Sprayable skin composition and method of applying

• US 7,608,655 B2
• Filed: 08/12/2004
• Issued: 10/27/2009
• Est. Priority Date: 08/12/2004
• Status: Expired due to Fees

• Current Assignee: Illinois Tool Works Inc.
• Original Assignee: Illinois Tool Works Inc.
• Inventors: Lauersdorf, William F., Whitley, Kimberly A.
• Primary Examiner(s): NERANGIS, VICKEY MARIE
• Application Number:
  US10/916,817
• Publication Number:
  US 20060036011A1
• Time in Patent Office: 1,902 Days
• Field of Search: 524/456, 264/255
• US Class Current: 524/456
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: Y10T 428/24994 Fiber embedded in or on the surface of a polymeric matrix

Abstract

A sprayable skin composition and method of applying the skin composition is provided for use in reinforcing plastic products. The skin composition comprises a mixture of reinforcing wollastonite fibers and a synthetic resin, along with additional additives such as thixotropic agents, accelerators, stabilizers, and an air release agent. The composition is applied by spraying onto a gel coat in a mold and forms a gel within 1 to 3 minutes without the formation of air bubbles.

Claims

1. A sprayable skin composition for use in reinforcing plastic products comprising:

about 15% to about 25% by weight of said sprayable skin composition of wollastonite reinforcing fibers;

about 50% to about 80% by weight of said sprayable skin composition synthetic polyester resin wherein the synthetic polyester resin is orthophthalic polyester resins, isophthalic polyester resins, or mixtures thereof; and

about 5% to about 15% by weight of said sprayable skin composition of a styrene monomer;

wherein said sprayable skin composition gels in about 1 to about 3 minutes at ambient temperature after being sprayed onto a gel coated surface without the formation of air bubbles.

2. The sprayable skin composition of claim 1 wherein said wollastonite has a mesh size of at least 100.

3. The sprayable skin composition of claim 1 wherein said sprayable skin composition further comprises an accelerator.

4. The sprayable skin composition of claim 3 wherein said accelerator is selected from dimethyl para-toluidine, dimethyl aniline, diethyl aniline, dimethyl acetalacetamide, cobalt octoate, potassium octoate, copper naphthanate, quaternary ammonium salts, or mixtures thereof.

5. The sprayable skin composition of claim 1 further comprising an air release additive.

6. The sprayable skin composition of claim 1 further comprising a thixotropic agent.

7. The sprayable skin composition of claim 6 wherein said thixotropic agent comprises a combination of an organoclay and fumed silica.

8. The sprayable skin composition of claim 1 further comprising a stabilizer.

9. The sprayable skin composition of claim 1 further comprising from about 5 to about 20% by weight chopped fibers.

10. A sprayable skin composition for reinforcing products comprising:

from about 15 to about 25% by weight of said sprayable skin composition of wollastonite;

from about 50% to about 80% by weight of said sprayable skin composition of a synthetic polyester resin wherein the synthetic polyester resin is orthophthalic polyester resins, isophthalic polyester resins, or mixtures thereof;

from about 5 to about 15% by weight of said sprayable skin composition of a styrene monomer;

from about 0 to about 5% by weight of said sprayable skin composition of a thixotropic agent;

from about 0 to about 5% by weight of said sprayable skin composition of an accelerator; and

from about 0 to about 5% by weight of said sprayable skin composition of an air release additive;

wherein said sprayable skin composition gels in about 1 to about 3 minutes at ambient temperature after being sprayed onto a gel coated surface without the formation of air bubbles.

11. The sprayable skin composition of claim 10 wherein said accelerator is selected from dimethyl para-toluidine, dimethyl aniline, diethyl aniline, dimethyl acetalacetamide, cobalt octoate, potassium octoate, copper naphthanate, quaternary ammonium salts, or mixtures thereof.

12. The sprayable skin composition of claim 10 further comprising from about 0 to about 1% by weight of said sprayable skin composition of a stabilizer.

13. The sprayable skin composition of claim 10 further comprising from about 5 to about 20% by weight of said sprayable skin composition chopped fibers.

14. A method of applying a sprayable skin composition comprising:

providing a molding surface;

applying a gel coat to said molding surface;

providing a sprayable skin composition comprising about 15% to about 25% by weight of said sprayable skin composition wollastonite reinforcing fibers, about 50% to about 80% by weight of said sprayable skin composition synthetic polyester resin wherein the synthetic polyester resin is orthophthalic polyester resins, isophthalic polyester resins, or mixtures thereof, and about 5% to about 15% by weight of said sprayable skin composition of a styrene monomer;

applying said sprayable skin composition to said gel coat by spraying, wherein said sprayable skin composition gels within about 1 to about 3 minutes at ambient temperature after application without the formation of air bubbles.

15. The method of claim 14 wherein said molding surface comprises a mold defining a mold cavity.

16. The method of claim 15 wherein said mold is an open mold.

17. The method of claim 14 further comprising allowing said sprayable skin composition to cure.

18. The method of claim 17 further comprising removing the cured sprayable skin composition with said gel coat from said molding surface.

19. The method of claim 14 further comprising applying one or more bulk reinforcing layers over said sprayable skin composition.

20. The product made by the method of claim 14.