 10/31/2006
• Issued: 12/30/2008
• Est. Priority Date: 07/01/2003
• Status: Active Grant

• Current Assignee: Transitions Optical, Inc. (EssilorLuxottica SA)
• Original Assignee: Transitions Optical, Inc. (EssilorLuxottica SA)
• Inventors: He, Meng, Shao, Jiping, Blackburn, Forrest R., Kumar, Anil, Foller, Peter C., Kellar, Terry A. II
• Primary Examiner(s): Dang; Hung X
• Assistant Examiner(s): Tra; Tuyen Q
• Application Number:
  US11/590,189
• Publication Number:
  US 20070053049A1
• Time in Patent Office: 791 Days
• Field of Search: 359/241, 359/270, 359/271, 359/272, 359/273, 359/485, 359/488, 359/489, 359/493, 351/44, 351/163, 349/13
• US Class Current: 359/241
• CPC Class Codes: C07D 311/94 condensed with rings other than six-membered or with ring systems containing such rings
• CPC Class Codes: C07D 405/10 linked by a carbon chain containing aromatic rings
• CPC Class Codes: C07D 405/14 containing three or more hetero rings
• CPC Class Codes: C07D 498/10 Spiro-condensed systems
• CPC Class Codes: C09B 57/00 Other synthetic dyes of known constitution
• CPC Class Codes: C09K 19/60 Pleochroic dyes
• CPC Class Codes: G02B 5/23 Photochromic filters
• CPC Class Codes: G02B 5/3016 involving passive liquid crystal elements optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528
• CPC Class Codes: G02B 5/3025 Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state G02B5/3008, G02B5/3016 take precedence
• CPC Class Codes: G02F 1/1335 Structural association of cells with optical devices, e.g. polarisers or reflectors
• CPC Class Codes: G03C 1/73 containing organic compounds
• CPC Class Codes: Y10T 428/24934 including paper layer

Abstract

A security element connected to at least a portion of a substrate, the security element including an at least partial coating having a first state and a second state connected to at least a portion of the substrate, the at least partial coating being adapted to switch from a first state to a second state in response to at least actinic radiation, to revert back to the first state in response to thermal energy, and to linearly polarize at least transmitted radiation in at least one of the first state and the second state.

Claims

1. A security element connected to at least a portion of a substrate, the security element comprising an at least partial coating having a first state and a second state connected to at least a portion of the substrate, the at least partial coating being adapted to switch from a first state to a second state in response to at least actinic radiation, to revert back to the first state in response to thermal energy, and to linearly polarize at least transmitted radiation in at least one of the first state and the second state, wherein the at least partial coating comprises at least one photochromic-dichroic compound having an average absorption ratio of at least 1.5 in the activated state.

2. The security element of claim 1 wherein the security element is at least one of a security mark and an authentication mark.

3. The security element of claim 2 wherein the at least a portion of the substrate to which the coating is connected is coated with a reflective material.

4. The security element of claim 1 wherein the substrate is chosen from transparent substrates and reflective substrates.

5. The security element of claim 1 wherein the substrate is chosen from untinted substrates, tinted substrates, photochromic substrates, tinted-photochromic substrates, linearly polarizing substrates, circularly polarizing substrates, and elliptically polarizing substrates.

6. The security element of claim 1 wherein the substrate is comprises access cards and passes;

negotiable instruments and non-negotiable instruments;

government documents;

consumer goods;

credit cards; and

/or merchandise tags, labels and packaging.

7. The security element of claim 1 further comprising at least one additional at least partial coating chosen from linearly polarizing coatings, circularly polarizing coatings, elliptically polarizing coatings, photochromic coatings, reflective coatings, and tinted coatings connected to at least a portion of the substrate.

8. The security element of claim 1 further comprising at least one sheet chosen from linearly polarizing sheets, circularly polarizing sheets, elliptically polarizing sheets, photochromic sheets, reflective sheets, tinted sheets, retarder sheets, and wide-angle view sheets connected to at least a portion of the substrate.

9. A method of making a security element comprising forming an at least partial coating on at least a portion of the substrate, the at least partial coating comprising at least one at least partially aligned thermally reversible photochromic-dichroic compound having an average absorption ratio of at least 1.5 in the activated state.

10. The method of claim 9 further comprising forming at least one additional at least partial coating chosen from linearly polarizing coatings, circularly polarizing coatings, elliptically polarizing coatings, photochromic coatings, reflective coatings, tinted coatings, retarder coatings, and wide-angle view coatings on at least a portion of the substrate prior to forming the at least one photochromic-dichroic compound that is at least partially aligned on the at least a portion of the substrate.

11. The method of claim 9 further comprising forming at least one additional at least partial coating chosen from linearly polarizing coatings, circularly polarizing coatings, elliptically polarizing coatings, photochromic coatings, reflective coatings, tinted coatings, retarder coatings, and wide-angle view coatings on at least a portion of the substrate after forming the at least one photochromic-dichroic compound that is at least partially aligned on the at least a portion of the substrate.

12. The method of claim 9 further comprising applying a sheet chosen from linearly polarizing sheets, circularly polarizing sheets, elliptically polarizing sheets, photochromic sheets, reflective sheets, tinted sheets, retarder sheets, and wide-angle view sheets to at least a portion of the substrate prior to forming the at least one photochromic-dichroic compound that is at least partially aligned on the at least a portion of the substrate.

13. The method of claim 9 further comprising applying a sheet chosen from linearly polarizing sheets, circularly polarizing sheets, elliptically polarizing sheets, photochromic sheets, reflective sheets, tinted sheets, retarder sheets, and wide-angle view sheets to at least a portion of the substrate after forming the at least one photochromic-dichroic compound that is at least partially aligned on the at least a portion of the substrate.