Electrolytes for lithium sulfur cells

• US 7,553,590 B2
• Filed: 04/07/2008
• Issued: 06/30/2009
• Est. Priority Date: 01/06/2004
• Status: Expired due to Term

• Current Assignee: Sion Power Corporation
• Original Assignee: Sion Power Corporation
• Inventors: Mikhaylik, Yuriy V.
• Primary Examiner(s): Weiner; Laura S
• Application Number:
  US12/099,107
• Publication Number:
  US 20080187840A1
• Time in Patent Office: 449 Days
• Field of Search: 429/326, 429/339, 429/218.1, 429/231.95, 429/329, 429/340, 429/341, 429/337, 429/307
• US Class Current: 429/326
• CPC Class Codes: H01M 10/0567 characterised by the additives
• CPC Class Codes: H01M 10/0568 characterised by the solutes
• CPC Class Codes: H01M 10/0569 characterised by the solvents
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/136 Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/40 Alloys based on alkali metals
• CPC Class Codes: H01M 6/164 by the solvent
• CPC Class Codes: H01M 6/166 by the solute
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.

Claims

1. An electrochemical cell comprising:

(a) a cathode comprising an electroactive sulfur-containing material;

(b) an anode comprising lithium; and

(c) a nonaqueous electrolyte, wherein the electrolyte comprises;

(i) one or more nonaqueous solvents selected from the group consisting of acyclic ethers, cyclic ethers, polyethers, and sulfones;

(ii) one or more lithium salts; and

(iii) one or more N—

O additives comprising an organic nitrite compound and the organic nitrite compounds are selected from one or more of the group consisting of ethyl nitrite, propyl nitrite, butyl nitrite, pentyl nitrite and octyl nitrite.

2. The cell of claim 1 wherein the acyclic ether is selected from one or more of the group consisting of dimethoxymethane, trimethoxymethane, dimethoxyethane, diethoxyethane, 1,3-dimethoxypropane, 1,2-dimethoxypropane, diethyl ether, dipropyl ether, and dibutyl ether.

3. The cell of claim 1 wherein the polyether is selected from one or more of the group consisting of diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, dipropylene glycol dimethyl ether, ethylene glycol divinylether, diethylene glycol divinylether, triethylene glycol divinylether, and butylenes glycol ethers.

4. The cell of claim 1 wherein the sulfone is selected from one or more of the group consisting of sulfolane, 3-methyl sulfolane, and 3-sulfolene.

5. The cell of claim 1 wherein the concentration of the one or more N—

O additives in the electrolyte is from about 0.02 m to 2.0 m.

6. The cell of claim 1 wherein the concentration of the one or more N—

O additives in the electrolyte is from about 0.1 m to 1.5 m.

7. The cell of claim 1 wherein the concentration of the one or more N—

O additives in the electrolyte is from about 0.2 m to 1.0 m.

8. The cell of claim 1 wherein the concentration of the one or more lithium salts in the electrolyte is from about 0.2 m to about 2.0 m.

9. The cell of claim 1 that further includes a separator disposed between the anode and the cathode.

10. The cell of claim 9 wherein the one or more N—

O additives was included as part of the separator and was introduced into the electrolyte after the electrolyte came into contact with the separator.

11. A battery comprising a casing and one or more cells of claim 1.

12. The cell of claim 1 wherein the nonaqueous solvent comprises a cyclic ether including dioxolane.

13. The cell of claim 1 wherein the one or more solvents consists of dimethoxyethane and dioxolane.

14. An electrochemical cell comprising:

(a) a cathode comprising an electroactive sulfur-containing material;

(b) an anode comprising lithium; and

(c) a nonaqueous electrolyte, wherein the electrolyte comprises;

(i) one or more nonaqueous solvents selected from the group consisting of acyclic ethers, cyclic ethers, polyethers, and sulfones; and

(ii) one or more N—

O additives comprising an organic nitrite compound and the organic nitrite compounds are selected from one or more of the group consisting of ethyl nitrite, propyl nitrite, butyl nitrite, pentyl nitrite and octyl nitrite.

15. A battery comprising a casing and one or more cells of claim 14.