Stable liquid enzyme compositions with enhanced activity

• US 7,553,806 B2
• Filed: 07/29/2002
• Issued: 06/30/2009
• Est. Priority Date: 06/29/2000
• Status: Expired due to Fees

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Tilleskjor, Jaclyn, Man, Victor Fuk-Pong, Lentsch, Steven Eugene
• Primary Examiner(s): Lipman; Bernard
• Application Number:
  US10/208,404
• Publication Number:
  US 20030087787A1
• Time in Patent Office: 2,528 Days
• Field of Search: 510/393, 510/530, 510/535, 510/531, 510/337, 252/174.12, 252/135
• US Class Current: 510/393
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/38663 Stabilised liquid enzyme compositions

Abstract

The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and: at high concentration of boric acid salt; in the absence of sodium ion; and/or in the presence of water at concentrations of at least about 60 weight percent. The present enzyme cleaning composition typically yields superior soil (especially protein soil) removal properties. In an embodiment, the composition of the invention stabilizes the enzyme with potassium and/or alkanolamine borate.

Claims

1. A liquid enzyme cleaning composition comprising surfactant, detersive enzyme, about 15 to about 85 wt-% water, and about 10 to about 35 wt-% alkanol amine borate;

the alkanol amine borate remaining dissolved in the cleaning composition at room temperature;

wherein the liquid enzyme cleaning composition;

is formulated to provide detersive enzyme that retains about 80% of its initial activity at ambient temperature for about 11 months after forming the composition, comprises less than 1 wt-% of sodium ions, and has a pH in the range of about 9 to about 10.5.

2. The composition of claim 1, wherein the alkanol amine borate comprises monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate, or a combination thereof.

3. The composition of claim 1, wherein the composition is a solution.

4. The composition of claim 1, wherein the detersive enzyme comprises protease, amylase, lipase, cellulase, peroxidase, gluconase, or a combination thereof.

5. The composition of claim 4, wherein the detersive enzyme comprises alkaline protease, lipase, amylase, or a combination thereof.

6. The composition of claim 1, wherein the surfactant comprises amphoteric surfactant.

7. The composition of claim 1, further comprising source of calcium ions, polyol, builder, dye, or a combination thereof.

8. A liquid enzyme cleaning composition consisting of:

detersive enzyme, about 15 to about 85 wt-% water, about 10 to about 35 wt-% alkanol amine borate, ethoxylate (EO) nonionic surfactant, anionic surfactant, amphoteric surfactant and builder; and

optionally, additional surfactants, hydrotrope, fragrance, source of calcium ions, polyol, dye, or mixtures thereof;

wherein the alkanol amine borate remains dissolved in the cleaning composition at room temperature; and

wherein the liquid enzyme cleaning composition;

is formulated to provide detersive enzyme that retains about 80% of its initial activity at ambient temperature for about 11 months after forming the composition, and

comprises less than 1 wt-% of sodium ions, and

has a pH in the range of about 9 to about 10.5.

9. The composition of claim 8, wherein the alkanol amine borate comprises monoethanolammonium borate, diethanolammonium borate, triethanolammonium borate, or a combination thereof.

10. The composition of claim 8, wherein the composition is a solution.

11. The composition of claim 8, wherein the detersive enzyme comprises protease, amylase, lipase, cellulase, peroxidase, gluconase, or a combination thereof.

12. The composition of claim 11, wherein the detersive enzyme comprises lipase.

13. The composition of claim 8, wherein the amphoteric surfactant comprises dicarboxylic coconut derivative sodium salts.

14. A liquid enzyme cleaning composition comprising

detersive enzyme,

to 35 wt-% alkanol amine borate,

0.5 to 40 wt-% surfactant,

3 to 15 wt-% builder,

8-30 wt-% polyol, and

to 85 wt-% water;

and

wherein the liquid enzyme cleaning composition comprises less than 1 wt-% of sodium ions, and has a pH in the range of about 9 to about 10.5.

15. The liquid enzyme cleaning composition of claim 14, wherein the detersive enzyme is lipase.

16. The liquid enzyme cleaning composition of claim 14, wherein the alkanol amine borate is monoethanolammoniumborate.

17. The liquid enzyme cleaning composition of claim 14, wherein the 0.5 to 40 wt-% surfactant includes at least one anionic surfactant, at least one amphoteric surfactant, and at least one nonionic surfactant.

18. The liquid enzyme cleaning composition of claim 17, wherein at least one amphoteric surfactant is dicarboxylic coconut derivative sodium salts.

19. The liquid enzyme cleaning composition of claim 14, wherein the builder is ethylenediaminetetraacetic acid.

20. The liquid enzyme cleaning composition of claim 17, wherein at least one nonionic surfactant is an alcohol ethoxylate.

21. The liquid enzyme cleaning composition of claim 17, wherein at least one anionic surfactant is dodecylbenzenesulfonic acid.

22. The liquid enzyme cleaning composition of claim 14, wherein the liquid enzyme cleaning composition provides detersive enzyme that retains about 80% of its initial activity at ambient temperature for about 11 months after forming the composition.