Process for the production of animal feed and ethanol and novel animal feed

• US 7,494,675 B2
• Filed: 04/18/2006
• Issued: 02/24/2009
• Est. Priority Date: 04/19/2005
• Status: Active Grant

• Current Assignee: Archer Daniels Midland Company
• Original Assignee: Archer Daniels Midland Company
• Inventors: Doane, Perry H., Cecava, Michael J., Binder, Thomas P., Holzgraefe, David P., Abbas, Charles, Solheim, Leif P., Beery, Kyle E.
• Primary Examiner(s): Lilling; Herbert J.
• Application Number:
  US11/405,724
• Publication Number:
  US 20060251764A1
• Time in Patent Office: 1,043 Days
• Field of Search: None
• US Class Current: 426/12
• CPC Class Codes: A23K 10/12 by fermentation of natural products, e.g. of vegetable material, animal waste material or biomass
• CPC Class Codes: A23K 10/37 from waste material from hydrolysates of wood or straw A23K10/32; from molasses A23K10/33
• CPC Class Codes: A23K 10/38 from distillers' or brewers' waste
• CPC Class Codes: A23K 50/10 for ruminants
• CPC Class Codes: A23L 33/105 Plant extracts, their artificial duplicates or their derivatives
• CPC Class Codes: A23L 33/21 Addition of substantially indigestible substances, e.g. dietary fibres
• CPC Class Codes: A23L 7/107 Addition or treatment with enzymes not combined with fermentation with microorganisms
• CPC Class Codes: B02B 1/08 Conditioning grain with respect to temperature or water content air containing or ventilating of silos F24F; drying apparatus F26B; hygrometers G01N
• CPC Class Codes: B02B 3/00 Hulling; Husking; Decorticating decorticating textile fibres D01B1/14; Polishing; Removing the awns in threshing machines A01F12/42; Degerming
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 60/87 Re-use of by-products of food processing for fodder production

Abstract

A method for the production of ethanol and a modified animal feed is provided. The method replaces the starch in known corn-based animal feed with biomass fiber treated to make it more digestible by animals. The process includes wherein the pericarp and germ are removed from the corn kernel and processed for by-products. The starch and protein are also removed and separated. The starch is then fermented and distilled to ethanol and stillage. The bioavailable modified animal feed comprises the pericarp and germ removed from corn kernels and optionally by-products of the pericarp and germ processing, and lignocellulosic materials. The modified animal feed may optionally include energy materials such as animal and vegetable fats, vegetable soapstocks, or glycerin, and combinations thereof.

Claims

1. A method for processing corn kernels comprising the steps of:

removing the pericarp from said corn kernels to obtain a pericarp enriched fraction;

contacting at least one of the pericarp enriched fraction and a lignocellulosic by-product of agricultural processing with a fiber hydrolyzing agent to at least partially hydrolyze lignocellulosic fibers and obtain a treated fiber fraction;

removing the germ from said corn kernels, resulting in a starch and a protein;

separating said protein from said starch;

liquefying and saccharifying and fermenting said starch to produce a fermented starch broth;

recovering ethanol and distillers dried grains from the fermented starch broth; and

combining the treated fiber fraction with the distillers dried grains to form a modified distiller'"'"'s dried grain product.

2. The method of claim 1 including liquefying said separated starch before said saccharification and fermentation of said starch.

3. The method of claim 1 including wherein said step of removing said pericarp comprises the steps of:

chemically separating said pericarp from the remainder of said corn kernel by alkali debranning, acid debranning, or gaseous or liquid ammonia addition of said corn kernel; and

milling said separated pericarp.

4. The method of claim 1 including wherein said step of removing said pericarp comprises the steps of:

conditioning said corn kernels with steam or hot water having a temperature from about 50°

C. to about 99°

C.; and

milling said corn kernels to abrade and remove said pericarp.

5. The method of claim 1 including wherein step of removing said germ from said corn kernels comprises the steps of:

utilizing a lactic acid steeping to hydrolyze the chemical bonds between the endosperm and said germ or utilizing enzyme hydrolysis to separate said germ from the endosperm; and

milling said corn kernel to remove said germ.

6. The method of claim 1 comprising the steps of:

processing said starch and protein to remove oils and sterols therefrom; and

milling said starch to granularize said starch.

7. The method of claim 1 including wherein said step of separating said starch and protein is accomplished utilizing a method selected from a group consisting of clam shell processing, centrifuge processing, solubilization of said starch portion by enzyme saccharification, jet cooking and membrane filtration.

8. The method of claim 1 wherein obtaining the treated fiber fraction comprises contacting the pericarp enriched fraction with the fiber hydrolyzing agent.

9. The method of claim 8 wherein obtaining the treated fiber containing fraction further comprises contacting the lignocellulosic by-product of agricultural processing with the fiber hydrolyzing agent.

10. The method of claim 8 comprising the step of processing said pericarp enriched fraction to obtain pericarp by-products prior to contacting the pericarp enriched fraction wit the hydrolyzing agent.

11. The method of claim 10 including wherein said by-products of said pericarp processing include phytosterols, hemicelluloses, ferulic acid, and coumaric acid.

12. The method of claim 1 wherein obtaining the treated fiber fraction comprises contacting the lignocellulosic by-product of agricultural processing with the fiber hydrolyzing agent.

13. The method of claim 1 wherein the fiber hydrolyzing agent comprises at least one composition selected from the group consisting of calcium hydoxide, calcium oxide, sodium hydroxide, hydrogen peroxide, ammonia and a hypochlorite salt.

14. The method of claim 1 wherein the lignocellulosic by-product of agricultural processing comprises at least one member selected from the group consisting of corn gluten fiber, corn stover, distillers dried grains, oat hulls, rice hulls, rice hulls, rice straw, soy hulls, and wheat straw.