Remote indicating cumulative thermal exposure monitor and system for reading same

• US 7,604,398 B1
• Filed: 03/26/2007
• Issued: 10/20/2009
• Est. Priority Date: 03/26/2007
• Status: Expired due to Fees

• Current Assignee: Gerald A. Coles, James Michael Zerkus, Jeffrey W. Akers
• Original Assignee: Gerald A. Coles, James Michael Zerkus, Jeffrey W. Akers
• Inventors: Zerkus, James Michael, Akers, Jeffrey W., Coles, Gerald A.
• Primary Examiner(s): Caputo; Lisa M
• Assistant Examiner(s): Jagan; Mirellys
• Application Number:
  US11/728,565
• Time in Patent Office: 939 Days
• Field of Search: 374/102, 374/187, 374/195, 374/188, 374/205, 116/216, 116/221, 340/584, 340/588
• US Class Current: 374/102
• CPC Class Codes: G01K 1/02 Means for indicating or recording specially adapted for thermometers
• CPC Class Codes: G01K 3/04 in respect of time
• CPC Class Codes: G01K 5/483 using materials with a configuration memory, e.g. Ni-Ti alloys

Abstract

Cumulative thermal exposures monitors and remote indicating cumulative thermal exposure monitors and system for reading the same are disclosed. The monitors have a thermally insulative housing with a cavity and a thermally-responsive member therein formed of shape memory material, which may be provided with a coating or sheath of insulative or shape memory polymer material, that gradually changes from a first shape to a second shape over a prescribed temperature range wherein the thermal capacity and insulative properties of the housing, cavity, and shape memory material transition temperature range are correlated relative to one another and calibrated to closely match a thermal decay profile (time-temperature profile) of the product being monitored. In remote indicating embodiments, the data can be retrieved remotely via RF transponder technology without directly viewing the monitor device.

Claims

1. A remote indicating time-temperature integrating cumulative thermal exposure monitor for monitoring heat energy absorbed over time and indicating the degree of deterioration based on a time and temperature thermal deterioration profile of a perishable product that has a known time and temperature thermal deterioration profile and is prescribed to be maintained within a preferred storage temperature range, comprising:

a thermally-conductive housing having a fluid sealed interior cavity, said housing formed of a material having thermal capacity and insulative properties which moderate heat energy conducted therethrough over time;

an electrically conductive thermally-responsive member movably disposed in said interior cavity formed of a shape memory material selected from the group consisting of shape memory alloys, shape memory polymer composites, and shape memory materials coated or sheathed with insulating material or polymers that moderate the influx of heat energy into said thermally-responsive member, said thermally-responsive member having a phase transition temperature range encompassing at least the preferred storage temperature range and having a first shape at temperatures below said phase transition temperature range and gradually changing to a second shape at temperatures within or above the preferred storage temperature range;

a radio frequency (RF) resonant circuit associated with said housing operatively coupled with said electrically conductive thermally-responsive member;

said thermal capacity and insulative properties of said housing material and said shape memory material phase transition temperature range calibrated relative to one another to function in mutual cooperation such that said housing moderates heat energy conducted therethrough over time and said thermally-responsive member absorbs the heat energy and gradually assumes its said second shape upon absorption of heat energy over time to closely match the known time and temperature thermal deterioration profile of the perishable product;

said electrically conductive thermally responsive member moves relative to said resonant circuit as it changes from its said first shape to said second shape and remains substantially in a position at which it was last moved, regardless of subsequent exposures of said shape memory material to lower temperatures; and

a resonant frequency is induced in said resonant circuit in proportion to the change in heat absorbed by said thermally-responsive member to indicate the cumulative amount of heat energy absorbed in and above said preferred storage temperature range and whether, at any time, the temperature has been above said preferred storage temperature range for a period of time sufficient to cause any degree of deterioration based on the time and temperature thermal deterioration profile of the perishable product.

2. The remote indicating thermal exposure monitor according to claim 1, wherein

said radio frequency (RF) resonant circuit is capacitively coupled with said electrically conductive thermally-responsive member.

3. The remote indicating thermal exposure monitor according to claim 1, wherein:

said thermally-responsive member is formed of shape memory polymer or polymer composite foam having a phase transition temperature range encompassing at least the preferred storage temperature range and having a first shape at temperatures below said phase transition temperature range and gradually changing to a second shape at temperatures within or above the preferred storage temperature range; and

said foam is reduced in density as it changes its said second shape sufficient to induce a resonant frequency in said resonant circuit in proportion to the change in heat absorbed by said foam to indicate the cumulative amount of heat energy absorbed in and above said preferred storage temperature range and whether, at any time, the temperature has been above said preferred storage temperature range for a period of time sufficient to cause any degree of deterioration based on the time and temperature thermal deterioration profile of the perishable product.

4. The remote indicating thermal exposure monitor according to claim 1, wherein

said thermally-conductive housing has a transparent window portion;

and

said thermally responsive member is visible through said window portion as it changes from its said first shape to said second shape.

5. The remote indicating thermal exposure monitor according to claim 4, further comprising:

indicator means visible through said window portion and associated with said thermally-responsive member to be moved from an initial position thereby as said thermally-responsive member gradually changes from said first shape to said second shape;

wherein

said indicator means remains substantially in a position at which it was last moved by said thermally-responsive member, regardless of subsequent exposures of said shape memory material to lower temperatures, to indicate the cumulative amount of heat energy absorbed in and above said preferred storage temperature range and whether, at any time, the temperature has been above said preferred storage temperature range for a period of time sufficient to cause any degree of deterioration based on the time and temperature thermal deterioration profile of the perishable product.

6. The remote indicating thermal exposure monitor according to claim 1, wherein

said radio frequency (RF) resonant circuit is a transponder that transmits data representing the cumulative amount of heat energy absorbed in and above said preferred storage temperature range and whether, at any time, the temperature has been above said preferred storage temperature range for a period of time sufficient to cause any degree of deterioration based on the time and temperature thermal deterioration profile of the perishable product.

7. The remote indicating thermal exposure monitor according to claim 6, wherein

said radio frequency (RF) resonant circuit includes an output coupled with at least one diode-resistor-capacitor circuit that rectifies a portion of energy received and transmits or retransmits a series of decaying pulses having variable decay times to produce an identifying code.

8. The remote indicating thermal exposure monitor according to claim 6, further comprising:

radio frequency (RF) reader/interrogator means that stimulates and receives a reply from said radio frequency (RF) circuit and records or displays said data.

9. The remote indicating thermal exposure monitor according to claim 8, wherein

said radio frequency (RF) reader/interrogator utilizes non-ionizing electromagnetic radiation to stimulate and receive said data from said cumulative thermal exposure monitor.

10. The remote indicating thermal exposure monitor according to claim 9, wherein

said radio frequency (RF) reader/interrogator has a transmitter and multiple receivers or antenna receiver combinations that are positioned to receive data from stimulated thermal exposure monitor units from different angles, whereby data from several monitors can be compared and used to reinforce weak signals or reject redundant or erroneous transmissions in a power signal processing technique.

11. The remote indicating thermal exposure monitor according to claim 9, wherein

said radio frequency (RF) reader/interrogator utilizes non-ionizing electromagnetic radiation in a swept or stepped carrier frequency modulated by a series of pulses wherein the variation in the frequency re-radiated or returned and the presence or absence or modification of the pulse train is used to convey said data, and data representing the identification of a respective said thermal exposure monitor.

12. The remote indicating thermal exposure monitor according to claim 11, wherein

said radio frequency (RF) reader/interrogator utilizes a unique code with a high degree of auto-correlation and a low degree of cross-correlation to uniquely identify a series of said thermal exposure monitors.