Process for producing electrophotographic photosensitive member

• US 7,622,238 B2
• Filed: 06/28/2007
• Issued: 11/24/2009
• Est. Priority Date: 01/31/2006
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Ochi, Atsushi, Uematsu, Hiroki, Ogaki, Harunobu, Shimada, Akira, Kikuchi, Toshihiro, Kawahara, Masataka, Sumida, Takayuki, Koganei, Akio, Maruyama, Akio, Teramoto, Kyoichi
• Primary Examiner(s): Goodrow; John L
• Application Number:
  US11/770,092
• Publication Number:
  US 20070281239A1
• Time in Patent Office: 880 Days
• Field of Search: 430/133, 430/56, 430/66, 430/130
• US Class Current: 430/130
• CPC Class Codes: G03G 5/043 Photoconductive layers characterised by having two or more layers or characterised by their composite structure
• CPC Class Codes: G03G 5/047 characterised by the charge-generation layers or charge transport layers G03G5/0433 and G03G5/0436 take precedence
• CPC Class Codes: G03G 5/05 Organic bonding materials; Methods for coating a substrate with a photoconductive layer; Inert supplements for use in photoconductive layers
• CPC Class Codes: G03G 5/0525 Coating methods
• CPC Class Codes: G03G 5/0592 Macromolecular compounds characterised by their structure or by their chemical properties, e.g. block polymers, reticulated polymers, molecular weight, acidity
• CPC Class Codes: G03G 5/0596 Macromolecular compounds characterised by their physical properties
• CPC Class Codes: G03G 5/10 Bases for charge-receiving or other layers

Abstract

A process for producing an electrophotographic photosensitive member, which has the step of bringing i) the surface of an electrophotographic photosensitive member having at least a charge transport layer on a cylindrical support and ii) a mold having a fine unevenness surface profile into pressure contact with each other to transfer the fine unevenness surface profile to the surface of the electrophotographic photosensitive member. The mold and the support are so temperature-controlled as to be T3<T1<T2 where the glass transition temperature of the charge transport layer is represented by T1 (°C.), the temperature of the mold by T2 (°C.), and the temperature of the support by T3 (°C.).

Claims

1. A process for producing an electrophotographic photosensitive member;

the process comprising the step of bringing i) the surface of an electrophotographic photosensitive member comprising at least a cylindrical support and a charge transport layer provided thereon and ii) a mold having a fine unevenness surface profile, into pressure contact with each other to transfer the fine unevenness surface profile to the surface of the electrophotographic photosensitive member, wherein;

the mold and the cylindrical support are so temperature-controlled as to be T3<

T1<

T2 where the glass transition temperature of the charge transport layer is represented by T1(°

C.), the temperature of the mold by T2(°

C.), and the temperature of the cylindrical support by T3(°

C.), and the following relationship is maintained;

T1<

T4 where the maximum value of the temperature of the charge transport layer at the part of pressure contact between the surface of the electrophotographic photosensitive member and the mold is represented by T4(°

C.), wherein the charge transport layer is formed by coating a solution containing at least a binder resin and a charge-transporting material, and then drying the solution;

T5<

T4 where the maximum value of the temperature of the charge transport layer in the step of drying is represented by T5(°

C.);

T6<

T1 where the maximum value of the temperature of the charge transport layer at the part other than the part of pressure contact between the surface of the electrophotographic photosensitive member and the mold is represented by T6(°

C.); and

T4<

T7 where the melting point of the charge-transporting material is represented by T7 (°

C.).

2. The process according to claim 1, wherein a member having a larger heat capacity than the cylindrical support is inserted to the interior of the cylindrical support.

3. The process according to claim 2, wherein the member having a larger heat capacity has a mechanism which controls the temperature of the cylindrical support.

4. The process according to claim 3, wherein the member having a larger heat capacity has a cooling mechanism.

5. The process according to claim 1, wherein the fine unevenness surface profile is continuously transfeffed to the surface of the electrophotographic photosensitive member in its peripheral direction.

6. A process for producing an electrophotographic photosensitive member having a unevenness profile on the surface thereof, comprising a cylindrical support and a charge transport layer provided thereon, the charge transport layer having a glass transition temperature of T1(°

C.),

the charge transport layer being formed by coating a solution containing at least a binder resin and a charge-transporting material, and then drying the solution,

the process comprising a step of bringing a mold having an unevenness surface profile corresponding to the unevenness profile, and having a temperature of T2(°

C.), into pressure contact with the peripheral surface of an electrophotographic photosensitive member, and rotating at least one of the mold and the electrophotographic photosensitive member to transfer the unevenness surface profile of the mold to the peripheral surface of the electrophotographic photosensitive member;

wherein the step is carried out while maintaining the relationship represented by the following inequalities;

T3<

T1<

T2, T6<

T1, T1<

T4, T5<

T4, T4<

T7,

where T3(°

C.) represents the temperature of the cylindrical support,

T4(°

C.) represents the maximum value of the temperature of the charge transport layer at the part of pressure contact between the surface of the electrophotographic photosensitive member and the mold;

T5(°

C.) represents the maximum value of the temperature of the charge transport layer in the step of drying;

T6(°

C.) represents the maximum value of the temperature of the charge transport layer at the part other than the part of pressure contact between the surface of the electrophotographic photosensitive member and the mold; and

T7 (°

C.) represents the melting point of the charge-transporting material.