Encapsulation compositions and processes for preparing the same

• US 7,488,503 B1
• Filed: 03/31/2004
• Issued: 02/10/2009
• Est. Priority Date: 03/31/2003
• Status: Active Grant

• Current Assignee: Mccormick & Company Incorporated
• Original Assignee: Mccormick & Company Incorporated
• Inventors: Zasypkin, Dmitriy, Porzio, Michael A.
• Primary Examiner(s): PADEN, CAROLYN A
• Application Number:
  US10/812,883
• Time in Patent Office: 1,777 Days
• Field of Search: 426/96, 426/98, 426/103, 426/658, 426/293, 424/439, 424/408
• US Class Current: 426/293
• CPC Class Codes: A23L 27/72 Encapsulation
• CPC Class Codes: A23P 10/30 Encapsulation of particles, e.g. foodstuff additives

Abstract

Matrix compositions which contain a mixture of two different food polymers are useful for encapsulating encapsulates, such as flavoring agents.

Claims

1. An encapsulation composition, comprising:

(A) an encapsulate, encapsulated in;

(B) a glassy matrix,

wherein said glassy matrix is;

(a) a composition, comprising;

(a₁) 5 to 95% by weight, based on the total weight of said composition (a), of a first food polymer;

(a₂) 5 to 90% by weight, based on the total weight of said composition (a), of a second food polymer; and

(a₃) 0 to 45% by weight, based on the total weight of said composition (a), of a component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof,

wherein said first food polymer is an n-octenylsuccinic anhydride-modified starch, and

wherein said second food polymer is selected from the group consisting of an exudate gum, a bacterial gum, an extract gum, a seed gum, a pectin, a pregelatinized starch, agar agar, a hydrogenated starch hydrolyzate, a modified cellulose, a seaweed hydrocolloid extract, a protein, a fractionated protein, a hydrolyzed protein, and chitosan.

2. The composition of claim 1, which has at least one glass transition temperature >

30°

C.

3. The composition of claim 1, which has at least one glass transition temperature >

40°

C.

4. The composition of claim 1, which has two glass transition temperatures.

5. The composition of claim 1, wherein said matrix (B) is a composition comprising 1 to 45% by weight, based on the total weight of said composition (a), of said component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof.

6. The composition of claim 1, wherein said encapsulate is selected from the group consisting of a medication, a pesticide, a vitamin, a preservative, and a flavoring agent.

7. The composition of claim 6, wherein said encapsulate is a flavoring agent.

8. The composition of claim 7, wherein said flavoring agent is selected from the group consisting of a natural extract, an oleoresin, an essential oil, a protein hydrolyzate, an aqueous reaction flavor, and a compounded flavor.

9. The composition of claim 1, wherein said second food polymer is at least one member selected from the group consisting of gum arabic, gum karaya, gum tragacanth, konjac, larch gum, locust bean gum, guar gum, xanthan gum, sodium carboxymethyl cellulose, agar agar, type A gelatin, type B gelatin, and mixtures thereof.

10. An encapsulate composition, prepared by a process comprising:

(i) mixing a matrix composition (B) with a liquid plasticizer and an encapsulate (A) in an extruder, to obtain a melted mixture comprising encapsulate (A) and matrix (B); and

(ii) extruding said melted mixture, to obtain said composition,

wherein said encapsulate (A) is encapsulated in a glassy matrix of said matrix composition (B), and

wherein said matrix composition (B) is selected from the group consisting of;

(a) a composition, comprising;

(a₁) 5 to 95% by weight, based on the total weight of said composition (a), of a first food polymer;

(a₂) 5 to 90% by weight, based on the total weight of said composition (a), of a second food polymer; and

(a₃) 0 to 45% by weight, based on the total weight of said composition (a), of a component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof,

wherein said first food polymer is an n-octenylsuccinic anhydride-modified starch, and

wherein said second food polymer is selected from the group consisting of an exudate gum, a bacterial gum, an extract gum, a seed gum, a pectin, a pregelatinized starch, agar agar, a hydrogenated starch hydrolyzate, a modified cellulose, a seaweed hydrocolloid extract, a protein, a fractionated protein, a hydrolyzed protein, and chitosan.

11. The composition of claim 10, which has at least one glass transition temperature >

30°

C.

12. The composition of claim 10, which has at least one glass transition temperature >

40°

C.

13. The composition of claim 10, which has two glass transition temperatures.

14. The composition of claim 10, wherein said encapsulate is selected from the group consisting of a medication, a pesticide, a vitamin, a preservative, and a flavoring agent.

15. The composition of claim 14, wherein said encapsulate is a flavoring agent.

16. The composition of claim 15, wherein said flavoring agent is selected from the group consisting of a natural extract, an oleoresin, an essential oil, a protein hydrolyzate, an aqueous reaction flavor, and a compounded flavor.

17. The composition of claim 10, wherein said matrix (B) is a composition comprising 1 to 45% by weight, based on the total weight of said composition (a), of said component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof.

18. The composition of claim 10, wherein said second food polymer is at least one member selected from the group consisting of gum arabic, gum karaya, gum tragacanth, konjac, larch gum, locust bean gum, guar gum, xanthan gum, sodium carboxymethyl cellulose, agar agar, type A gelatin, type B gelatin, and mixtures thereof.

19. A process for preparing an encapsulation composition, said process comprising:

(i) mixing a matrix composition (B) with a liquid plasticizer and an encapsulate (A) in an extruder, to obtain a melted mixture comprising encapsulate (A) and matrix (B); and

(ii) extruding said melted mixture, to obtain said composition,

wherein said encapsulate (A) is encapsulated in a glassy matrix of said matrix composition (B), and

wherein said matrix composition (B) is selected from the group consisting of;

(a) a composition, comprising;

(a₁) 5 to 95% by weight, based on the total weight of said composition (a), of a first food polymer;

(a₂) 5 to 90% by weight, based on the total weight of said composition (a), of a second food polymer; and

(a₂) 0 to 45% by weight, based on the total weight of said composition (a), of a component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof,

wherein said first food polymer is an n-octenylsuccinic anhydride-modified starch, and

wherein said second food polymer is selected from the group consisting of an exudate gum, a bacterial gum, an extract gum, a seed gum, a pectin, a pregelatinized starch, agar agar, a hydrogenated starch hydrolyzate, a modified cellulose, a seaweed hydrocolloid extract, a protein, a fractionated protein, a hydrolyzed protein, and chitosan.

20. The process of claim 19, wherein said encapsulate is selected from the group consisting of a medication, a pesticide, a vitamin, a preservative, and a flavoring agent.

21. The process of claim 20, wherein said encapsulate is a flavoring agent.

22. The process of claim 21, wherein said flavoring agent is selected from the group consisting of a natural extract, an oleoresin, an essential oil, a protein hydrolyzate, an aqueous reaction flavor, and a compounded flavor.

23. The process of claim 19, wherein said matrix (B) is a composition comprising 1 to 45% by weight, based on the total weight of said composition (a), of said component selected from the group consisting of a sugar, a polyol, a corn syrup solid, and mixtures thereof.

24. The process of claim 19, wherein said second food polymer is at least one member selected from the group consisting of gum arabic, gum karaya, gum tragacanth, konjac, larch gum, locust bean gum, guar gum, xanthan gum, sodium carboxymethyl cellulose, agar agar, type A gelatin, type B gelatin, and mixtures thereof.