Porous composites containing hydrocarbon-soluble well treatment agents and methods for using the same

• US 7,598,209 B2
• Filed: 01/26/2006
• Issued: 10/06/2009
• Est. Priority Date: 01/26/2006
• Status: Active Grant

• Current Assignee: Baker Hughes Holdings LLC (Baker Hughes Company)
• Original Assignee: BJ Services Company
• Inventors: Kaufman, Philip B., Becker, Harold L.
• Primary Examiner(s): Kugel; Timothy J.
• Assistant Examiner(s): Admasu; Atnaf
• Application Number:
  US11/340,052
• Publication Number:
  US 20070173417A1
• Time in Patent Office: 1,349 Days
• Field of Search: 507/269
• US Class Current: 507/269
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/54 Compositions for in situ inhibition of corrosion in boreholes or wells
• CPC Class Codes: C09K 8/70 characterised by their form or by the form of their components, e.g. foams
• CPC Class Codes: C09K 8/706 Encapsulated breakers
• CPC Class Codes: C09K 8/80 Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open

Abstract

Composites containing a hydrocarbon-soluble well treatment agent may be supplied to a well using a porous particulate. Such well treatment agents may for example inhibit the formation of paraffins, salts, gas hydrates, asphaltenes and/or other deleterious processes such as emulsification (both water-in-oil and oil-in-water). Further, other well treatment agents include foaming agents, oxygen scavengers, biocides and surfactants as well as other agents wherein slow release into the production well is desired.

Claims

1. A composite comprising a porous particulate and a hydrocarbon-soluble well treatment agent wherein the porosity and permeability of the porous particulate is such that the hydrocarbon-soluble well treatment agent is absorbed into the interstitial spaces of the porous particulate material and further wherein the composite is prepared by the addition of the well treatment agent in an organic solvent to the porous particulate and the porous particulate is an aluminosilicate, silicon carbide, alumina or silica-based material.

2. The composite of claim 1, wherein the hydrocarbon-soluble well treatment agent is a polymeric wax crystal modifier.

3. The composite of claim 2, wherein the polymeric wax crystal modifier is selected from the group consisting of ethylene/vinyl acetate copolymers, homopolymers and copolymers of acrylate esters, phenol-aldehyde resins and olefin/maleic esters copolymers.

4. The composite of claim 2, wherein the hydrocarbon-soluble well treatment agent further comprises at least one member selected from the group consisting of demulsifiers, corrosion inhibitors, paraffin inhibitors, gas hydrate inhibitors, flocculating agents and asphaltene dispersants.

5. The composite of claim 1, wherein the porous particulate has a porosity of no greater than 30%.

6. The composite of claim 1, wherein the porous particulate is an aluminosilicate.

7. The composite of claim 1, wherein the porous particulate is a proppant.

13. A method for treating a well penetrating a subterranean formation, comprising introducing into the well the composite of claim 1, wherein the hydrocarbon-soluble well treatment agent is leached out into the well fluid over a period of time.

14. The method of claim 13, wherein the hydrocarbon-soluble well treatment agent comprises at least member selected from the group consisting of demulsifiers, corrosion inhibitors, paraffin inhibitors, gas hydrate inhibitors, flocculating agents and asphaltene dispersants.

15. The method of claim 13, wherein the hydrocarbon-soluble well treatment agent is a polymeric wax crystal modifier.

16. The method of claim 15, wherein the polymeric wax crystal modifier is selected from the group consisting of ethylene/vinyl acetate copolymers, homopolymers and copolymers of acrylate esters, phenol-aldehyde resins and olefin/maleic esters copolymers.

17. The method of claim 13, wherein the porous particulate has a porosity of no greater than 30%.

8. A composite comprising a porous proppant and a hydrocarbon-soluble oilfield chemical well treatment agent, the porosity of the porous particulate being no greater than 30% and sufficient to at least partially absorb into its interstitial spaces the hydrocarbon-soluble oilfield chemical well treatment agent.

9. The composite of claim 8, wherein the porous proppant is selected from the group consisting of porous ceramics, inorganic oxides and organic polymeric materials.

10. The composite of claim 8, wherein the hydrocarbon-soluble oilfield chemical well treatment agent is a polymeric wax crystal modifier.

11. The composite of claim 10, wherein the polymeric wax crystal modifier is selected from the group consisting of ethylene/vinyl acetate copolymers, homopolymers and copolymers of acrylate esters, phenol-aldehyde resins and olefin/maleic esters copolymers.

12. The composite of claim 8, wherein the hydrocarbon-soluble oilfield chemical well treatment agent comprises at least one member selected from the group consisting of demulsifiers, corrosion inhibitors, paraffin inhibitors, gas hydrate inhibitors, flocculating agents and asphaltene dispersants.