Lithium-ion battery prognostic testing and process

• US 7,576,545 B2
• Filed: 10/18/2006
• Issued: 08/18/2009
• Est. Priority Date: 10/18/2006
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Johnson, James S., Singh, Harmohan N.
• Primary Examiner(s): Ullah; Akm E
• Assistant Examiner(s): RAMADAN, RAMY O
• Application Number:
  US11/550,566
• Publication Number:
  US 20080094031A1
• Time in Patent Office: 1,035 Days
• Field of Search: 320/132, 320/149, 324426-427, 324431-432
• US Class Current: 324/427
• CPC Class Codes: G01R 31/387 Determining ampere-hour charge capacity or SoC
• CPC Class Codes: G01R 31/392 Determining battery ageing or deterioration, e.g. state of health
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/42 Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells H01M10/60 takes precedence
• CPC Class Codes: H01M 10/4285 Testing apparatus
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

In accordance with various embodiments, there are systems and methods for predicting end of life of a Li-ion battery. The method can include at least one of partially charging and partially discharging a battery, measuring an open circuit voltage of the battery before and after at least one of partial charging and partial discharging, and determining a state of charge value of the battery corresponding to the open circuit voltage measured before and after at least one of partial charging and partial discharging. The method can also include correlating at least one of a charge energy and a discharge energy with a change in the state of charge value and extrapolating to get a full battery capacity, tracking the full battery capacity as a function of time, and performing trend analysis of the full battery capacity over time to predict the battery'"'"'s end of life.

Claims

1. A method for determining full capacity of a Li-ion battery comprising:

depolarizing the battery until the battery is in a quiescent state;

measuring a first open circuit voltage of the battery;

determining a first state of charge value of the battery corresponding to the first open circuit voltage;

partially charging the battery with a known state of charge by applying a constant current until the battery exhibits a measured second open circuit voltage of n*3.5 V, wherein n is equal to the number of cells of the battery;

determining a second state of charge value of the battery corresponding to the second open circuit voltage measured after the step of partial charging; and

correlating a charge energy with a change in the state of charge to determine a full capacity of the battery;

wherein the charge energy is the energy required for charging at a constant current until the voltage across the battery reaches a predetermined value; and

wherein the change in the state of the charge is the difference between the first state of charge value of the battery and the second state of charge value of the battery.

2. The method according to claim 1, wherein the step of partial charging further comprises selecting a partial charge region from at least one of a charge and a discharge curve.

3. The method according to claim 2, wherein the step of partial charging further comprises selecting the partial charge region from the steepest region of at least one of the charge and discharge curves.

4. The method according to claim 1, wherein the battery is charged at a charge rate of about 0.1C to about 1C.

5. The method according to claim 1, wherein the state of charge value of the battery is determined by at least one of looking at a graph and a look up table of a state of charge versus open circuit voltage of the battery.

6. The method according to claim 1 further comprising determining full capacity as a function of temperature.

7. A method for predicting end of life of a Li-ion battery comprising:

depolarizing the battery until the battery is in a quiescent state;

measuring a first open circuit voltage of the battery;

determining a first state of charge value of the battery corresponding to the first open circuit voltage;

partially charging a battery until the battery exhibits a measured second open circuit voltage value that is n*3.5 V, wherein n is equal to the number of cells of the battery;

determining a second state of charge value of the battery corresponding to the second open circuit voltage measured after the step of partial charging;

correlating a charge energy with a change in the state of charge value and extrapolating to get a full battery capacity, wherein the charge energy is the energy required for partial charging and the change in the state of the charge is the difference between the first state of charge value and the second state of charge value;

recording and tracking the battery'"'"'s full capacity as a function of time; and

performing trend analysis of the battery'"'"'s full capacity over time to predict the battery'"'"'s end of life.

8. The method of claim 7, wherein the step of partially charging a battery further comprises selecting a partial charge region from the steepest region of a charge curve.

9. The method of claim 7, wherein the step of performing trend analysis comprises determining whether the battery'"'"'s full capacity has declined by a certain amount, wherein the certain amount depends upon the application in which the battery is used.

11. A system of claim 7, further comprising a temperature sensor for measuring a temperature of the battery.

10. A system for predicting end of life of a Li-ion battery comprising:

an instrumentation and control module comprising an analog-to-digital converter, a digital-to-analog converter, and an electronics control signal generator;

a depolarizing device for depolarizing the battery to a quiescent state;

a power supply that supplies a current to partially charge the battery until the battery exhibits an open circuit voltage of n'"'"'3.5 V, where n is equal to the number of cells of the battery;

a current sensor disposed in series between the power supply and the battery to measure a current passing to the battery from the power supply;

a voltage sensor electrically connected to the battery to measure the open circuit voltage of the battery before and after the partial charge of the battery, wherein a first state of charge value of the battery and a second state of charge value of the battery correspond to a first open circuit voltage and a second open circuit voltage measured before and after the partial charge, respectively;

a computer with a processor that determines the full capacity of the battery by correlating a charge energy with a change in a state of charge value and extrapolating to get a full battery capacity, wherein the charge energy is the energy required for partial charging and the change in the state of the charge is the difference between the first state of charge value and the second state of charge value, prepares a trend analysis of the battery'"'"'s full capacity as a function of time, and predicts battery'"'"'s end of life.

12. A computer readable medium comprising program code that configures a processor to perform a method for predicting end of life of a Li-ion battery, said program code comprising:

a program code for depolarizing the battery to a quiescent state;

a program code for partial charging the battery;

a program code for measuring an open circuit voltage of the battery before and after the step of partial charging;

a program code for ending the partial charging upon measurement of an open circuit voltage of n*3.5 V, wherein n is equal to the number of cells of the battery;

a program code for determining a state of charge value of the battery corresponding to the open circuit voltage measured before and after the step of partial charging;

a program code for correlating a charge energy with a change in state of charge and extrapolating to get the battery'"'"'s full capacity; and

a program code for performing trend analysis of the battery'"'"'s full capacity over time to predict the battery'"'"'s end of life.