Three-dimensional structured printing

• US 7,578,958 B2
• Filed: 05/24/2002
• Issued: 08/25/2009
• Est. Priority Date: 05/24/2001
• Status: Active Grant

• Current Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Original Assignee: Huntsman Advanced Materials Americas, Inc.
• Inventors: Patel, Ranjana C., Peace, Richard J., Zhao, Yong
• Primary Examiner(s): Tentoni; Leo B
• Application Number:
  US10/479,303
• Publication Number:
  US 20040145088A1
• Time in Patent Office: 2,650 Days
• Field of Search: 264/113, 264/208, 264/401, 264/497, 264/333, 264/109, 264/463, 264/460, 156/384, 428/703
• US Class Current: 264/460
• CPC Class Codes: B29C 41/003 characterised by the choice of material
• CPC Class Codes: B29C 64/165 using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
• CPC Class Codes: B29C 67/246 Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM] casting monomers B29C39/006, mixing construction B29B7/74
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/10 Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials

Abstract

A process for forming a three-dimensional article in sequential layers in accordance with a digital model of the article. The process comprises the steps of defining a layer of powder or liquid material, applying a liquid reagent to the layer in a pattern corresponding to the digital model, and repeating these steps to form successive layers. The powder or liquid material comprises a first reactive component and the applied liquid includes a second active component capable of reacting with the first reactive component so that the article is built up in layers. The characteristics of the layers vary across those layers and/or the properties vary from layer to layer.

Claims

1. A process for forming a three-dimensional article in sequential layers in accordance with a model of the article, the process comprising the steps of:

defining a layer of a first material;

applying a second material in the form of a liquid reagent to the layer of the first material in a pattern corresponding to the model; and

repeating these steps to form successive layers; and

in which the deposited layer comprises a first reactive component and the applied liquid material includes a reactive diluent having a reactive group selected from an oxetane and a second active component capable of either reacting with the first reactive component or facilitating the first reactive component to react with itself, whereby the article is built up in layers; and

in which the characteristics of at least some of the layers vary across those layers and/or the properties vary from layer to layer and in which the article formed by the sequential layers is substantially void free, apart from voids programmed in the model and wherein the first material is a thermoplastic powder and the whole of the applied liquid material is incorporated with the thermoplastic powder.

2. A process as claimed in claim 1, in which the applied liquid material is a filly curable resin.

3. A process as claimed in claim 2, in which the powder substantially comprises the first reactive component.

4. A process as claimed in claim 1, in which the diluent is present in the range 30-60% by volume.

5. A process as claimed in claim 1, in which the powder and/or the applied liquid contains an organic or inorganic filler, a pigment, nanoparticles, a dye and/or a surfactant.

6. A process as claimed in claim 2, in which the thickness of the applied powder layers is in the range 1 to 1000 μ

m.

7. A process as claimed in claim 2, in which the applied liquid material includes a proportion of the first reactive component in the first material.

8. A process as claimed in claim 1, in which the second active component represents 1 to 80% of the applied liquid material.

9. A process as claimed in claim 1, in which the applied liquid material is coloured.

10. A process as claimed in claim 1, in which the applied liquid material contains colloidal or nano-particles.

11. A process as claimed in claim 1, in which the viscosity of the applied liquid material is in the range of 2 to 500 cps at room temperature.

12. A process as claimed in claim 1, in which the second active component acts as a catalyst to facilitate cross-linking of the first reactive component.

13. A process as claimed in claim 1, in which the applied liquid material is deployed through a plurality of nozzles.

14. A process as claimed in claim 13, in which the nozzles form part of an inkjet printer or a device including a set of nozzles generally equivalent to an inkjet print head.

15. A process as claimed in claim 14, in which the nozzles operate on the principles of piezo inkjet technology.

16. A process as claimed in claim 13, in which the size of the nozzle openings is in the range 10 to 200 μ

m and/or the size of the applied droplets is in the range 10 to 200 μ

m.

17. A process as claimed in claim 1, in which the size of the nozzle openings is in the range of 0.1 to 200 μ

m and/or the sizes of the applied droplets is in the range 0.1 to 200 μ

m.

18. A process as claimed in claim 1, in which the applied liquid material has a viscosity in the range 2 to 30 cps at ambient temperatures.

19. A process as claimed in claim 1, further including the step of irradiating the article.

20. A process as claimed in claim 19, in which the article is irradiated, pixel by pixel, line by line or layer by layer, either randomly or clustered.

21. A process as claimed in claim 19, in which the article is irradiated after several layers have been formed.

22. A process as claimed in claim 19, in which the article is irradiated after all the layers have been formed.

23. A process as claimed in claim 19, in which the irradiating step employs electromagnetic radiation.

24. A process as claimed in claim 19, in which the irradiating step employs UV radiation.

25. A process as claimed in claim 1, in which the model is a digital model.

26. A process as claimed in claim 1, in which the first and/or second material comprise respective mixtures of the first reactive and second active components.

27. A process as claimed in claim 1, in which the thickness of the formed layer is from 30 μ

m to 200 μ

m.

28. A process as claimed in claim 1, in which a plurality of different liquids is applied to respective deposited layers of the first material.

29. A process as claimed in claim 1, in which a plurality of different liquids is applied to a single deposited layer of the first material, in the same or different locations.

30. A process as claimed in claim 29, in which the different liquids are applied in a single pass.

31. A process as claimed in claim 29, in which the different liquids are applied in respective sequential passes.

32. A process as claimed in claim 1, in which at least one of the deposited layers comprises a different material.

33. A process as claimed in claim 1, in which the layers formed have differing thicknesses.

34. A process as claimed in claim 1, in which a layer is formed with a varying thickness over its extent.

35. A process as claimed in claim 1, including the step of varying the number of pixel drops and/or varying the applied liquid per pixel, per line applied and/or per layer, in order to achieve variable properties in the article.

36. A process as claimed in claim 10, wherein the colloidal or nano-particles are selected from the group consisting of silica, organic core-shells (made from micro-emulsions), metals or alloys.