Stable liquid enzyme compositions

• US 7,569,532 B2
• Filed: 04/08/2004
• Issued: 08/04/2009
• Est. Priority Date: 06/29/2000
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Man, Victor F., Ruhr, Rick O., McBroom, Amy B., Lentsch, Steven E., Peitersen, Nathan D., Schacht, Paul F., Tilleskjor, Jaclyn
• Primary Examiner(s): Lipman; Bernard
• Application Number:
  US10/820,891
• Publication Number:
  US 20050020466A1
• Time in Patent Office: 1,944 Days
• Field of Search: 510/392, 510/393, 510/321, 510/530, 510/535, 510/531, 510/532, 510/337
• US Class Current: 510/393
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/38663 Stabilised liquid enzyme compositions

Abstract

The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and: at high concentration of boric acid salt; in the absence of sodium ion; and/or in the presence of at least about 40 wt-% water. In an embodiment, water is present at concentrations of at least about 60 weight percent. The present enzyme cleaning composition typically yields superior soil (especially protein soil) removal properties. In an embodiment, the composition of the invention stabilizes the enzyme with potassium and/or alkanolamine borate.

Claims

1. A liquid enzyme cleaning composition comprising a surfactant, a detersive enzyme, about 10% to about 20% by weight of a boric acid salt, and 40% to about 85% by weight water;

wherein the liquid enzyme cleaning composition is formulated to provide detersive enzyme that retains 80% of its initial enzyme activity at ambient temperature for at least 30 days after forming the composition.

2. The composition of claim 1, wherein the boric acid salt comprises at least one of an alkali metal boric acid salt, an alkanolammonium boric acid salt, an alkanolamine boric acid salt, and a combination thereof.

3. The composition of claim 2, wherein the boric acid salt comprises at least one of monoethanolammonium borate, monoethanolamine borate, diethanolammonium borate, diethanolamine borate, triethanolammonium borate, triethanolamine borate, and a combination thereof.

4. The composition of claim 1, wherein the composition is a solution.

5. The composition of claim 1, wherein the detersive enzyme comprises at least one of protease, amylase, lipase, cellulase, peroxidase, gluconase, mannanase, and a combination thereof.

6. The composition of claim 1, wherein the surfactant comprises at least one of anionic surfactant, nonionic surfactant, and a combination thereof.

7. The composition of claim 6, wherein the surfactant comprises at least one of a C13-C15 alcohol alkoxylate, a polyoxyethylene alkyl phosphate ester acid, and a combination thereof.

8. The composition of claim 1, further comprising an ingredient comprising at least one of a source of calcium ions, an optical brightener, a hydrotrope, a polyol, a builder, a dye, and a combination thereof.

9. The composition of claim 1, further comprising a pH in the range of 9 to 11.

10. The composition of claim 1, wherein the composition is configured for use in a clean-in-place cleaning program.

11. The composition of claim 1, wherein the composition is a 1:

10 dilution with water and the dilution is physically stable for one week.