Treated aluminum article and method for making same

• US 7,527,872 B2
• Filed: 10/25/2005
• Issued: 05/05/2009
• Est. Priority Date: 10/25/2005
• Status: Active Grant

• Current Assignee: Goodrich Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: Goodrich Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Steele, Leslie Scotte, Brandewie, Brian
• Primary Examiner(s): Zimmer; Marc S
• Application Number:
  US11/258,395
• Publication Number:
  US 20070092739A1
• Time in Patent Office: 1,288 Days
• Field of Search: None
• US Class Current: 428/447
• CPC Class Codes: C25D 11/24 Chemical after-treatment
• CPC Class Codes: C25D 7/00 Electroplating characterised by the article coated
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249956 Void-containing component is inorganic
• CPC Class Codes: Y10T 428/249957 Inorganic impregnant
• CPC Class Codes: Y10T 428/249967 Inorganic matrix in void-containing component
• CPC Class Codes: Y10T 428/24997 Of metal-containing material
• CPC Class Codes: Y10T 428/249976 Voids specified as closed
• CPC Class Codes: Y10T 428/249987 With nonvoid component of specified composition
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

The disclosed invention relates to an article, comprising: a substrate having a surface comprising aluminum or an aluminum alloy; a sealed anodic coating layer overlying at least part of the surface of the substrate; and a layer of a silicon-containing polymer overlying the sealed anodic coating layer. The article may be useful as a brake or wheel component.

Claims

1. An article, comprising:

a substrate having a surface comprising aluminum or an aluminum alloy;

a sealed anodic coating layer overlying at least part of the surface of the substrate, wherein the sealed anodic coating layer has a surface and comprises (a) a porous anodic coating coating an outside surface and a plurality of pores on the outside surface of the anodic coating layer, and (b) a sorbed compound completely sealing the plurality of pores; and

a layer of a silicon-containing polymer overlying the surface of the sealed anodic coating layer, the silicon-containing polymer derived from at least one silane, at least one siloxane, or a mixture thereof.

2. The article of claim 1, wherein the aluminum alloy comprises aluminum and at least one alloying constituent, the alloying constituent comprising copper, manganese, silicon, magnesium, zinc, zirconium, silver, or a mixture of two or more thereof.

3. The article of claim 1 wherein the aluminum alloy comprises aluminum and at least one alloying constituent, the alloying constituent comprising copper.

4. The article of claim 1 wherein the aluminum alloy comprises aluminum and at least one alloying consitutent, the alloying constituent comprising zinc.

5. The article of claim 1 wherein the aluminum alloy comprises from about 90.4 to about 95% by weight aluminum, from about 3.9 to about 5% by weight copper, from about 0.2 to about 0.8% by weight magnesium, from about 0.4 to about 1.2% by weight manganese, from about 0.5 to about 1.2% by weight silicon, up to about 0.1% by weight chromium, up to about 0.7% by weight iron, up to about 0.15% by weight titanium, and up to about 0.25% by weight zinc.

6. The article of claim 1 wherein the aluminum alloy comprises from about 87.3 to about 90.3% by weight aluminum, from about 5.7 to about 6.7% by weight zinc, from about 2 to about 2.6% by weight copper, from about 1 .9 to about 2.6% by weight magnesium, from about 0.08 to about 0.15% by weight zirconium, up to about 0.04% by weight chromium, up to about 0.15% by weight iron, up to about 0.06% by weight titanium, up to about 0.1% by weight manganese, and up to about 0.12% by weight silicon.

7. The article of claim 1 wherein the aluminum alloy comprises from about 91.2 to 93.6% by weight aluminum, from about 4.8 to about 5.4% by weight of copper, from about 0.7 to about 1.1% by weight magnesium, from about 0.45 to about 1.0% by weight manganese, from about 0.40 to about 0.70% by weight silver, from about 0.08 to about 0.15% by weight of zirconium, up to about 0.25% by weight zinc, up to about 0.10% by weight iron, up to about 0.08% by weight silicon, up to about 0.06% by weight titanium, and up to about 0.05% by weight chromium.

8. The article of claim 1 wherein the aluminum alloy meets the standards set by the Aluminum Association for a Series 2009, 2014, 2016, 2017, 2024, 2040, 2080, 2117, 2214, 2618, 6013, 6061, 6091, 6092, 6113, 7005, 7009, 7010, 7033, 7049, 7050, 7075, 7085, 7093, 7175 or 7250 alloy.

9. The article of claim 1 wherein the alloy meets the standards set by the Aluminum Association for a Series 355.0, C355.0, 356.0, A356.0 or A357.0 alloy.

10. The article of claim 1, wherein the anodic coating layer is formed using a sulfuric acid bath, a chromic acid bath or a phosphoric acid bath.

11. The article of claim 1 wherein the anodic coating layer is formed using a sulfuric acid bath.

12. The article of claim 1 wherein the anodic coating layer comprises a barrier region overlying the aluminum substrate and a porous region overlying the barrier region.

13. The article of claim 1 wherein oxydichromate, oxychromate, hydroxyl, nickel hydroxide, cobalt hydroxide, or a mixture of two or more thereof, is sorbed by the anodic coating layer.

14. The article of claim 1, wherein the silicon-containing polymer is derived from methyl trimethoxysilane, phenyltrimethoxysilane, propyltrimethoxysilane, diethoxysiloxane, ethylenediaminopropylytrimethoxysilane, glycidoxymethoxysilane, glycidoxypropyl trimethoxy silane, 1,2 bis (triethoxysilyl) ethane, gamma-aminopropyl triethoxy silane, mercaptopropyl trimethoxy silane, dimethylsilane, aminopropyl silane, vinyltrimethoxysilane, bis-triethoxysilylpropyl tetrasulfone, amino trimethoxysilane, ureidopropyl trimethoxysilane, 1,2-bis-(trimethoxysilyl) ethane, 1,6-bis-(trialkoxysilyl) hexane, 1,2-bis-(triethoxysilyl) ethylene, bis-triethoxysilylpropyl tetrasulfone, or a mixture of two or more thereof.

15. The article of claim 1 wherein the thickness of the sealed anodic coating layer is in the range from about 0.5 to about 115 microns.

16. The article of claim 1 wherein the thickness of the sealed anodic coating layer is in the range from about 0.5 to about 25 microns.

17. The article of claim 1 wherein the thickness of the sealed anodic coating layer is in the range from about 12 to about 115 microns.

18. The article of claim 1 wherein the silicon-containing polymer layer has a thickness in the range from about 0.5 to about 100 microns.

19. The article of claim 1 wherein the silicon-containing polymer layer has a thickness in the range from about 25 to about 100 microns.

20. The article of claim 1 wherein the silicon-containing polymer layer has a thickness in the range from about 0.5 to about 25 microns.

21. The article of claim 1 wherein the article is a wheel or brake component.

22. The article of claim 1 wherein the article is an aircraft wheel or brake component.

23. The article of claim 1, wherein the silicon-containing compound is derived from at least one siloxane.

24. The article of claim 1 comprising an aluminum alloy, wherein the aluminum alloy meets the standards set by the Aluminum Association for a Series 2XXX alloy, 6XXX alloy, 7XXX alloy, or 3XX.X alloy.

25. A method of treating a substrate having a surface comprising an aluminum alloy, the method comprising:

forming an anodic coating layer overlying at least part of the surface of the substrate, the anodic coating layer comprising an outside surface and a plurality of pores on the outside surface;

completely sealing the plurality of pores of the anodic coating layer to form a sealed anodic coating layer having an outside surface; and

forming a silicon-containing polymer layer overlying the outside surface of the sealed anodic coating layer, the silicon-containing polymer derived from at least one alkoxysilane.

26. A method of treating a substrate, the substrate having a surface comprising an aluminum alloy, the process comprising:

forming an anodic coating layer overlying at least part of the surface of the substrate, the anodic coating layer being formed using a sulfuric acid bath, wherein the anodic coating layer comprises an outside surface and a plurality of pores on the outside surface;

completely sealing the plurality of pores of the anodic coating layer using water and/or a sealing solution to form a sealed anodic coating layer having an outside surface, the sealing solution comprising water and one or more of sodium dichromate, potassium dichromate, nickel acetate or cobalt acetate; and

forming a silicon-containing polymer layer over the outside surface of the sealed anodic coating layer, the silicon containing polymer derived from at least one alkoxysilane.