Flame retardant multicomponent articles

• US 7,547,650 B2
• Filed: 03/07/2006
• Issued: 06/16/2009
• Est. Priority Date: 03/07/2006
• Status: Expired due to Fees

• Current Assignee: Missing Octave Insights, Inc.
• Original Assignee: Missing Octave Insights, Inc.
• Inventors: Keep, Gerald Timothy
• Primary Examiner(s): TORRES VELAZQUEZ, NORCA LIZ
• Application Number:
  US11/369,252
• Publication Number:
  US 20070212963A1
• Time in Patent Office: 1,197 Days
• Field of Search: 442/136, 442/414, 428/920, 428/921
• US Class Current: 442/414
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2262/0284 Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
• CPC Class Codes: B32B 2262/12 Conjugate fibres, e.g. core/sheath or side-by-side
• CPC Class Codes: B32B 2307/3065 Flame resistant or retardant, fire resistant or retardant
• CPC Class Codes: B32B 2471/02 Carpets
• CPC Class Codes: B32B 2605/003 Interior finishings
• CPC Class Codes: B32B 2607/00 Walls, panels
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 5/06 characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
• CPC Class Codes: B32B 5/08 the fibres or filaments of a layer being of different substances , e.g. conjugate fibres, mixture of different fibres
• CPC Class Codes: B32B 5/26 another layer next to it also being fibrous or filamentary relative arrangement of fibres or filaments of different layers B32B5/12
• CPC Class Codes: C09K 21/06 Organic materials
• CPC Class Codes: D04H 1/4374 using different kinds of webs, e.g. by layering webs
• CPC Class Codes: D04H 1/43828 sheath-core
• CPC Class Codes: D04H 1/4383 sea-island
• CPC Class Codes: D04H 1/43832 side-by-side
• CPC Class Codes: D04H 1/43835 : Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• CPC Class Codes: D04H 1/43918 : nonlinear fibres, e.g. crimped or coiled fibres
• CPC Class Codes: Y10S 428/92 : Fire or heat protection feature
• CPC Class Codes: Y10S 428/921 : Fire or flameproofing
• CPC Class Codes: Y10T 442/2631 : Coating or impregnation provides heat or fire protection
• CPC Class Codes: Y10T 442/696 : Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]

Abstract

The present invention is directed to flame retardant multicomponent articles. The multicomponent articles include a reactive, migratory agent which is present in at least a first component of the article. The reactive migratory agent is capable of migrating from the first component of the article into a different component of the article under flame conditions to react with an element of that second component to produce a flame retardant effect. Applications include fibers, yarns, nonwovens, carpets, other fibrous materials, films, coating and composites.

Claims

1. A multicomponent article having fire retardant properties, comprising:

at least a first article component and at least a second article component; and

a flame retardant system comprising at least a first reactive agent and a second reactive agent that react with one another to provide a flame retardant effect, wherein said first reactive agent is present in at least one of said first and second article components and said second reactive agent is present in the other of said first and second article components which is different from the article component in which the first reactive agent is present, and wherein said first reactive agent migrates under flame conditions to the other of said first and second article components and reacts with said second reactive agent present therein to provide a flame retardant effect.

2. The article of claim 1, wherein the flame retardant system generates a gas.

3. The article of claim 2, wherein at least one of the reactive agents comprises at least one triggering agent capable of initiating a flame retarding effect upon reaction with the other of the reactive agents.

4. The article of claim 3, wherein at least another of the reactive agents comprises at least one blowing agent capable of creating a flame retardant effect upon reaction with the triggering agent.

5. The article of claim 3, wherein said at least one triggering agent comprises at least one compound selected from the group consisting of organic acids, organic alcohols, epoxides, amines, amides, and mixtures thereof.

6. The article of claim 5, wherein said organic acids comprise at least one compound selected from the group consisting of citric acid, stearic acid, and mixtures thereof.

7. The article of claim 4, wherein said at least one blowing agent comprises at least one compound selected from the group consisting of compounds capable of releasing carbon dioxide, compounds capable of releasing water, and mixtures thereof.

8. The article of claim 7, wherein the compounds capable of releasing carbon dioxide comprise at least one carbonate compound.

9. The article of claim 8, wherein said at least one carbonate compound is selected from the group consisting of sodium bicarbonate, sodium carbonate, calcium carbonate, and mixtures thereof.

10. The article of claim 7, wherein the compounds capable of releasing water comprise at least one compound having hydroxyl functionality.

11. The article of claim 10, wherein said at least one compound having hydroxyl functionality comprises at least one polymer having hydroxyl functionality.

12. The article of claim 11, wherein said at least one polymer having hydroxyl functionality is selected from the group consisting of phenoxy resins, polyvinyl alcohol resins, and mixtures thereof.

13. The article of claim 10, wherein said at least one compound having hydroxyl functionality comprises at least one organic alcohol.

14. The article of claim 7, wherein the compounds capable of releasing water comprise at least one hydrate.

15. The article of claim 1, wherein said reactive agents of the flame retardant system comprise at least one Generally Recognized As Safe (GRAS) agent.

16. The article of claim 2, wherein the gas generating flame retardant system comprises citric acid and sodium bicarbonate.

17. The article of claim 3, wherein said activation conditions comprise a temperature sufficient to activate the triggering agent.

18. The article of claim 17, wherein said activation temperature comprises a temperature of at least about 230°

C.

19. The article of claim 1, wherein the flame retardant system comprises a char forming flame retardant system.

20. The article of claim 19, wherein at least one reactive agent of the char forming flame retardant system comprises at least one char initiation agent or at least one compound capable of generating a char initiation agent.

21. The article of claim 20, wherein the char initiation agent comprises at least one compound selected from the group consisting of phosphorous compounds, borates, titanates, and mixtures thereof.

22. The article of claim 20, wherein said at least one compound capable of generating a char initiation agent comprises at least one phosphate that releases a mobile form of phosphorous upon reaction with an acid.

23. The article of claim 22, wherein said at least one phosphate that releases a mobile form of phosphorous comprises sodium phosphate and wherein said acid comprises citric acid.

24. The article of claim 20, wherein said char forming flame retardant system further comprises a char forming polymer.

25. The article of claim 24, wherein the char forming polymer comprises a polyester polymer.

26. The article of claim 25, wherein at least one component thereof comprises a char initiation agent and wherein at least one other component thereof comprises a polyester resin and optionally an olefin resin.

27. The article of claim 1, wherein the flame retardant system comprises a cross linking flame retardant system.

28. The article of claim 27, wherein at least one reactive agent of the cross linking flame retardant system comprises at least one cross linking agent and wherein at least one other reactive agent of the cross linking flame retardant system comprises at least one crosslinkable polymer.

29. The article of claim 28, wherein at least one component thereof comprises a cross linking agent and wherein at least one other component thereof comprises a crosslinkable polyamide resin and optionally a polyester resin.

30. The article of claim 1, wherein at least one of the reactive agents comprises a halogenated compound and wherein at least one other of the reactive agents comprises an antimony synergist.

31. The article of claim 1, wherein said reactive agents are present in said article in an amount sufficient to provide a flame retardant effect under activation conditions.

32. The article of claim 31, wherein said reactive agents are present in said article in an amount from about 0.1 to about 20 weight percent, based on the total weight of the article.

33. The article of claim 1, wherein said article further comprises a char initiation agent.

34. The article of claim 33, wherein at least one of said reactive agents comprises said char initiation agent.

35. The article of claim 33, wherein said reactive agents together comprise said char initiation agent.

36. The article of claim 33, wherein said char initiation agent is a different compound than either of said reactive agents.

37. The article of claim 1, wherein said first and second article components comprising said reactive agents are adjacent one another.

38. The article of claim 1, wherein said article further comprises at least a third article component.

39. The article of claim 38, wherein said first and second article components comprising said reactive agents are adjacent or in contact with one another.

40. The article of claim 38, wherein said at least a third article component is disposed between said first and second article components comprising said reactive agents.

41. The article of claim 1, wherein at least one of said first and second article components comprises a polymer.

42. The article of claim 41, wherein both of said first and second article components comprise a polymer.

43. The article of claim 41, wherein said polymer is a flame retardant polymer.

44. The article of claim 43, wherein said flame retardant polymer comprises a char forming polymer.

45. The article of claim 42, wherein both of said first and second article components comprise the same polymer.

46. The article of claim 42, wherein each of said first and second article components comprises different polymers.

47. The article of claim 41, wherein said polymer comprises at least one polymer selected from the group consisting of polyesters, polyolefins, polyacrylates, polyamides, elastomers, polyacrylonitrile, acetals, fluoropolymers, epoxies, phenoxies, vinyl alcohol polymers, polyesterimides, Hytrel, hot melt adhesives, co- and ter-polymers thereof, ionomers thereof, and mixtures thereof.

48. The article of claim 1, wherein said article is a fiber bundle.

49. The article of claim 48, wherein said fiber bundle comprises at least two fibers or filaments, wherein at least one of said reactive agents is present in at least one of said fibers or filaments and the other of said reactive agents is present in the other of said fibers or filaments.

50. The article of claim 48, wherein said fiber bundle comprises at least one or more multicomponent fibers comprising at least two or more distinct polymeric segments, wherein at least one of said reactive agents is present in at least one of said components and the other of said reactive is present in another of said components.

51. The article of claim 1, wherein said article is a yarn.

52. The article of claim 51, wherein said yarn comprises at least two fibers or filaments, wherein at least one of said reactive agents is present in at least one of said fibers or filaments and the other of said reactive agents is present in the other of said fibers or filaments.

53. The article of claim 51, wherein said yarn comprises at least one or more multicomponent fibers comprising at least two or more distinct polymeric segments, wherein at least one of said reactive agents is present in at least one of said components and the other of said reactive is present in another of said components.

54. The article of claim 51, wherein said yarn comprises a plurality of staple fibers spun into said yarn.

55. The article of claim 1, wherein said article comprises a twisted pair of yarns.

56. The article of claim 1, wherein said article is a fiber comprising at least two distinct segments, wherein at least one of said reactive agents is present in at least one of said fiber segments and the other of said reactive agents is present in a different one of said fiber segments.

57. The article of claim 56, wherein said fiber is a bicomponent fiber.

58. The article of claim 56, wherein said fiber is a multicomponent fiber comprises at least three or more distinct polymeric segments.

59. The article of claim 56, wherein said fiber comprises a fiber selected from the group consisting of sheath core fibers, pie wedge fibers, shaped fibers, islands in the sea fibers, and side-by-side fibers.

60. The article of claim 56, wherein said fiber comprises a fiber selected from the group consisting of continuous filaments, staple fibers, and meltblown fibers.

61. The article of claim 1, wherein said article is a laminate or composite comprising at least two layers, wherein at least one of said reactive agents is present in at least one of said laminate layers and the other of said reactive agents is present in the other of said laminate layers.

62. The article of claim 61, wherein said laminate comprises at least one film layer.

63. The article of claim 62, wherein said laminate comprises at least two film layers.

64. The article of claim 63, wherein said at least two film layers comprise coextruded film layers.

65. The article of claim 61, wherein at least one of said laminate layers comprises a coating.

66. The article of claim 1, wherein at least one of said article components comprises a coating.

67. The article of claim 66, wherein said article comprises a coated yam.

68. The article of claim 66, wherein said coating optionally includes at least one reactive agent incorporated therein.

69. The article of claim 1, wherein at least one of said article components comprises a hot melt adhesive.

70. The article of claim 69, wherein said hot melt adhesive optionally includes at least one reactive agent incorporated therein.