Multilayer ceramic NOx gas sensor device

• US 7,611,612 B2
• Filed: 07/14/2005
• Issued: 11/03/2009
• Est. Priority Date: 07/14/2005
• Status: Active Grant

• Current Assignee: EmiSense Technologies, LLC (Trelleborg AB)
• Original Assignee: Ceramatec, Inc.
• Inventors: Nair, Balakrishnan G., Nachlas, Jesse
• Primary Examiner(s): Olsen; Kaj K
• Application Number:
  US11/182,278
• Publication Number:
  US 20070012566A1
• Time in Patent Office: 1,573 Days
• Field of Search: 204/424, 204/426, 204/427, 205/781, 205/785
• US Class Current: 204/426
• CPC Class Codes: G01N 27/4067 Means for heating or controlling the temperature of the solid electrolyte

Abstract

A mixed potential NO_x sensor apparatus for measuring the total NO_x concentration in a gas stream is disclosed. The NO_x sensing apparatus comprises a multilayer ceramic structure with electrodes for sensing both oxygen and NO_x gas concentrations and includes screen-printed metalized patterns that function to heat the ceramic sensing element to the proper temperature for optimum performance. This design may provide advantages over the existing technology by miniaturizing the sensing element to provide potentially faster sensor light off times and thereby reduce undesired exhaust gas emissions. By incorporating the heating source within the ceramic sensing structure, the time to reach the temperature of operation is shortened, and thermal gradients and stresses are minimized. These improvements may provide increased sensor performance, reliability, and lifetime.

Claims

1. A gas sensor element for detecting the concentration of a gas constituent in an exhaust gas, the sensor element comprising:

a sensor body including a first sensing electrode that generates a voltage signal that is a function of the concentration of a first gas constituent being measured;

a second sensing electrode that generates a voltage signal that is a function of the concentration of a second gas constituent being measured, wherein the first and second sensing electrodes are configured to interact with said first and second gas constituents independently of each other;

a first heater element integrated into the ceramic body; and

a second heater element longitudinally displaced from the first heater element and integrated into the ceramic body, the first and second heater elements being placed and adapted to create first and second temperature zones.

2. The gas sensor element of claim 1 wherein the first and second heater elements are separate electrical circuits that may share a common ground potential electrical lead.

3. The gas sensor element of claim 1 wherein the first and second heater elements are independently controlled electrical circuits.

4. The gas sensor element of claim 1 wherein the first temperature zone is from about 500°

C. to about 900°

C.

5. The gas sensor element of claim 4, wherein the first temperature zone is from about 650°

C. to about 750°

C.

6. The gas sensor element of claim 5, wherein the first temperature zone is about 700°

C.

7. The gas sensor element of claim 1, wherein the second temperature zone is from about 400°

C. to about 600°

C.

8. The gas sensor element of claim 7, wherein the second temperature zone is from about 450°

C. to about 550°

C.

9. The gas sensor element of claim 8, wherein the second temperature zone is about 500°

C.

10. The gas sensor element of claim 1, wherein the first sensing electrode is placed on an outside surface of the body.

11. The gas sensor element of claim 1 further comprising a metallic air reference electrode that is exposed to atmospheric air containing about 20.9% oxygen.

12. The gas sensor element of claim 11, wherein the metallic air reference electrode is composed of a metal selected from the group consisting of platinum, silver, gold, rhodium or any combination thereof.

13. The gas sensor element of claim 1, further comprising a sealed metal/metal oxide reference electrode.

14. The gas sensor element of claim 13, wherein the sealed metal/metal oxide reference electrode is a Ni/NiO electrode.

15. The gas sensor element of claim 1, wherein the first electrode is selected from the group consisting of NO_x-sensing electrodes, oxygen-sensing electrodes, hydrocarbon-sensing electrodes, SO₂-sensing electrodes, and CO-sensing electrodes.

16. The gas sensor element of claim 1, wherein the sensor body has a generally planar configuration.

17. The gas sensor element of claim 1, wherein the sensor body has a generally tubular configuration.

18. A gas sensor element for detecting the concentration of two or more gas constituents in an exhaust gas, the sensor element comprising:

a multilayer ceramic sensor body including a first sensing electrode placed on an outside surface of the body, and a second sensing electrode placed on an outside surface of the body, wherein at least one of the first and second sensing electrodes is a potentiometric sensing electrode for sensing a gas other than oxygen, and wherein the first and second sensing electrodes are configured to interact with an exhaust gas independently of each other;

a metallic shared air reference electrode;

a first heater element integrated into the ceramic body;

a second heater element integrated into the ceramic body, the first and second heater elements being placed and adapted to create first and second temperature zones associated with the first and second sensing electrodes, respectively.

19. The gas sensor element of claim 18 wherein the first and second heater elements are separate electrical circuits that may share a common ground potential electrical lead.

20. The gas sensor element of claim 18 wherein the first and second heater elements are independently controlled electrical circuits.

21. The gas sensor element of claim 18 wherein the first temperature zone is from about 500°

C. to about 900°

C., or from about 650°

C. to about 750°

C.

22. The gas sensor element of claim 21, wherein the first temperature zone is about 700°

C.

23. The gas sensor element of claim 18, wherein the second temperature zone is from about 400°

C. to about 600°

C., or from about 450°

C. to about 550°

C.

24. The gas sensor element of claim 23, wherein the second temperature zone is about 500°

C.

25. The gas sensor element of claim 18, wherein the metallic shared air reference electrode is exposed to atmospheric air containing about 20.9% oxygen.

26. The gas sensor element of claim 18, wherein the metallic shared air reference electrode is composed of a metal selected from the group consisting of platinum, silver, gold, rhodium or any combination thereof.

27. The gas sensor element of claim 18, wherein the metallic shared air reference electrode is sealed and the partial pressure of oxygen is established by a metal/metal-oxide equilibrium such as Ni/NiO.

28. The gas sensor element of claim 18, wherein the first or second electrode is selected from the group consisting of NO_x-sensing electrodes, oxygen-sensing electrodes, hydrocarbon-sensing electrodes, SO₂-sensing electrodes, and CO-sensing electrodes.

29. The gas sensor element of claim 18, wherein the sensor body has a generally planar configuration.

30. The gas sensor element of claim 18, wherein the sensor body has a generally tubular configuration.

31. A gas sensor element for detecting the concentration of a gas constituent in an exhaust gas, the sensor element comprising:

a sensor body including a first sensing electrode that generates a voltage signal measured potentiometrically, that is a function of the concentration of a first gas constituent being measured, said first gas constituent comprising NO or NO₂;

a second sensing electrode that generates a voltage signal that is a function of the concentration of a second gas constituent being measured, wherein the first and second sensing electrodes are configured to interact with said first and second gas constituents independently of each other;

a first heater element integrated into the ceramic body; and

a second heater element integrated into the ceramic body, the first and second heater elements being placed and adapted to create first and second temperature zones.