Densified molybdenum metal powder and method for producing same

• US 7,524,353 B2
• Filed: 02/17/2006
• Issued: 04/28/2009
• Est. Priority Date: 10/21/2004
• Status: Expired due to Fees

• Current Assignee: Cyprus AMAX Minerals Company (Freeport-Mcmoran Copper & Gold Incorporated)
• Original Assignee: Climax Engineered Materials, LLC (Freeport-Mcmoran Copper & Gold Incorporated)
• Inventors: Thompson, Patrick Ansel, Johnson, Loyal M. Jr., Jha, Sunil Chandra
• Primary Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US11/356,938
• Publication Number:
  US 20060204395A1
• Time in Patent Office: 1,166 Days
• Field of Search: None
• US Class Current: 75/360
• CPC Class Codes: B22F 1/05 Metallic powder characterised by the size or surface area of the particles
• CPC Class Codes: B22F 1/052 characterised by a mixture of particles of different sizes or by the particle size distribution
• CPC Class Codes: B22F 1/142 Thermal or thermo-mechanical treatment
• CPC Class Codes: B22F 9/22 using gaseous reductors
• CPC Class Codes: C22C 27/04 Alloys based on tungsten or molybdenum

Abstract

Densified molybdenum metal powder and method for producing same. Densified molybdenum powder has substantially generally spherical particles, surface area to mass ratio of no more than about 0.5 m²/g as determined by BET analysis, and a flowability greater than about 32 s/50g as determined by a Hall Flowmeter. A method for producing densified molybdenum metal powder includes providing a supply of precursor material of molybdenum metal powder particles reduced from ammonium molybdate; providing a supply of reducing gas; densifying the precursor material in the presence of the reducing gas; and producing the densified molybdenum metal powder.

Claims

1. A method for producing densified molybdenum metal powder comprising:

providing a supply of a precursor material comprising molybdenum metal particles reduced from ammonium molybdate;

providing a supply of reducing gas;

densifying said precursor material in the presence of said reducing gas; and

producing said densified molybdenum metal powder comprising substantially generally spherical particles of molybdenum metal, having a surface-area-to-mass ratio of no more than about 0.5 m²/g as determined by BET analysis and a flowability greater than about 32 s/50 g as determined by a Hall Flowmeter.

2. The method of claim 1 wherein said reducing gas comprises hydrogen.

3. The method of claim 1 further comprising preheating said precursor material at at least one temperature of not more than about 900°

C.

4. The method of claim 1 wherein said densifying is performed by heating said precursor material at a substantially uniform temperature.

5. The method of claim 4 wherein said substantially uniform temperature is between about 1065°

C. and about 1500°

C.

6. The method of claim 4 wherein said heating occurs for at least about 45 minutes.

7. The method of claim 4 wherein said heating occurs for between about 45 minutes and about 320 minutes.

8. A method for producing a densified molybdenum metal powder comprising:

providing a supply of a precursor material comprising molybdenum metal particles having a surface-area-to-mass ratio of between about 1 m²/g and about 4 m²/g as determined by BET analysis, and a flowability of between about 29 s/50 g and about 86 s/50 g as determined by a Hall Flowmeter;

providing a supply of reducing gas;

densifying said precursor material in the presence of said reducing gas; and

creating said densified molybdenum metal powder.

9. The method of claim 8 wherein said reducing gas comprises hydrogen.

10. The method of claim 8 further comprising preheating said precursor material at at least one temperature of not more than about 900°

C.

11. The method of claim 10 further comprising cooling said densified molybdenum metal powder.

12. The method of claim 8 wherein said densifying is performed by heating said precursor material at a substantially uniform temperature.

13. The method of claim 12 wherein said substantially uniform temperature is between about 1065°

C. and about 1500°

C.

14. The method of claim 13 wherein said heating occurs for between about 45 minutes and about 320 minutes.

15. The method of claim 12 wherein said heating occurs for at least about 45 minutes.

16. The method of claim 8 wherein said densified molybdenum metal powder comprises substantially generally spherical particles.

17. The method of claim 8 wherein said densified molybdenum metal powder comprises particles having a surface-area-to-mass ratio of no more than about 0.5 m²/g as determined by BET analysis and a flowability faster than about 32 s/50 g as determined by a Hall Flow meter.

18. The method of claim 17 wherein said densified molybdenum metal powder further comprises a Scott density of greater than 2 g/cm³.

19. The method of claim 17 wherein said flowability greater than about 32 s/50 g further comprises flowability in a range of about 16 s/50 g to about 32 s/50 g.

20. A method for producing a densified molybdenum metal powder comprising:

introducing into a furnace a supply of precursor material comprising molybdenum metal particles reduced from ammonium molybdate and having a surface-area-to-mass ratio of between about 1 m²/g and about 4 m²/g as determined by BET analysis, and a flowability of between about 29 s/50 g and about 86 s/50 g as determined by a Hall Flowmeter;

introducing a reducing gas into said furnace;

densifying said precursor material in the presence of said reducing gas at a substantially uniform temperature; and

producing said densified molybdenum metal powder having a surface-area-to-mass ratio of no more than about 0.5 m²/g as determined by BET analysis and a flowability greater than about 32 s/50 g as determined by a Hall Flowmeter.

21. The method of claim 20 further comprising preheating said precursor material to at least one temperature of not more than about 900°

C.

22. The method of claim 21 further comprising cooling said densified molybdenum metal powder.

23. The method of claim 20 wherein said substantially uniform temperature is between about 1065°

C. and about 1500°

C.

24. The method of claim 20 wherein said furnace has an inlet end and an outlet end, and further comprising:

introducing through the inlet end of said furnace said precursor material;

causing said precursor material to move through said furnace from the inlet end to the outlet end of said furnace;

introducing said reducing gas into said furnace near the outlet end of said furnace; and

causing said reducing gas to travel through said furnace in a direction opposite to that of said precursor material.

25. The method of claim 20 wherein said flowability greater than about 32 s/50 g further comprises flowability in a range from about 16 s/50 g to about 32 s/50 g.

26. A method for producing densified molybdenum metal powder, comprising:

introducing into a plasma furnace a supply of precursor material comprising molybdenum metal particles reduced from ammonium molybdate and having a surface-area-to-mass ratio of between about 1 m²/g and about 4 m²/g, as determined by BET analysis, and a flowability of between about 29 s/50 g and 86 s/50 g as determined by a Hall Flowmeter;

creating a plasma;

densifying said precursor material in said plasma; and

producing said densified molybdenum metal powder comprising spherical particles of molybdenum metal.

27. The method of claim 26 wherein said densified molybdenum powder further comprises an oxygen content of no more than about 0.02 total weight percent.

28. The method of claim 26 wherein said densifying further comprises:

melting said precursor material in said plasma, forming droplets; and

cooling said droplets.

29. The method of claim 26 wherein said densified molybdenum metal powder further comprises a flowability of no more than about 13 s/50 g.

30. The method of claim 26 wherein said densified molybdenum metal powder further comprises a tap density no less than about 6 g/cm³.

31. The method of claim 26 further comprising driving off at least one impurity contained in said precursor material.

32. A method for producing densified molybdenum powder, comprising:

introducing a supply of ammonium molybdate precursor material into a first furnace;

introducing a first reducing gas into said first furnace;

heating said ammonium molybdate precursor material in the presence of said first reducing gas in said first furnace;

producing a molybdenum metal powder intermediate having a surface-area-to-mass ratio of between about 1 m²/g and about 4 m²/g, as determined by BET analysis, and a flowability of between about 29 s/50 g and about 86 s/50 g as determined by a Hall Flowmeter;

introducing said molybdenum metal powder intermediate into a second furnace;

introducing a second reducing gas into said second furnace;

densifying said intermediate molybdenum metal powder in the presence of said second reducing gas in said second furnace; and

producing said densified molybdenum metal powder having a surface-area-to-mass ratio of no more than about 0.5 m²/g as determined by BET analysis and a flowability greater than about 32 s/50 g as determined by a Hall Flow meter.

33. A method for producing densified molybdenum powder, comprising:

introducing a supply of ammonium molybdate precursor material into a first furnace;

introducing a reducing gas into said first furnace;

heating said ammonium molybdate precursor material in the presence of said first reducing gas in said first furnace;

producing a molybdenum metal powder intermediate having a surface-area-to-mass ratio of between about 1 m²/g and about 4 m²/g, as determined by BET analysis, and a flowability of between about 29 s/50 g and about 86 s/50 g as determined by a Hall Flowmeter;

introducing said intermediate molybdenum metal powder into a plasma induction furnace;

creating a plasma;

densifying said molybdenum metal powder intermediate in said plasma; and

producing said densified molybdenum metal powder comprising spherical particles of molybdenum metal.

34. The method of claim 33 wherein said densified molybdenum metal powder further comprises an oxygen content of no more than about 0.02 total weight percent.

35. The method of claim 33, absent any grinding of said ammonium molybdate precursor material and said molybdenum metal powder intermediate.