Highlighting marking compositions, highlighting kits, and highlighted complexes

• US 7,488,380 B2
• Filed: 05/11/2006
• Issued: 02/10/2009
• Est. Priority Date: 10/07/2003
• Status: Expired due to Fees

• Current Assignee: Sanford LP (Newell Brands Inc.)
• Original Assignee: Sanford LP (Newell Brands Inc.)
• Inventors: Duong, Cindy, Kwan, Wing Sum Vincent
• Primary Examiner(s): Lorengo; J. A.
• Assistant Examiner(s): FAISON, VERONICA F
• Application Number:
  US11/432,816
• Publication Number:
  US 20070017413A1
• Time in Patent Office: 1,006 Days
• Field of Search: 106/31.32, 106/31.64
• US Class Current: 106/31.32
• CPC Class Codes: C09D 11/037 characterised by the pigment
• CPC Class Codes: C09D 11/17 characterised by colouring agents

Abstract

A highlighting (or marking) composition, such as an ink, including a non-eradicable colorant, an eradicable colorant; a kit including a first marking instrument comprising the highlighting mixture and a second marking instrument comprising an eradicator fluid; a colorant complex including a colorless or substantially colorless eradicable dye, a non-eradicable dye, and an eradicator; and methods of applying an eradicator to at least a portion of a marking made with a highlighting composition, are described herein.

Claims

1. A highlighting composition comprising:

at least one eradicable dye capable of becoming substantially colorless or of changing color;

at least one non-eradicable dye incapable of becoming substantially colorless or of changing color; and

at least one solvent,

wherein the non-eradicable dye is selected from the group consisting of reactive dyes and direct dyes.

2. The highlighting composition of claim 1, wherein said eradicable dye is selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof.

3. The highlighting composition of claim 1, wherein said eradicable dye comprises a pH indicator.

4. The highlighting composition of claim 1, further comprising a pH indicator that is substantially colorless.

5. The highlighting composition of claim 4, wherein said substantially colorless pH indicator is selected from the group consisting of o-Cresolphthalein, Eosin B, Phenolphthalein, Ethyl Red, Quinaldine Red, and combinations thereof.

6. The highlighting composition of claim 1, wherein said highlighting composition is substantially free of pigments.

7. The highlighting composition of claim 1, wherein said eradicable dye is present in an amount from about 0.01 to about 30 wt. %.

8. The highlighting composition of claim 1, wherein said non- eradicable dye is present in an amount from about 0.01 to about 30 wt. %.

9. The highlighting composition of claim 1, wherein said non-eradicable dye is substantially insoluble in water.

10. The highlighting composition of claim 1, wherein said non-eradicable dye is substantially insoluble in an organic solvent.

11. The highlighting composition of claim 1, further comprising a binder resin.

12. A marking instrument containing the highlighting composition of claim 1.

13. An ink-jet cartridge containing the highlighting composition of claim 1.

14. A highlighting ink kit, comprising a first marking instrument comprising a highlighting composition of claim 1 and a second marking instrument comprising an eradicator.

15. The highlighting ink kit of claim 14, wherein said eradicator is dissolved or dispersed in an aqueous mixture and is selected from the group consisting of a base, an acid, an oxidizing agent, a reducing agent, and combinations thereof.

16. The highlighting ink kit of claim 15, wherein the non-eradicable dye is substantially insoluble in water.

17. The highlighting ink kit of claim 14, wherein said eradicator is dissolved or dispersed in a mixture comprising a non-aqueous fluid and is selected from the group consisting of a base, an acid, an oxidizing agent, a reducing agent, and combinations thereof.

18. The highlighting ink kit of claim 17, wherein the non-eradicable dye is substantially insoluble in the non-aqueous fluid.

19. The highlighting ink kit of claim 18, wherein the non-aqueous fluid comprises at least about 50 weight percent of a polar aprotic solvent.

22. A method of highlighting, comprising making a marking with the highlighting composition of claim 1, and applying an eradicator to at least a portion of said marking to form a highlighted marking.

24. A method of rotary printing comprising transferring the highlighting composition of claim 1 from a first cylinder to a substrate carried by a second cylinder.

20. A highlighting ink kit comprising:

a first marking instrument comprising a highlighting composition comprising at least one eradicable dye capable of becoming substantially colorless or of changing color, at least one non-eradicable dye incapable of becoming substantially colorless or of changing color, and at least one solvent;

a second marking instrument comprising an eradicator; and

a third marking instrument comprising an agent capable of substantially converting an eradicated dye back to its original form.

21. The highlighting ink kit of claim 20, wherein said agent is selected from the group consisting of a base, an acid, an oxidizing agent, a reducing agent, and combinations thereof.

23. A method of reversibly highlighting, comprising:

making a marking with a highlighting composition comprising at least one eradicable dye capable of becoming substantially colorless or of changing color, at least one non-eradicable dye incapable of becoming substantially colorless or of changing color, and at least one solvent,

applying an eradicator to at least a portion of said marking to form a highlighted marking, and

applying an agent capable of substantially converting the highlighted marking back to its original form.

25. A highlighting composition, comprising:

at least one eradicable colorant capable of becoming substantially colorless or of changing color;

at least one non-eradicable dye incapable of becoming substantially colorless or of changing color;

at least one substantially colorless pH indicator or at least one pH indicator having substantially the same color as the combination of the eradicable colorant(s) and the non- eradicable colorant(s) in the mixture; and

at least one solvent,

wherein the non-eradicable dye is selected from the group consisting of reactive dyes and direct dyes.

26. The highlighting composition of claim 25, wherein said composition is a primary color selected from the group consisting of red, blue, and yellow.

27. The highlighting composition of claim 25, wherein said eradicable colorant comprises an eradicable dye selected from the group consisting of triarylmethane dyes, diarylmethane dyes, methine dyes, and combinations thereof.

28. The highlighting composition of claim 25, wherein said pH indicator is selected from the group consisting of Congo Red, o-Cresolphthalein, Eosin B, Phenolphthalein, Ethyl Red, Quinaldine Red, and combinations thereof.

29. A marking instrument containing the highlighting composition of claim 25.

30. A highlighting ink kit, comprising a first marking instrument comprising the highlighting composition of claim 25 and a second marking instrument comprising an eradicator.

31. A method of highlighting, comprising making a marking with the highlighting composition of claim 25, and applying an eradicator to at least a portion of said marking to form a highlighted marking.

33. A method of rotary printing comprising transferring the highlighting composition of claim 25 to a substrate carried by a second sylinder.

34. An injk-jet cartridge containing the highlighting composition of claim 25.

32. A method of reversibly highlighting, comprising:

making a marking with the highlighting composition comprising at least one eradicable colorant capable of becoming substantially colorless or of changing color, at least one non-eradicable colorant incapable of becoming substantially colorless or of changing color, at least one substantially colorless pH indicator or at least one pH indicator having substantially the same color as the combination of the eradicable colorant(s) and the non-eradicable colorant(s) in the mixture, and at least one solvent,

applying an eradicator to at least a portion of said marking to form a highlighted marking, and

applying an agent capable of substantially converting the highlighted marking back to its original form.