Water-based asphalt coating composition

• US 7,491,756 B2
• Filed: 09/16/2005
• Issued: 02/17/2009
• Est. Priority Date: 09/16/2004
• Status: Active Grant

• Current Assignee: Tremco CPG UK Ltd. (RPM International Incorporated)
• Original Assignee: Tremco Incorporated (RPM International Incorporated)
• Inventors: Hernandez, Pamela, Peters, Stephen Robert
• Primary Examiner(s): Brunsman; David M
• Application Number:
  US11/228,823
• Publication Number:
  US 20060276559A1
• Time in Patent Office: 1,250 Days
• Field of Search: 524/60, 524/61
• US Class Current: 524/60
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/302 Water
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08K 5/0016 Plasticisers
• CPC Class Codes: C08L 21/02 Latex
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 7/02 Latex
• CPC Class Codes: C08L 75/00 Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 9/08 Latex
• CPC Class Codes: C08L 95/00 Compositions of bituminous materials, e.g. asphalt, tar, pitch
• CPC Class Codes: C08L 95/005 Aqueous compositions, e.g. emulsions
• CPC Class Codes: C09D 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09D 135/06 : Copolymers with vinyl aromatic monomers
• CPC Class Codes: C09D 153/02 : Vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: C09D 175/04 : Polyurethanes

Abstract

The present invention relates to multi-part coating compositions that comprise a first part which is an asphalt emulsion comprising water, asphalt, and a dispersion system and a second part which is a liquid polymer composition that lacks water. The asphalt emulsion and liquid polymer composition are combined in situ to provide a coating that has fast dry characteristics, and that quickly develops good water-resistance. Such compositions are useful as coatings on metal, wood, and other surfaces, where fast drying characteristics are important. Such compositions are particularly useful as coatings on substrates where early water-resistance of the coating is important, such as those surfaces which are routinely exposed to the outdoors.

Claims

1. A multipart system for preparing a coating composition in situ, the system comprising:

a) an emulsion comprising asphalt, water, and a dispersion system; and

b) a liquid polymer composition that lacks water;

wherein the asphalt emulsion and the liquid polymer composition are present in the multipart system at a ratio of 3;

1 or greater.

2. The multipart system of claim 1, wherein the asphalt emulsion and the liquid polymer composition are present in the system at a ratio of 17:

1 to 3;

1.

3. The multipart system of claim 1, wherein the asphalt emulsion further comprises one or more of the following emulsions:

natural rubber, styrene butadiene rubber, an acrylic resin, and a polyvinyl acetate, or any combination thereof.

4. The multipart system of claim 1, wherein the solids content of the asphalt emulsion is from 35 to 65% by weight.

5. The multipart system of claim 1, wherein the liquid polymer is chosen from one or more of the following:

a polyurethane, an acrylic polymer, styrene butadiene, a styrene-containing block polymer, a silicone polymer, or any combinations thereof.

6. The multipart system of claim 1, wherein the liquid polymer lacks a solvent.

7. The multipart system of claim 1, wherein the liquid polymer composition comprises a solvent.

8. The multipart system of claim 1, wherein the liquid polymer composition comprises calcium oxide, calcium carbonate, a plasticizer, or any combination thereof.

9. The multipart system of claim 1, wherein the liquid polymer composition comprises a polyurethane.

10. The multipart system of claim 1, wherein the liquid polymer composition comprises an acrylic polymer.

11. The multipart system of claim 1, wherein the liquid polymer composition comprises a silicone polymer.

12. The multipart system of claim 1, wherein the liquid polymer composition comprises a styrene block polymer.

13. The multipart system of claim 1, wherein the liquid polymer composition comprises styrene butadiene.

14. The multipart system of claim 1, further comprising a catalyst, wherein said catalyst is a separate part of the system or is included in the asphalt emulsion.

15. A method of coating a substrate comprising:

a) preparing a coating composition in situ,

wherein the coating composition is prepared by combining an emulsion comprising asphalt, water, and a dispersion system with a liquid polymer composition, wherein said liquid polymer composition lacks water and comprises a polyurethane, an acrylic polymer, styrene butadiene, a silicone polymer, a sytrene-containing block polymer, or any combination of said polymers, and,

wherein the asphalt emulsion and liquid polymer composition are combined at a ratio of 3;

1 or greater; and

b) applying the coating composition to the substrate.

16. The method of claim 15, wherein the method is performed without heating the coating composition.

17. The method of claim 15, wherein one or more layers of the coating composition are applied to the substrate, and wherein at least one of said one or more layers is 250 millimeters or more in thickness.

18. The method of claim 15, wherein a curing catalyst is incorporated into the coating composition prior to application of the coating composition to the substrate.

19. The method of claim 18, wherein the curing catalyst is a tin catalyst.

20. The method of claim 15, wherein the ratio of asphalt emulsion to liquid polymer composition ranges from 17:

1 to 3;

1.

21. A method of increasing the cure-through rate of a coating comprising an asphalt emulsion, comprising:

(a) providing an asphalt emulsion comprising asphalt, water, and a dispersion system,

(b) combining the asphalt emulsion of step a with a liquid polymer composition that lacks water to provide a coating composition, wherein the ratio of asphalt emulsion to liquid polymer composition is 3;

1 or greater,

(c) applying the coating composition of step b to a substrate;

wherein the cure-through rate of a coating formed from the coating composition of step b is faster than the cure through rate of a coating formed from the asphalt emulsion alone.

22. A method of preparing a weather-resistant, single-layer coating, having a thickness of 250 millimeters or greater, comprising

a) combining in situ an asphalt emulsion comprising water, asphalt, and a dispersion system with a non-emulsion, liquid polymer composition to provide a coating composition, wherein said non-emulsion liquid polymer composition lacks water and comprises a polyurethane, an acrylic polymer, styrene butadiene, a silicone polymer, a sytrene block polymer, or any combination of said polymers, and

wherein the ratio of asphalt emulsion to the non-emulsion polyurethane polymer composition is from 17:

1 to 3;

1; and

b) applying at least one layer of the coating composition to a substrate, wherein the at least one layer has a thick of 250 millimeters or greater.