Electrophoretic display and process for its manufacture

• US 7,522,332 B2
• Filed: 08/10/2005
• Issued: 04/21/2009
• Est. Priority Date: 03/03/2000
• Status: Expired due to Fees

• Current Assignee: E Ink California, LLC (E Ink Corporation)
• Original Assignee: SiPix Imaging, Inc. (E Ink Holdings Incorporated)
• Inventors: Wu, Zarng-Arh George, Chan-Park, Mary, Liang, Rong-Chang, Zang, HongMei, Tseng, Scott C-J
• Primary Examiner(s): Dang; Hung X
• Assistant Examiner(s): Tra; Tuyen Q
• Application Number:
  US11/202,437
• Publication Number:
  US 20060164715A1
• Time in Patent Office: 1,350 Days
• Field of Search: 359/296, 245/105, 245/107, 430/323, 430/438, 430/7, 430/32, 430/34, 430/38, 204/450, 204/600, 204/485, 204/478, 345/84, 345/105, 345/107
• US Class Current: 359/296
• CPC Class Codes: B01J 13/16 Interfacial polymerisation
• CPC Class Codes: C08G 18/0866 the dispersing or dispersed phase being an aqueous medium
• CPC Class Codes: C08G 18/5015 having fluorine atoms
• CPC Class Codes: C08G 18/5039 containing amide groups
• CPC Class Codes: C08G 18/5066 having halogens in addition to nitrogen
• CPC Class Codes: C08G 18/792 formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
• CPC Class Codes: C08G 18/8038 with compounds of C08G18/3225
• CPC Class Codes: C08G 18/8087 containing halogen atoms
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1679 Gaskets; Spacers; Sealing of cells; Filling or closing of cells

Abstract

This invention relates to an electrophoretic display comprising cells which are filled with charged particles dispersed in a solvent and are individually sealed with a polymeric sealing layer.

Claims

1. A process for forming an electrophoretic display, which process comprises the steps of:

a) filling microcups with a dispersion comprising a sealing composition and an electrophoretic fluid, wherein the electrophoretic fluid comprises charged pigment particles dispersed in a dielectric solvent,

b) floating the sealing composition on top of said electrophoretic fluid, and

c) hardening the sealing composition to form a sealing layer to enclose said electrophoretic fluid within each of said microcups.

2. The process of claim 1 wherein said cell is partially filled with said electrophoretic fluid.

3. The process of claim 1 wherein said sealing composition comprises a material selected from the group consisting of polyvalent acrylate or methacrylate, cyanoacrylates, polyvalent vinyl, polyvalent epoxide, polyvalent isocyanate, polyvalent allyl, and oligomers or polymers containing crosslinkable functional groups.

4. The process of claim 3 wherein said sealing composition further comprises an additive selected from the group consisting of surfactants, antioxidants, initiators, catalysts, crosslinkers, thickeners, polymer binders, pigments, dyes and fillers.

5. The process of claim 4 wherein said filler is selected from the group consisting of silica, CaCO₃, BaSO₄, TiO₂, metal particles, metal oxides and carbon black.

6. The process of claim 3 wherein said polyvalent vinyl is vinylbenzene, vinylsilane or vinylether.

7. The process of claim 1 wherein said sealing composition has a specific gravity lower than that of the electrophoretic fluid.

8. The process of claim 7 wherein said sealing composition comprises a thermoplastic, thermoset or a precursor thereof.

9. The process of claim 7 wherein said sealing composition comprises a thermoplastic or thermoset precursor.

10. The process of claim 1 wherein said hardening of said sealing composition is accomplished by solvent evaporation, interfacial reaction, moisture, heat or radiation.

11. The process of claim 1 wherein each of said microcups comprises partition walls.

12. A sealing process for the manufacture of an electrophoretic display, which process comprises hardening a sealing composition on top of an electrophoretic fluid wherein said sealing composition has a specific gravity lower than that of the electrophoretic fluid.

13. A sealing process for the manufacture of an electrophoretic display, which process comprises

a) dispersing a sealing composition in an electrophoretic fluid to form a dispersion, wherein said sealing composition has a specific gravity lower than that of the electrophoretic fluid;

b) filling the dispersion in microcups, and

c) hardening said sealing composition to form a sealing layer on top of, and in contact with, the electrophoretic fluid, to enclose said electrophoretic fluid within each of said microcups.

14. The process of claim 13 wherein each of said microcups comprises partition walls.

15. A sealing process for the manufacture of an electrophoretic display which process comprises the steps in the order of:

a) filling microcups with an electrophoretic fluid comprising charged pigment particles dispersed in a dielectric solvent;

b) said microcups overcoating a sealing composition comprising a solvent onto the electrophoretic fluid in each of said microcups; and

c) hardening said sealing composition to enclose said electronhoretic fluid within each of said microcups.

16. The sealing process of claim 15 wherein said sealing composition has a specific gravity lower than that of the electrophoretic fluid.

17. The process of claim 15 wherein each of said microcups comprises partition walls.

18. The process according to claim 15, wherein said solvent is an organic solvent.

19. The process according to claim 15, wherein said sealing composition is a solution comprising a thermoplastic or thermoset precursor.