Chemical derivatization of silica coated fullerenes and use of derivatized silica coated fullerenes

• US 7,491,376 B2
• Filed: 06/12/2006
• Issued: 02/17/2009
• Est. Priority Date: 06/12/2006
• Status: Active Grant

• Current Assignee: NewCyte, Inc. (Natcore Technology, Inc.)
• Original Assignee: NewCyte, Inc. (Natcore Technology, Inc.)
• Inventors: Guzelian, Andrew A., Barron, Andrew R., Flood, Dennis J.
• Primary Examiner(s): Saad; Erin Barry
• Assistant Examiner(s): SAAD, ERIN BARRY
• Application Number:
  US11/451,110
• Publication Number:
  US 20080233040A1
• Time in Patent Office: 981 Days
• Field of Search: 423/335, 423/445.B, 423/460, 423/DIG.39, 423/DIG.40, 977/734, 977/735, 977/742
• US Class Current: 423/445.00B
• CPC Class Codes: C07B 2200/11 Compounds covalently bound to a solid support
• CPC Class Codes: C07F 7/1804 Compounds having Si-O-C linkages Si-O-acyl linkages C07F7/1896
• CPC Class Codes: Y10S 423/39 Fullerene, e.g. c60, c70 derivative and related process
• CPC Class Codes: Y10S 423/40 Fullerene composition
• CPC Class Codes: Y10S 977/734 Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
• CPC Class Codes: Y10S 977/735 Carbon buckyball
• CPC Class Codes: Y10S 977/742 Carbon nanotubes, CNTs
• CPC Class Codes: Y10T 428/2993 Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]

Abstract

This invention is directed to a new composition of matter in the form of chemically derivatized silica coated fullerenes, including silica coated C₆₀ molecules and silica coated carbon nanotubes, processes for making the same and to uses for the derivatized silica coated fullerenes. Included among many uses in chemical, physical or biological fields of use, but not limited thereto, are high speed, low loss electrical interconnects for nanoscale electronic devices, components and circuits. In one embodiment, this invention also provides a method for preparing silica coated fullerenes having substituents attached to the surface of silica coated fullerenes by reacting silica coated fullerenes with a wide range of organic or inorganic chemical species in a gaseous or liquid state. Preferred substituents include but are not limited to organic groups and organic groups containing heteroatoms such as oxygen, nitrogen, sulfur, and halogens. The identity of the surface functional group is chosen to provide desirable properties to the silica coated fullerenes including but not limited to solubility, miscibility, stickiness, and melting point. The present invention also describes the application of surface functionalized silica coated fullerenes as components of polymer blends and composites.

Claims

1. A method for derivatizing the surface of a silica coated fullerene, including the surface of a silica coated C₆₀ molecule and sidewall or endcaps of silica coated carbon nanotubes comprising:

(i) reacting silica coated fullerenes, including silica coated C₆₀ molecules and silica coated carbon nanotubes, with a derivatizing agent, and (ii) producing derivatized silica coated fullerenes, including derivatized silica coated C₆₀ molecules and derivatized sidewalls or endcaps of silica coated carbon nanotubes, wherein the silica coated carbon nanotubes generally have a length from about 5 nm to greater than 1000 nm.

2. A method for derivatizing the surface of a silica coated fullerene including the surface of a silica coated C₆₀ molecule and the sidewall or endcaps of a silica coated carbon nanotube comprising reacting the silica coated fullerene, including silica coated C₆₀ molecules and silica coated carbon nanotubes, with a derivatizing agent.

3. The method of claim 2, wherein the derivatizing agent is selected from the functional group consisting of a wide range of organic or inorganic chemical species.

4. The method of claim 3, wherein the functional group is an organic group.

5. The method of claim 4, wherein the organic group contains an aliphatic or aromatic hydrocarbon.

6. The method of claim 5, wherein the organic group contains a heteroatom containing functional group.

7. The method of claim 5, wherein the heteroatom is chosen from oxygen, nitrogen, boron, sulfur, a halogen, silicon, phosphorus, or a metal atom.

8. The method of claim 3, wherein the silica coated fullerene, including silica coated C₆₀ molecules and silica coated carbon nanotubes, is reacted with the derivatizing agent at a reaction temperature between about −

78°

C. and about 500°

C.

9. The method of claim 4, wherein the silica coated fullerene, including silica coated C₆₀ molecules and silica coated carbon nanotubes, is reacted with the derivatizing agent at a reaction temperature between about −

10°

C. and 100°

C.

10. A method for derivatizing the surface of a silica coated fullerene, including the surface of a silica coated C₆₀ molecule and the sidewall or endcaps of silica coated carbon nanotubes comprising:

(i) selecting a derivatizing agent; and

(ii) reacting the silica coated fullerenes with the derivatizing agent at a suitable reaction temperature in a suitable solvent or matrix.

11. The method of claim 10, wherein the solvent is the derivatizing agent.