Integrated electro-pressure membrane deionization system

• US 7,501,064 B2
• Filed: 01/06/2005
• Issued: 03/10/2009
• Est. Priority Date: 01/06/2005
• Status: Expired due to Fees

• Current Assignee: EET Corporation
• Original Assignee: EET Corporation
• Inventors: Williams, Michael E., Sferrazza, Alois F., Schmidt, Ernst
• Primary Examiner(s): Fortuna; Ana M
• Application Number:
  US11/030,542
• Publication Number:
  US 20060144787A1
• Time in Patent Office: 1,524 Days
• Field of Search: 210650-653, 210/195.2, 210/257.2, 210/641, 204/522, 204/523, 204/526, 204/524, 204/805, 204/525
• US Class Current: 210/652
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: B01D 61/027 Nanofiltration
• CPC Class Codes: B01D 61/423 comprising multiple electrodialysis steps
• CPC Class Codes: B01D 61/44 Ion-selective electrodialysis
• CPC Class Codes: B01D 61/58 Multistep processes
• CPC Class Codes: C02F 1/44 by dialysis, osmosis or reverse osmosis general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 1/469 by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
• CPC Class Codes: C02F 1/4693 electrodialysis
• CPC Class Codes: Y10S 204/905 Heavy metal agent

Abstract

An integrated treatment system using electrodialysis and pressure-driven membranes for deionizing and decontaminating liquids to a near-pure quality for use or reuse in industrial or municipal operations. The integrated system includes steps of pre-filtering contaminated feed liquids blending the filtered liquids in preparation for treating the mixed liquids in parallel or sequential treatment steps utilizing nanofiltration or reverse osmosis, proceeded by or followed by an integrated electrodialysis treatment. A control means selectively directs mixed liquids to each of the treatment units for treatment in parallel or in series depending on the conductivity and residual contaminants in the mixed liquids. In comparison with nanofiltration or reverse osmosis only systems, or electrodialysis only systems, the integrated system provides improved efficiencies for treatment, requires less energy to operate, and reduces maintenance and capital costs.

Claims

1. An apparatus for electrodialysis treatment of contaminated feed liquids, comprising:

a pretreatment filtration unit having at least one filtration membrane through which contaminated feed liquids are directed, said at least one filtration membrane having sufficient pore diameters to deny passage of insoluble particles and to allow passage of filtrate liquids, said pretreatment filtration unit having at least one effluent channel for passage of said filtrate liquids;

a mixing unit in hydraulic connection with said at least one effluent channel of said pretreatment filtration unit, said mixing unit including means for mixing fluids transferred to said mixing unit; and

an electrodialysis unit in hydraulic connection with said mixing unit, said electrodialysis unit including a stacked configuration of a plurality of interdisposed anion cell membranes and cation cell membranes interleaved with a plurality of spacers, said electrodialysis unit providing at least one fluid path therethrough for movement of said filtrate liquids whereby a partially deionized product diluate liquid and concentrated ion fluid are separated from said filtrate liquids by at least one fluid path through said stacked configuration of said electrodialysis unit with said concentrated ion fluid channeled for release from said electrodialysis unit;

a recycle conduit through which partially deionized fluids are transferred to said mixing unit for blending;

a pressure-driven filtration unit including at least one of a nanofiltration or reverse osmosis membrane through which said blended feed liquid is channeled for separation of ionic and nonionic contaminants from said blended feed liquid, at least one of said nanofiltration or reverse osmosis membrane having a plurality of fluid paths through which said blended feed liquid is pressure driven whereby said pressure-driven filtration unit separates said blended feed liquid into a decontaminated product liquid and a concentrated liquid;

an effluent channel for release of said decontaminated product liquid from said pressure-driven filtration unit; and

at least one recycle channel through which said concentrated liquid is transferred to said mixing unit for blending.

2. The apparatus of claim 1 further comprising:

a computer circuitry controlling flow of filtrate liquids transferred through said mixing tank and said electrodialysis unit, whereby said computer circuitry controls flow to said electrodialysis unit in parallel with movement of said filtrate liquid through at least one of said nanofiltration or reverse osmosis membrane thereby said decontaminated product liquid is separated from said concentrated liquid.

3. The apparatus of claim 1 further comprising:

a computer circuitry controlling flow of blended filtrate liquids transferred to said mixing tank and said electrodialysis unit, whereby said computer circuitry controls flow independently to said electrodialysis unit in parallel with said blended feed liquid channeled at an independent flow rate through at least one of said nanofiltration or reverse osmosis membrane thereby said decontaminated product liquid is separated from said concentrated liquid.

4. The apparatus of claim 1 wherein said electrodialysis unit further includes:

said stacked configuration having at least one each of anion and cation ion exchange membranes; and

said plurality of spacers interleaved with said anion and cation ion exchange membranes to define said stacked configuration through which said pretreated filtrate liquids are transferred by application of continuous liquid flow therethrough whereby said ionic constituents are diverted for removal from said stacked configuration and said ion concentrated liquid is separated for release from said electrodialysis unit.

5. A method of electrodialysis and pressure driven filtration treatment of contaminated feed liquids comprising the steps of:

pretreating by filtration of contaminated feed liquids having inorganic contaminants and organic contaminants mixed therein, wherein said pretreating step removes particulates and generates pretreated filtrate liquids;

channeling said pretreated filtrate liquids to a mixing unit for blending with additional liquids;

directing said mixed pretreated filtrate liquids through a nanofiltration or reverse osmosis membrane unit providing pressure induced liquid transfer across permeable membranes thereby generating a permeate liquid stream and a concentrated reject liquid;

deionizing said blended filtrate liquids by pumping through a multiple flow path electrodialysis unit, said step of electrically treating producing a partially deionized diluate liquid portion channeled to a storage unit, and further producing a concentrate liquid portion directed for exiting said electrodialysis unit;

channeling said partially deionized diluate liquid portion from the electrodialysis unit for mixing in said mixing unit with said pretreated filtrate liquids; and

redirecting said concentrated reject liquid from said nanofiltration or reverse osmosis membrane for mixing in said mixing unit with said partially deionized diluate liquid portion wherein said liquids blended in the mixing unit are the concentrate and deionized diluate.

6. The method of claim 5 wherein said step of deionizing includes:

providing said multiple flow path electrodialysis unit with a plurality of electrodialysis membranes in a stacked configuration including a cathode electrode plate and an anode electrode plate between which a plurality of spacers are interleaved with said plurality of electrodialysis ion exchange membranes whereby a plurality of fluid flow paths are maintained within said electrodialysis unit; and

supplying a voltage differential between said cathode electrode plate and said anode electrode plate, whereby said step of deionizing produces said partially deionized diluate liquid for recycled to the mix unit and said concentrated liquid directed for existing said electrodialysis unit.

7. The method of claim 6 wherein said contaminated feed liquids include glycol based thermal transfer liquids.

8. A membrane-based process for treating contaminated feed liquids, comprising the steps of:

providing contaminated feed liquids having a plurality of insoluble and soluble contaminants and ionic constituents therein;

removing insoluble insoluble contaminants from said contaminated feed liquids in a pretreatment filtration unit for generating a pretreated filtrate liquid;

channeling said pretreated filtrate liquid to a mixing unit for blending thereby forming a blended filtrate liquid;

substantially simultaneously transferring an independently controlled selected flow of said blended filtrate liquid to an electric-driven membranes unit and an independently controlled selected flow of said blended filtrate liquid to a nanofiltration or reverse osmosis unit, thereby substantially simultaneously separating ionic constituents and producing a diluate in said blended filtrate liquid during passage through said electric-driven membrane unit and forming a separated ionic concentrate during passage of said selected flow through said nanofiltration or reverse osmosis unit;

substantially simultaneously continuously redirecting flow of diluate from said electric-driven unit and a selected flow of said concentrate stream from said nanofiltration or reverse osmosis unit to said mixing unit for additionally blending and further treatment within said nanofiltration or reverse osmosis unit and within said electric-driven ionic separation unit;

and removing deionized product liquid from sand nanofiltration or reverse osmosis unit for reused.

9. The process of claim 8 wherein said pressure-driven membrane unit is pressurized to pressures between about 50 pounds per square inch to about 400 pounds per square inch.

10. The process of claim 8 wherein said pressure-driven membrane unit is pressurized to pressures between about 200 pounds per square inch to about 1,000 pounds per square inch.