Method and apparatus for producing methane from carbonaceous material

• US 7,575,613 B2
• Filed: 05/26/2005
• Issued: 08/18/2009
• Est. Priority Date: 05/26/2005
• Status: Expired due to Fees

• Current Assignee: Arizona Public Service Company (Pinnacle West Capital Corporation)
• Original Assignee: Arizona Public Service Company (Pinnacle West Capital Corporation)
• Inventors: Hobbs, Raymond S.
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US11/138,638
• Publication Number:
  US 20060265953A1
• Time in Patent Office: 1,545 Days
• Field of Search: 48/76, 48/63, 482/06, 481/97.R, 48/77, 482/10, 110/264, 110/261, 110/347, 423/648.1, 422/207, 422/232
• US Class Current: 48/197.00R
• CPC Class Codes: B01J 19/2405 provoking a turbulent flow of the reactants, such as in cyclones, or having a high Reynolds-number
• CPC Class Codes: B01J 19/26 Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
• CPC Class Codes: B01J 2219/00763 Baffles
• CPC Class Codes: C01B 2203/0445 Selective methanation
• CPC Class Codes: C01B 2203/047 the impurity being carbon monoxide
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/0485 the impurity being a sulfur compound
• CPC Class Codes: C01B 3/50 Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification C01B3/14 takes precedence
• CPC Class Codes: C01B 3/586 the reaction being a methanation reaction
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/0906 Physical processes, e.g. shredding, comminuting, chopping, sorting
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0966 Hydrogen
• CPC Class Codes: C10J 2300/0969 Carbon dioxide
• CPC Class Codes: C10J 2300/1662 to methane
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 3/487 Swirling or cyclonic gasifiers
• CPC Class Codes: C10J 3/506 for entrained flow gasifiers
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/005 Carbon dioxide
• CPC Class Codes: C10K 1/024 : by filtration
• CPC Class Codes: C10L 3/08 : Production of synthetic natural gas
• CPC Class Codes: Y02P 20/133 : Renewable energy sources, e.g. sunlight

Abstract

A method for producing methane (69) from a carbonaceous (22) material includes conveying pulverized carbonaceous material (28) entrained in an inert carrier fluid, such as carbon dioxide (36), into a reactor (34). The reactor (34) includes a vortex region (72) for receiving hydrogen gas (38) and imparting a swirling motion to the hydrogen gas (38). The pulverized carbonaceous material (28) is exposed to the swirling stream of hydrogen gas (38) in a first reaction zone (114) within the reactor (34) to form an exit gas (40) that includes methane (69). Remaining unreacted carbonaceous material (28) is further exposed to the hydrogen gas (38) in a second, low velocity, reaction zone (120). The methane rich exit gas (40) is subsequently extracted from the reactor (34) for further processing.

Claims

1. A method for producing methane from a carbonaceous material comprising:

conveying said carbonaceous material entrained in an inert carrier fluid into a reactor;

exposing said carbonaceous material in said reactor to a swirling stream of a hydrogen gas to react said carbonaceous material with said hydrogen gas in a first reaction zone and form an exit gas that includes said methane;

contacting said exit gas with hydrogen gas in a second reaction zone having a lower reaction rate than said first reaction zone to increase an amount of said methane in said exit gas; and

extracting said exit gas from said reactor.

2. A method as claimed in claim 1 further comprising pulverizing said carbonaceous material prior to said conveying operation.

3. A method as claimed in claim 2 wherein said pulverizing operation forms particulates of said carbonaceous material, with at least seventy percent of said particulates being sized to pass through a one hundred mesh screen.

4. A method as claimed in claim 1 wherein said inert carrier fluid is carbon dioxide gas.

5. A method as claimed in claim 1 further comprising pressurizing said reactor to a reaction pressure of approximately 1000 psi prior to said conveying operation.

6. A method as claimed in claim 5 wherein said pressurizing operation comprises utilizing said inert carrier fluid to pressurize said reactor.

7. A method as claimed in claim 1 further comprising preheating said reactor to approximately 1200°

F. prior to said conveying operation.

8. A method as claimed in claim 1 wherein said conveying operation conveys said carbonaceous material under pressure to an input of said first reaction zone of said reactor, said pressure being greater than a reactor pressure.

9. A method as claimed in claim 1 wherein said conveying operation comprises delivering a diffused spray of said carbonaceous material to an input of said first reaction zone of said reactor.

10. A method as claimed in claim 1 further comprising:

delivering said hydrogen gas to a vortex region of said reactor to impart a swirling motion to said hydrogen gas to form said swirling stream; and

passing said swirling stream of said hydrogen gas from said vortex region to said first reaction zone to react said carbonaceous material with said hydrogen gas.

11. A method as claimed in claim 10 wherein said hydrogen gas is produced in a gasification process, and said method further comprises injecting said hydrogen gas from said gasification process into said reactor.

12. A method as claimed in claim 1 further comprising:

capturing ash produced in response to said exposing operation; and

transporting said ash entrained in a second inert carrier fluid from said reactor.

13. A method as claimed in claim 12 wherein said second inert carrier fluid is carbon dioxide gas.

14. A method as claimed in claim 1 wherein said exposing operation generates heat in response to reaction of said carbonaceous material with said hydrogen gas, and said method further comprises:

transferring said heat from said exit gas to a fluid flowing in a heat exchanger in communication with said reactor; and

selectively releasing said heat from said fluid to maintain said exit gas at a predetermined temperature.

15. A method as claimed in claim 14 wherein said heat exchanger is a water wall lining said reactor, said fluid is water, and said selectively releasing operation releases said heat in the form of discharge steam.

16. A method as claimed in claim 15 further comprising utilizing said heat stored in said discharge steam for a secondary thermal process.

17. A method as claimed in claim 1, wherein said hydrogen gas is produced in a separate process.

18. A method as claimed in claim 17, wherein said hydrogen gas is produced using a renewable energy source.

20. A system as claimed in claim 18 wherein said fuel feed element comprises:

a tubular member having said first inlet and said first outlet on opposing ends of said tubular member; and

a diffuser coupled to said tubular member at said first outlet for delivering a diffused spray of said carbonaceous material to an inlet end of said reaction tube.

21. A system as claimed in claim 18 wherein said vortex region comprises vanes for imparting said swirling motion to said hydrogen gas.

22. A system as claimed in claim 18 wherein said vortex region comprises:

a generally cylindrical housing, said second inlet being formed on a circumferential surface of said housing;

a lid coupled to a first end of said cylindrical housing; and

a bottom coupled to a second end of said cylindrical housing, said second outlet being positioned in said bottom.

23. A system as claimed in claim 22 wherein said fuel feed element is a tubular member extending through said lid and passing through an interior of said cylindrical housing, said fuel feed element exiting from said bottom, said first inlet being located external to said vortex region proximate said top, and said first outlet being located external to said vortex region proximate said bottom.

24. A system as claimed in claim 22 wherein said reaction tube includes an inlet end coupled with said bottom of said vortex region.

25. A system as claimed in claim 18 wherein said reaction tube is formed from a ceramic material, having a heat resistance greater than fifteen hundred degrees Fahrenheit.

26. A system as claimed in claim 18 wherein:

a first interior of said reaction tube forms a first reaction zone; and

said apparatus further comprises a secondary reactor vessel in fluid communication with an outlet end of said reaction tube, a second interior of said secondary reactor vessel forming a second reaction zone, and said exit gas passes from said first reaction zone to said second reaction zone to react a remaining portion of said carbonaceous material in said exit gas with a portion of said hydrogen gas to increase an amount of said methane in said exit gas.

27. A system as claimed in claim 26 wherein hydrogen gas in said second reaction zone exhibits a lower velocity than hydrogen gas in said first reaction zone.

28. A system as claimed in claim 26 wherein said first reaction zone is positioned inside said secondary reactor vessel.

29. A system as claimed in claim 26 further comprising a water wall lining said secondary reactor vessel and having water flowing through said water wall, said water wall including a fluid inlet for receiving said water and a fluid outlet for releasing heat in the form of discharge steam, said heat being absorbed by said water in response to reaction of said carbonaceous material with said hydrogen gas.

19. A system for producing methane from a carbonaceous material comprising:

a pulverizer for forming particulates of said carbonaceous material;

a screw conveyor coupled to said pulverizer, wherein said screw conveyor is configured to convey said particulates; and

a reactor in communication with said screw conveyor, said reactor including;

a fuel feed element having a first inlet for receiving said particulates of said carbonaceous material entrained in an inert carrier fluid from said conveyor, and said fuel feed element having a first outlet;

a vortex region having a second inlet for receiving a hydrogen gas and having a second outlet, said vortex region imparting a swirling motion to said hydrogen gas to form a swirling stream of said hydrogen gas;

a reaction tube in fluid communication with each of said first and second outlets for exposing said carbonaceous material to said swirling stream of said hydrogen gas to react said carbonaceous material with said hydrogen gas and form an exit gas that includes said methane; and

a reactor outlet in fluid communication with said reaction tube for extracting said exit gas from said reactor.

30. A method for producing methane from a carbonaceous material comprising:

delivering a hydrogen gas to a vortex region of a reactor to impart a swirling motion to said hydrogen gas and form a swirling stream of said hydrogen gas;

passing said swirling stream of said hydrogen gas from said vortex region to a reaction zone of said reactor;

conveying said carbonaceous material entrained in an inert carrier fluid into said reaction zone;

in the absence of added water, exposing said carbonaceous material in said reaction zone to said swirling stream of a hydrogen gas to react said carbonaceous material with said hydrogen gas and form an exit gas that includes said methane;

and

contacting said exit gas with hydrogen gas to react a remaining portion of said carbonaceous material in said exit gas with hydrogen gas to increase an amount of said methane in said exit gas; and

extracting said exit gas from said reactor.

31. A method as claimed in claim 30 further comprising pulverizing said carbonaceous material prior to said conveying operation.

32. A method as claimed in claim 30 wherein said inert carrier fluid is carbon dioxide.

33. A method as claimed in claim 30 wherein said conveying operation comprises delivering a diffused spray of said carbonaceous material to an input of a reaction zone of said reactor.

34. A method as claimed in claim 30 wherein reaction of said carbonaceous material with said hydrogen gas generates heat, and said method further comprises:

transferring said heat from said exit gas to a fluid flowing in a heat exchanger lining said reactor; and

selectively releasing said heat from said fluid to maintain said exit gas at a predetermined temperature.

35. A method as claimed in claim 30, wherein said exposing step takes place in a first reaction zone and said contacting step takes place in a second reaction zone.

36. A method as claimed in claim 35, wherein hydrogen gas located in said second reaction zone has a lower velocity than hydrogen gas located in said first reaction zone.