Method for producing acrylic acid

• US 7,612,230 B2
• Filed: 01/28/2005
• Issued: 11/03/2009
• Est. Priority Date: 01/30/2004
• Status: Expired due to Fees

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Takahashi, Tsukasa, Shima, Masahide
• Primary Examiner(s): Zucker; Paul A
• Assistant Examiner(s): VALENROD, YEVGENY
• Application Number:
  US10/585,793
• Publication Number:
  US 20070129570A1
• Time in Patent Office: 1,740 Days
• Field of Search: None
• US Class Current: 562/535
• CPC Class Codes: C07C 45/52 by dehydration and rearrangement involving two hydroxy groups in the same molecule
• CPC Class Codes: C07C 47/22 Acryaldehyde; Methacryaldehyde
• CPC Class Codes: C07C 51/235 of —CHO groups or primary alcohol groups
• CPC Class Codes: C07C 51/252 of propene, butenes, acrolein or methacrolein
• CPC Class Codes: C07C 57/04 Acrylic acid; Methacrylic acid

Abstract

There is provided a novel process for producing acrylic acid by which acrylic acid can be obtained from a raw material independent of petroleum. The process for producing acrylic acid according to the present invention comprises the steps of: applying a dehydration reaction to glycerol as a raw material in a gas phase; and then applying a gas phase oxidation reaction to a gaseous reaction product formed by the dehydration reaction.

Claims

1. A process for producing acrylic acid, comprising the steps of:

a) vaporizing a raw material comprising an aqueous glycerol solution to generate a first gas, wherein said aqueous glycerol solution has a water content, of not more than 20% by weight;

b) applying a dehydration reaction to glycerol in a gas phase that includes said first gas; and

c) applying a gas phase oxidation reaction to a gaseous reaction product formed by the dehydration reaction to obtain said acrylic acid; and

d) conducting the dehydration reaction and the gas phase oxidation reaction in a single-type reactor comprising one reaction tube, where said one reaction tube is filled with catalysts for the dehydration reaction and for the gas phase oxidation reaction uniformly mixed together or with a catalyst which functions both for the dehydration reaction and the gas phase oxidation reaction, thus conducting the dehydration reaction and the gas phase oxidation reaction in said one reaction tube at the same time.

2. The process for producing acrylic acid according to claim 1, and further comprising the steps of:

a) adding an inert gas to the first gas to obtain a resultant mixed gas, wherein the inert gas is selected from the group consisting of nitrogen gas, carbon dioxide gas and rare gas; and

b) controlling a concentration of said inert gas in said resultant mixed gas to a concentration of not less than 50% by volume.

3. The process for producing acrylic acid according to claim 1, wherein the gas phase in which the dehydration reaction is conducted is a mixed gas comprising glycerol, water vapor and oxygen.

4. The process for producing acrylic acid according to claim 3, wherein the amount of the water vapor relative to the glycerol in the mixed gas is not larger than 1.2 times by mol.

5. The process for producing acrylic acid according to claim 1, wherein the acrylic acid is used to produce a water-absorbent resin.

6. The process for producing acrylic acid according to claim 1, further comprising the step of collecting the resultant acrylic acid as a solution by using water or a solvent.

7. The process for producing acrylic acid according to claim 6, further comprising a distillation step for removing low- and high-boiling-point materials from the resultant solution containing acrylic acid.

8. The process for producing acrylic acid according to claim 6, further comprising a crystallization step for purifying acrylic acid by crystallizing it.

9. A petroleum independent process for producing acrylic acid, comprising the steps of:

a) obtaining glycerol from one of i) hydrolysis of oils-and-fats, ii) waste fluids in soap production, and iii) a by-product in production of a bio-diesel fuel as a renewable fuel;

b) vaporizing a raw material comprising an aqueous glycerol solution having said glycerol to generate a first gas, wherein said aqueous glycerol solution has a water content of not more than 20% by weight;

c) adding an inert gas to the first gas to obtain a resultant mixed gas, wherein the inert gas is selected from the group consisting of nitrogen gas, carbon dioxide gas and rare gas, and controlling a concentration of said inert gas in said resultant mixed gas to a concentration of not less than 50% by volume;

d) applying a dehydration reaction to glycerol in a gas phase that includes said resultant mixed gas, wherein the gas phase in which said dehydration reaction is conducted comprises glycerol, water vapor and oxygen, and wherein the amount of the water vapor relative to the glycerol in the mixed gas is not larger than 1.2 times by mol;

e) applying a gas phase oxidation reaction to a gaseous reaction product formed by the dehydration reaction to obtain said acrylic acid; and

f) conducting the dehydration reaction and the gas phase oxidation reaction in a single-type reactor comprising one reaction tube, where said one reaction tube is filled with catalysts for the dehydration reaction and for the gas phase oxidation reaction uniformly mixed together or with a catalyst which functions both for the dehydration reaction and the gas phase oxidation reaction, thus conducting the dehydration reaction and the gas phase oxidation reaction in said one reaction tube at the same time.