High-throughput continuous-flow ultrasound reactor

• US 7,559,241 B2
• Filed: 05/27/2004
• Issued: 07/14/2009
• Est. Priority Date: 05/27/2004
• Status: Expired due to Fees

• Current Assignee: SulphCo, Inc.
• Original Assignee: SulphCo, Inc.
• Inventors: Gunnerman, Rudolf W.
• Primary Examiner(s): Mendez; Manuel A
• Application Number:
  US10/857,444
• Publication Number:
  US 20050274600A1
• Time in Patent Office: 1,874 Days
• Field of Search: 604 19- 22, 606/169, 736/43, 736/49, 156/580.1, 156/580.2, 318/118, 318/114, 318126-128, 310/26, 310/316
• US Class Current: 73/643
• CPC Class Codes: B01J 19/10 employing sonic or ultrasonic vibrations
• CPC Class Codes: B01J 2219/0869 Feeding or evacuating the reactor
• CPC Class Codes: B01J 2219/0871 Heating or cooling of the reactor
• CPC Class Codes: B01J 2219/0877 Liquid
• CPC Class Codes: B01J 2219/0888 Liquid-liquid
• CPC Class Codes: B01J 2219/0892 involving catalytically active material
• CPC Class Codes: B06B 3/00 Methods or apparatus specially adapted for transmitting mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
• CPC Class Codes: C10G 32/02 by electric or magnetic means

Abstract

Liquids are treated by ultrasound in a flow-through reaction vessel with an elongate ultrasonic horn mounted to the vessel with one end of the horn extending into the vessel interior. The liquid flow path inside the vessel is such that the entering liquid strikes the end of the horn at a direction normal to the end, then flows across the surface of the end before leaving the vessel. The end surface of the horn is positioned in close proximity to the entry port to provide a relatively high surface-to-volume ratio in the immediate vicinity of the horn end. In a further improvement, the horn is joined to an ultrasonic transducer through a booster block that provides an acoustic gain to the ultrasonic vibrations, and the booster block is plated with a reflective metal to lessen any loss of ultrasonic energy being transmitted to the horn.

Claims

1. A flow-through reactor for the continuous treatment of a liquid material with ultrasound, said flow-through reactor comprising:

a reaction vessel,

an elongate ultrasonic horn having first and second opposing end surfaces, said ultrasonic horn mounted to said reaction vessel with said first end surface extending into the interior of said reaction vessel,

an electrical power source,

an ultrasonic transducer operatively connecting said electrical power source to said second end surface of said ultrasonic horn to convert said electrical energy from said electrical power source to ultrasonic vibrations in said ultrasonic horn, and

entry and exit ports in said reaction vessel arranged to cause liquid material entering said reaction vessel to strike said first end surface and flow across said first end surface before leaving said vessel through said exit port.

2. The flow-through reactor of claim 1 wherein said elongate ultrasonic horn further comprises a side surface joining said first and second end surfaces, said ultrasonic horn is mounted to said reaction vessel with said first end surface and at least a portion of said side surface extending into the interior of said reaction vessel, and said exit port is arranged to cause said liquid material to flow along said portion of said side surface before leaving said vessel through said exit port.

3. The flow-through reactor of claim 1 wherein said entry port is positioned less than 3.0 cm from said first end surface of said ultrasonic horn.

4. The flow-through reactor of claim 1 wherein said entry port is positioned less than 2.0 cm from said first end surface of said ultrasonic horn.

5. The flow-through reactor of claim 1 wherein said reaction vessel has an internal wall surface that is complementary in contour to side surface of said ultrasonic horn with a clearance of less than 2.0 cm between said internal wall surface and said side surface.

6. The flow-through reactor of claim 5 wherein said clearance is less than 1.5 cm.

7. The flow-through reactor of claim 5 wherein said clearance is less than 1.0 cm.

8. Apparatus for generating ultrasonic vibration, said apparatus comprising:

an ultrasonic horn,

an ultrasonic transducer arranged to receive electrical energy and to convert said electrical energy to ultrasonic vibrations, and

a vibration transmitting block joining said ultrasonic transducer to said ultrasonic horn to transmit said ultrasonic vibrations from said ultrasonic transducer to said ultrasonic horn,

in which at least one of said ultrasonic horn and said vibration transmitting block is clad with an ultrasound reflecting cladding.

9. The apparatus of claim 8 wherein said vibration transmitting block is shaped to amplify said ultrasonic vibrations and is clad with an ultrasound reflecting cladding.

10. The apparatus of claim 8 wherein said vibration transmitting block is comprised of a first metal selected from the group consisting of steel, nickel, aluminum, titanium, copper, and alloys of nickel, aluminum, titanium and copper, and said cladding is comprised of a second metal different from said first metal and selected from the group consisting of silver, gold, copper and aluminum.

11. The apparatus of claim 8 wherein said cladding is on said vibration transmitting block and is silver.

12. The apparatus of claim 8 wherein said vibration transmitting block is comprised of steel and said cladding is a member selected from the group consisting of silver, gold, copper and aluminum.

13. The apparatus of claim 8 wherein said vibration transmitting block is comprised of steel and said cladding is a member selected from the group consisting of silver and gold.

14. The apparatus of claim 8 wherein said vibration transmitting block is comprised of steel and said cladding is silver.

15. A flow-through reactor for the continuous treatment of a liquid material with ultrasound, said flow-through reactor comprising:

a reaction vessel,

an elongate ultrasonic horn having first and second opposing end surfaces joined by a side surface, said ultrasonic horn mounted to said reaction vessel with said first end surface and at least a portion of said side surface extending into the interior of said reaction vessel,

an electrical power source,

an ultrasonic transducer operatively connecting said electrical power source to said second end surface of said ultrasonic horn to convert said electrical energy from said electrical power source to ultrasonic vibrations in said ultrasonic horn,

a vibration transmitting block joining said ultrasonic transducer to said ultrasonic horn to transmit said ultrasonic vibrations from said ultrasonic transducer to said ultrasonic horn, said vibration transmitting block clad with an ultrasound reflecting cladding, and

entry and exit ports in said reaction vessel arranged to cause liquid material entering said reaction vessel to strike said first end surface and flow across said first end surface before leaving said vessel through said exit port.

16. The flow-through reactor of claim 15 wherein said vibration transmitting block is comprised of steel and said cladding is a member selected from the group consisting of silver and gold.

17. The flow-through reactor of claim 15 wherein said cladding is on said vibration transmitting block and is silver.

18. The flow-through reactor of claim 15 wherein said vibration transmitting block is comprised of steel and said cladding is silver.

19. A process for treating a liquid fossil fuel by ultrasound, said process comprising continuously passing a fluid comprising said liquid fossil fuel and water through a reactor comprising:

a reaction vessel,

an elongate ultrasonic horn having first and second opposing end surfaces, said ultrasonic horn mounted to said reaction vessel with said first end surface extending into the interior of said reaction vessel, and

an ultrasonic transducer that converts electrical energy to ultrasonic vibrations, said ultrasonic transducer operatively connecting an electrical power source to said second end surface of said ultrasonic horn to transmit ultrasonic vibrations through said ultrasonic horn to said first end surface,

while supplying electrical energy to said ultrasonic transducer to produce said ultrasonic vibrations at said first end, and causing said fluid upon entering said reaction vessel to first strike said first end surface of said ultrasonic horn in a direction substantially normal to said first end surface and then to flow across said first end surface.

20. The process of claim 19 further comprising feeding said fluid to said reaction vessel through an entry port in said reaction vessel that is positioned less than 3.0 cm from said first end surface of said ultrasonic horn.

21. The process of claim 19 further comprising feeding said fluid to said reaction vessel through an entry port in said reaction vessel that is positioned less than 2.0 cm from said first end surface of said ultrasonic horn.

22. The process of claim 19 further comprising feeding said fluid to said reaction vessel through an entry port in said reaction vessel that is positioned less than 1.5 cm from said first end surface of said ultrasonic horn.

23. The process of claim 19 comprising continuously passing said fluid through said reactor at a rate that includes a fossil fuel flow rate of from about 0.3 to about 30 L/sec.

24. The process of claim 19 comprising continuously passing said fluid through said reactor at a rate that includes a fossil fuel flow rate of from about 0.5 to about 10 L/sec.

25. The process of claim 19 further comprising feeding said fluid to said reaction vessel through an entry port in said reaction vessel that is positioned less than 1.5 cm from said first end surface of said ultrasonic horn, at a rate that includes a fossil fuel flow rate of from about 0.5 to about 10 L/sec.

26. The process of claim 19 wherein said fluid is an emulsion consisting of an aqueous phase and an organic phase in which said aqueous phase constitutes from about 20% to about 75% by volume of said emulsion.

27. The process of claim 19 wherein said fluid is an emulsion consisting of an aqueous phase and an organic phase in which said aqueous phase constitutes from about 30% to about 50% by volume of said emulsion.

28. The process of claim 19 wherein said electrical energy is at a wattage of from about 1 to about 10 kilowatts.

29. The process of claim 19 wherein said electrical energy is in the form of a pulsewise voltage at a frequency of from about 10 to about 50 megahertz and a wattage of about 1 to about 10 kilowatts.

30. The process of claim 19 wherein said ultrasonic transducer is operatively connected to said ultrasonic horn through a vibration transmitting block that is clad with an ultrasound reflecting cladding.

31. The process of claim 30 wherein said vibration transmitting block is comprised of a first metal selected from the group consisting of steel, nickel, aluminum, titanium, copper, and alloys of nickel, aluminum, titanium, and copper, and said cladding is comprised of a second metal different from said first metal and selected from the group consisting of silver, gold, copper and aluminum.

32. The process of claim 30 wherein said vibration transmitting block is comprised of steel and said cladding is a member selected from the group consisting of solver, gold, copper and aluminum.

33. The process of claim 30 wherein said vibration transmitting block is comprised of steel and said cladding is silver.