Switchable window based on electrochromic polymers

• US 7,547,658 B2
• Filed: 10/31/2007
• Issued: 06/16/2009
• Est. Priority Date: 06/25/2001
• Status: Expired due to Term

• Current Assignee: University of Washington
• Original Assignee: University of Washington
• Inventors: Taya, Minoru, Xu, Chunye, Liu, Lu, Legenski, Susan E.
• Primary Examiner(s): Stultz; Jessica T
• Application Number:
  US11/932,834
• Publication Number:
  US 20080055701A1
• Time in Patent Office: 594 Days
• Field of Search: 502/353
• US Class Current: 502/353
• CPC Class Codes: C07D 493/04 Ortho-condensed systems
• CPC Class Codes: C08G 2261/1424 containing ether groups, including alkoxy
• CPC Class Codes: C08G 2261/3221 containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
• CPC Class Codes: C08G 2261/3223 containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
• CPC Class Codes: C08G 2261/44 Electrochemical polymerisation, i.e. oxidative or reductive coupling
• CPC Class Codes: C08G 2261/54 electrochromatic
• CPC Class Codes: C08G 61/124 with a five-membered ring containing one nitrogen atom in the ring
• CPC Class Codes: C08G 61/126 with a five-membered ring containing one sulfur atom in the ring
• CPC Class Codes: C09K 2211/1408 Carbocyclic compounds
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds

Abstract

Syntheses of a new blue EC monomer (ProDOT-MePro), and a new red EC monomer (ProDOP-Et2) are described. Two additional new types of EC monomers based on 3,4-alkylenedioxythiophene include fluorinated EC monomers and an EC monomer including silicon. EC polymer devices having more than one different color EC polymer to enable additional colors to be provided using subtractive color mixing are also described, as well as EC polymer devices incorporating a logo, image, or text, are generally obscured when the device is colored, but become visible when the device is not colored. Also described are EC polymer devices that include a cathodic EC polymer layer, a gel electrolyte, a counter electrode, and a reference electrode. Working prototypes of such devices exhibit significant increases in the speed of transition of the EC device from a colored state to a transparent state.

Claims

1. A method for making a high quality vanadium oxide film suitable for use as a counter electrode in an electrochromic device, comprising the steps of:

(a) providing a substantially transparent and conductive substrate;

(b) attaching an additional conductive material to a portion of the substantially transparent and conductive substrate, such that the additional conductive material is electrically coupled to the substantially transparent and conductive substrate; and

(c) producing the counter electrode for use in the electrochromic device by depositing a thin film of vanadium oxide onto the substantially transparent and conductive substrate using cyclic voltammetry, wherein the step of using cyclic voltammetry comprises the step of applying the cyclic voltammetry potential to the additional conductive material to ensure a substantially uniform vanadium oxide film is deposited on the substantially transparent and conductive substrate.

2. The method of claim 1, wherein the step of attaching the additional conductive material comprises the step of attaching a strip of copper at a border of the substantially transparent and conductive substrate.

3. The method of claim 1, wherein the step of depositing the thin film of vanadium oxide onto the substantially transparent and conductive substrate using cyclic voltammetry comprises the steps of:

(a) introducing the substantially transparent and conductive substrate to which the additional conductive material is attached into a solution comprising hydrated vanadium oxide nano-particles; and

(b) depositing the vanadium oxide using a deposition speed ranging from about 5-150 mV/s, an applied voltage ranging from about 1-3 V, and a plurality of deposition cycles ranging from about 10-100.

4. The method of claim 1, wherein the step of depositing a thin film of vanadium oxide onto the substantially transparent and conductive substrate using cyclic voltammetry comprises the step of increasing the voltage and number of sweeps as the size of the substantially transparent and conductive substrate is increased.

5. The method claim 1, wherein the step of depositing a thin film of vanadium oxide onto the substantially transparent and conductive substrate using cyclic voltammetry further comprises the step of using a substrate angle ranging from about 60-90 degrees.

6. The method of claim 1, further comprising the step of heating the substantially transparent and conductive substrate after deposition of the vanadium oxide film to remove moisture.