Ammonia SCR catalyst and method of using the catalyst
First Claim
1. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising:
- a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof;
a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof;
at least one zeolite andstrontium.
6 Assignments
0 Petitions
Accused Products
Abstract
A catalyst and a method for selectively reducing nitrogen oxides with ammonia are provided. The catalyst includes a first component of copper, chromium, cobalt, nickel, manganese, iron, niobium, or mixtures thereof, a second component of cerium, a lanthanide, a mixture of lanthanides, or mixtures thereof, and a zeolite. The catalyst may also include strontium as an additional second component. The catalyst and the method may have special application to selective reduction of nitrogen oxides in exhaust gas from diesel vehicles, although the catalyst and the method have broad application to a wide range of gas streams that contain nitrogen oxides.
-
Citations
10 Claims
-
1. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising:
-
a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; at least one zeolite and strontium.
-
-
2. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising:
-
a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; at least one zeolite and an oxygen storage material. - View Dependent Claims (3)
-
-
4. A catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising:
-
approximately 1 to approximately 20 weight percent of a first component, said first component comprising at least one selected from the group consisting of copper, chromium, cobalt nickel, manganese, iron, niobium, and mixtures thereof; approximately 2 to approximately 35 weight percent of a second component, said second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; approximately 10 to approximately 90 weight % of at least one zeolite, and approximately 2 to approximately 35 weight percent of strontium, wherein the weight percent of the strontium is on the basis of strontium metal, and wherein the weight percentages of the first component and the second component are on the basis of the metals.
-
-
5. A catalyst composition comprising:
-
a substrate; and a catalyst for selective catalytic reduction of nitrogen oxides with ammonia, the catalyst comprising; a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; at least one zeolite, and an oxygen storage material, wherein the catalyst is placed on the substrate. - View Dependent Claims (6)
-
-
7. A method for selective reduction of nitrogen oxides in a gas stream with ammonia, wherein the gas stream comprises nitrogen oxides, the method comprising:
-
contacting the gas stream with ammonia in the presence of a catalyst, the catalyst comprising; a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; at least one zeolite and strontium.
-
-
8. A method for selective reduction of nitrogen oxides in a gas stream with ammonia, wherein the gas stream comprises nitrogen oxides, the method comprising:
-
contacting the gas stream with ammonia in the presence of a catalyst, the catalyst comprising; a first component comprising at least one selected from the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof; a second component comprising at least one selected from the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof; at least one zeolite and an oxygen storage material. - View Dependent Claims (9)
-
-
10. A method for selective reduction of nitrogen oxides in a gas stream with ammonia, wherein the gas stream comprises nitrogen oxides, the method comprising:
- contacting the gas stream with ammonia in the presence of a catalyst, the catalyst comprising;
a first component comprising at least one of the group consisting of copper, chromium, cobalt, nickel, manganese, iron, niobium, and mixtures thereof, a second component comprising at least one of the group consisting of cerium, a lanthanide, a mixture of lanthanides, and mixtures thereof, and at least one zeolite, wherein the catalyst comprises approximately 1 to approximately 20 weight percent of the first component, approximately 2 to approximately 35 weight percent of the second component, and approximately 10 to approximately 90 weight % of the at least one zeolite, wherein the weight percentages of the first component and the second component are on the basis of the metals, and approximately 2 to approximately 35 weight percent of strontium, wherein the weight percent of the strontium is on the basis of strontium metal.
- contacting the gas stream with ammonia in the presence of a catalyst, the catalyst comprising;
Specification