Compositions comprising tetrafluoropropene and carbon dioxide

• US 7,629,306 B2
• Filed: 04/29/2005
• Issued: 12/08/2009
• Est. Priority Date: 04/29/2004
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Singh, Rajiv R., Shankland, Ian
• Primary Examiner(s): Webb; Gregory E
• Application Number:
  US11/118,833
• Publication Number:
  US 20060043331A1
• Time in Patent Office: 1,684 Days
• Field of Search: 510/408, 510/412, 252/67
• US Class Current: 510/408
• CPC Class Codes: C08J 2203/06 CO2, N2 or noble gases
• CPC Class Codes: C08J 2203/162 Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
• CPC Class Codes: C08J 2203/164 Perhalogenated unsaturated hydrocarbons, e.g. F2C=CF2
• CPC Class Codes: C08J 2203/182 of physical blowing agents, e.g. acetone and butane
• CPC Class Codes: C08J 9/127 Mixtures of organic and inorganic blowing agents
• CPC Class Codes: C09K 2205/106 Carbon dioxide
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen

Abstract

Disclosed are compositions useful in a wide variety of applications, including heat transfer fluids which possess a highly desirable and unexpectedly superior combination of properties, and heat transfer systems and methods based on these fluids. The preferred heat transfer fluid comprises from about 1 to about 40 percent, on a weight basis, of carbon dioxide (CO₂) and from about 99 to about 60 percent, on a weight basis, of a compound having the Formula I XCF_zR_3-z (I), where X is a C₂ or a C₃ unsaturated, substituted or unsubstituted, alkyl radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3. A preferred compound of Formula I is tetrafluoropropene, particularly 1,1,1,3-tetrafluoropropene and/or 1,1,1,3-tetrafluoropropene.

Claims

1. A foam formed from a foamable composition comprising a blowing agent comprising CO₂ and one or more compounds of Formula I

XCF_zR_3-z 

 

(I),

wherein

X is a C₂ or a C₃ unsaturated, substituted or unsubstituted, alkyl radical,

R is independently selected from Cl, F, Br, I or H, and

z is 1 to 3,

wherein the foam comprises CO₂ and said at least one compound of Formula I in a weight ratio from about 1;

99 to about 40;

60, respectively.

2. A closed cell foam comprising the foam of claim 1.

3. The foam of claim 1 wherein said compound of Formula I is a tetrafluoropropene.

4. The foam of claim 3 wherein said tetrafluoropropene is 1,1,1,3-tetrafluoropropene.

5. The foam of claim 3 wherein said tetrafluoropropene is trans-1,1,1,3-tetrafluoropropene.

6. The foam of claim 5 wherein the weight ratio of CO₂ to trans-1,1,1,3-tetrafluoropropene is at least about 5:

95.

7. The foam of claim 3 wherein said tetrafluoropropene is 1,1,1,2-tetrafluoropropene.

8. The foam of claim 7 wherein said tetrafluoropropene is trans-1,1,1,2-tetrafluoropropene.

9. The foam of claim 7 wherein the weight ratio of CO₂ to trans-1,1,1,2-tetrafluoropropene is at least about 3:

97.

10. The foam of claim 1 wherein said blowing agent is non-flammable.

11. The foam of claim 1, wherein said foamable composition further comprises at least one adjuvant selected from the group consisting of dispersing agents, surfactants, supplemental flame suppressants, cell stabilizers, polyols, polyol premix components, and combinations of two or more of these.

12. The foam of claim 1, wherein said foam is characterized as at least one of a thermoplastic foam and a thermosetting foam.

13. The foam of claim 12, wherein said foam is a thermoplastic foam.

14. The foam of claim 13, wherein the thermoplastic foam is characterized as at least one of an extruded thermoplastic foam, a polystyrene foam, a polyethylene foam, a low density polyethylene foam, a polypropylene foam and a polyethyleneterephthalate foam.

15. The foam of claim 12, wherein said foam is a thermosetting foam.

16. The foam of claim 15, wherein the thermosetting foam is characterized as at least one of a polyurethane foam, a polyisocyanurate foam and a phenolic foam.