High infrared reflection coatings and associated technologies

• US 7,572,510 B2
• Filed: 10/10/2006
• Issued: 08/11/2009
• Est. Priority Date: 10/11/2005
• Status: Active Grant

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Hartig, Klaus
• Primary Examiner(s): Speer; Timothy M
• Assistant Examiner(s): ROBINSON, LAUREN E
• Application Number:
  US11/545,231
• Publication Number:
  US 20070082206A1
• Time in Patent Office: 1,036 Days
• Field of Search: 428/428, 428/432, 428/434
• US Class Current: 428/432
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: C23C 14/0036 Reactive sputtering
• CPC Class Codes: C23C 14/086 of zinc, germanium, cadmium, indium, tin, thallium or bismuth
• CPC Class Codes: C23C 14/185 by cathodic sputtering
• CPC Class Codes: C23C 14/568 Transferring the substrates through a series of coating stations C23C14/562 takes precedence
• CPC Class Codes: Y10T 428/231 Filled with gas other than air; or under vacuum

Abstract

The invention provides low-emissivity coatings that are highly reflective of infrared radiation. The coating includes three infrared-reflection film regions, which may each comprise silver.

Claims

1. A coated substrate having a major surface bearing a low-emissivity coating, the coating comprising, from said major surface outwardly:

a) a first transparent dielectric film region;

b) a first infrared-reflection film region comprising silver;

c) a second transparent dielectric film region;

d) a second infrared-reflection film region comprising silver;

e) a third transparent dielectric film region;

f) a third infrared-reflection film region comprising silver;

g) a fourth transparent dielectric film region;

wherein the coated substrate is part of a multiple-pane insulating glazing unit that includes another substrate, both substrates being clear glass, wherein the first, second, and third infrared-reflection film regions have a combined thickness of between 420 Å

-575 Å

, the coating has an emissivity of less than 0.025, and yet said glazing unit has a total visible transmission of greater than 60%, wherein the coated substrate has a spectral transmission curve with a transmission peak that is located within a visible wavelength range, and wherein said spectral transmission curve has a halfwidth of less than 290 nm, the coating having a first reflection-region ratio defined as the thickness of the first infrared-reflective film region divided by the thickness of the second infrared-reflective film region, the coating having a second reflection-region ratio defined as the thickness of the second infrared-reflective film region divided by the thickness of the third infrared-reflective film region, both the first and second reflection-region ratios being less than 0.83, and at least one of the first and second reflection-region ratios being less than 0.80.

2. The coated substrate of claim 1 wherein the halfwidth is less than 275 nm.

3. The coated substrate of claim 1 wherein the halfwidth is less than 250 nm.

4. The coated substrate of claim 1 wherein the halfwidth is greater than 100 nm.

5. The coated substrate of claim 1 wherein the halfwidth is greater than 150 nm.

6. The coated substrate of claim 1 wherein the combined thickness of the first, second, and third infrared-reflection film regions is greater than 425 angstroms.

7. The coated substrate of claim 1 wherein the total visible transmission is greater than 65%.

8. The coated substrate of claim 1 wherein the coating has an emissivity of less than 0.02.

9. The coated substrate of claim 8 wherein the emissivity is less than 0.015.

10. The coated substrate of claim 1 wherein the first transparent dielectric film region comprises film having a refractive index of 1.7 or greater, and wherein between the first infrared-reflection film region and said major surface of the substrate there is a desired total thickness of film that has a refractive index of 1.7 or greater, said desired total thickness being less than 190 angstroms.

11. The coated substrate of claim 10 wherein said desired total thickness is less than 175 angstroms.

12. The coated pane of claim 10 wherein the low-emissivity coating has a total thickness of greater than 1,800 angstroms.

13. The coated pane of claim 12 wherein the low-emissivity coating has a total thickness of greater than 1,900 angstroms.

14. The coated substrate of claim 1 wherein the first, second, and third infrared-reflection film regions are silver layers each consisting essentially of silver, and wherein these three silver layers are the only silver layers in the coating.

15. The coated substrate of claim 1 wherein said glazing unit has a visible-thermal efficiency ratio of greater than 2.3, the visible-thermal efficiency ratio being defined as the total visible transmittance of said glazing unit divided by a solar heat gain coefficient of said glazing unit.

16. The coated substrate of claim 1 wherein the emissivity is less than 0.023.

17. The coated substrate of claim 1 wherein said major surface bearing the low-emissivity coating is a #2 surface of said glazing unit.