Switchable polymer-dispersed liquid crystal optical elements

• US 7,583,423 B2
• Filed: 11/08/2005
• Issued: 09/01/2009
• Est. Priority Date: 07/12/1996
• Status: Expired due to Fees

• Current Assignee: Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Kelly, William J., Hagan, Bill, Epling, Bob, Sutherland, Richard L.
• Primary Examiner(s): Lavarias; Arnel C
• Application Number:
  US11/268,584
• Publication Number:
  US 20060114533A1
• Time in Patent Office: 1,393 Days
• Field of Search: None
• US Class Current: 359/15
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: G02B 5/32 Holograms used as optical elements
• CPC Class Codes: G02F 1/1326 Liquid crystal optical waveguides or liquid crystal cells specially adapted for gating or modulating between optical waveguides
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G02F 1/13712 the liquid crystal having negative dielectric anisotropy
• CPC Class Codes: G02F 1/31 Digital deflection, i.e. optical switchingG02F1/33 takes precedence
• CPC Class Codes: G02F 2201/346 distributed (Bragg) reflector
• CPC Class Codes: G02F 2203/05 wavelength dependent
• CPC Class Codes: G02F 2203/055 wavelength filtering
• CPC Class Codes: G02F 2203/585 Add/drop devices
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2001/0264 Organic recording material
• CPC Class Codes: G03H 2001/2231 Reflection reconstruction
• CPC Class Codes: G03H 2001/2234 Transmission reconstruction
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound

Abstract

Transmission and reflection type holograms may be formed utilizing a novel polymer-dispersed liquid crystal (PDLC) material and its unique switching characteristics to form optical elements. Applications for these switchable holograms include communications switches and switchable transmission, and reflection red, green, and blue lenses. The PDLC material offers all of the features of holographic photopolymers with the added advantage that the hologram can be switched on and off with the application of an electric field. The material is a mixture of a polymerizable monomer and liquid crystal, along with other ingredients, including a photoinitiator dye. Upon irradiation, the liquid crystal separates as a distinct phase of nanometer-size droplets aligned in periodic channels forming the hologram. The material is called a holographic polymer-dispersed liquid crystal (H-PDLC).

Claims

1. An optical system for wavelength selection comprising:

at least one coherent light source for inputting multiple wavelengths;

a first polymer-dispersed liquid crystal switchable holographic component for diffracting a first single wavelength of an incident beam;

a second polymer-dispersed liquid crystal switchable holographic component for diffracting a second single wavelength of an incident beam, wherein the first and second polymer-dispersed liquid crystal switchable holographic components are located in stacked relationship with one another and placed in the path of the incident beam; and

an output component alternately configured for receiving from the first and second polymer-dispersed liquid crystal holographic;

(a) all undiffracted multiple wavelengths; and

(b) both the first and second diffracted single wavelengths and the undiffracted multiple wavelengths;

wherein the output component is not a polymer-dispersed liquid crystal switchable holographic component.

2. The optical system for wavelength selection according to claim 1, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components are capable of diffracting a wavelength in the presence of an applied voltage and transmitting the remaining multiple inputted wavelengths in the absence of the applied voltage.

3. The optical system for wavelength selection according to claim 1, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components are capable of transmitting all of the multiple inputted wavelengths in the presence of an applied voltage.

4. The optical system for wavelength selection according to claim 1, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components are capable of diffracting a wavelength in the absence of an applied voltage and transmitting the remaining multiple inputted wavelengths in the presence of the applied voltage.

5. The optical system for wavelength selection according to claim 1, wherein each of the first and second polymer-dispersed liquid crystal switchable holographic components are capable of transmitting all of the multiple inputted wavelengths in the absence of an applied voltage.

6. The optical system for wavelength selection according to claim 1, wherein the multiple wavelength input component is a laser.

7. The optical system for wavelength selection according to claim 1, wherein the multiple wavelength input component is a fiber.

8. The optical system for wavelength selection according to claim 1, wherein the multiple wavelength input component is a waveguide.

9. The optical system for wavelength selection according to claim 1, wherein the output component is a single-mode fiber.

10. The optical system for wavelength selection according to claim 1, wherein the output component is an array of single-mode fibers.

11. The optical system for wavelength selection according to claim 1, wherein the output component is a single-mode waveguide.

12. The optical system for wavelength selection according to claim 1, wherein the output component is an array of single-mode waveguides.

13. The optical system for wavelength selection according to claim 1, wherein the output component is a detector.

14. The optical system for wavelength selection according to claim 1, wherein the output component is a combiner.

15. The optical system for wavelength selection according to claim 1, wherein each of the multiple polymer-dispersed liquid crystal switchable holographic components comprises:

a pair of transparent conductive slides;

a voltage source electrically contacted to the pair of transparent conductive slides;

at least one spacer for separating the pair of transparent conductive slides;

a layer of polymer-dispersed liquid crystal material located within the confines of the pair of transparent conductive slides and the at least one spacer; and

a switchable holographic grating formed within the layer of polymer-dispersed liquid crystal material.

16. The optical system for wavelength selection according to claim 15, wherein the polymer-dispersed liquid crystal material is made from:

(a) a polymerizable monomer comprising at least one acrylate;

(b) at least one type of liquid crystal material;

(c) a chain-extending monomer;

(d) a coinitiator; and

(e) a photoinitiator.

17. The optical system for wavelength selection according to claim 16, wherein the polymerizable monomer comprises at least one of a di-, tri-, tetra-, and pentaacrylate.

18. The optical system for wavelength selection according to claim 17, wherein the polymerizable monomer is at least one acrylate selected from the group consisting of triethyleneglycol diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, pentaerythritol tetracrylate, and dipentaerythritol pentaacrylate.

19. The optical system for wavelength selection according to claim 18, wherein the polymerizable monomer comprises a mixture of tri- and pentaacrylates.

20. The optical system for wavelength selection according to claim 19, wherein the polymerizable monomer comprises dipentaerythritol pentaacrylate.

21. The optical system for wavelength selection according to claim 16, wherein the polymer-dispersed liquid crystal material further comprises a surfactant.

22. The optical system for wavelength selection according to claim 21, wherein the surfactant is octanoic acid.

23. The optical system for wavelength selection according to claim 16, wherein the polymerizable monomer comprises dipentaerythritol pentaacrylate, the at least one liquid crystal comprises at least one cyanobiphenyl, the chain-extending monomer is N-vinyl pyrrolidone, the coinitiator is N-phenylglycine, and the photoinitiator is rose bengal.